蒸馏水中蒙脱石晶层间膨胀压力理论研究

蒙脱石颗粒周围的溶液浓度对其膨胀性有较大影响,传统的双电层模型可以对电解质环境下蒙脱石的膨胀特性做出较好的模拟,但并不适于蒸馏水的情况。针对膨润土在蒸馏水或纯水中已有的膨胀特性试验,本文在前人的研究基础上详细推导了蒸馏水中蒙脱石晶层间的膨胀压力模型,并给出一种简便算法。运用此算法可以避免非线性方程的求解,从而可以较方便的将膨胀力和晶层间距联系起来。     

Provenance System Analysis of the Nantun Formation of the Huhehu Sag in Hailar Basin

Huhehu Sag is a new battlefield for the future oil and gas exploration in the Hailar Basin. At present, exploration of this area stays at a low level and the understanding of the provenance system of the Nantun Formation is comparatively weak. So, to carry out the detailed depiction of the provenance system in the study area is significant for the sedimentary system reconstruction, for the prediction of reservoir distribution and favorable areas. Based on comprehensive analysis of paleogeomorphy, light-heavy mineral and seismic reflection features, sandstone thickness and sandstone percentage, this paper analyzes in detail the provenance system of the Nantun Formation in Huhehu Sag from various angles and levels. It shows that provenances of the Huhehu Sag mainly originated from the eastern Xilinbeier Salient and western Bayan Mountain Uplift. The provenances surrounding the lake basin converged to the center of the basin, among which, the steep slope belt and the gentle slope belt are the main provenances, and the southern uplift is a secondary one. The distribution framework of the provenance fundamentally determines the distribution rules of the depositional system and its sand body developing during the Nantun period.     

基于DGT和化学提取法研究浙西北地质高背景区土壤镉生物有效性

地质高背景区相较于人类活动引起的土壤镉污染影响范围更广,在区域尺度上对生态系统和人类健康构成危害。土壤镉生物有效性是决定其生物可利用性、生物毒性的关键因素,因此探寻可行的土壤镉生物有效性评价方法对污染农用地安全利用和风险管控具有重要的理论和实际意义。DGT技术、单一提取法、连续提取法和土壤溶液法常用于测定土壤有效镉,但已有研究成果主要基于同种土地利用类型土壤的室内盆栽实验,难以代表自然污染土壤中的复杂情况。为探明各土壤重金属有效态提取技术对地质高背景区不同土地利用类型土壤Cd生物有效性评估效果,本文以浙江西北部土壤Cd高地质背景区水田土壤-水稻籽实和旱地土壤-小白菜样品为研究对象,实验应用DGT技术、单一提取法（0.01mol/L氯化钙提取）、连续提取法（七步连续提取）和土壤溶液法评价土壤中镉生物有效性。结果显示：①研究区水田和旱地土壤Cd平均含量分别为1.07mg/kg和0.73mg/kg,显著高于浙江和全国土壤平均水平,Cd的异常富集主要与浙西北地区广泛分布的黑色岩系有关。②相较于碳酸盐岩区,黑色岩系区土壤中Cd的生物有效组分占比较高,水田和旱地土壤Cd的活动系数（MF）高达59.9%和51.8%,Cd易在土壤-作物系统中发生迁移富集;③植物体内镉含量Cd-P与不同方法测定的有效镉含量均呈显著正相关,但Cd-P与DGT技术测定的有效镉含量相关性优于其他三种方法,水田土壤测得的有效Cd与水稻籽实相关关系：$ {{C}}_{\text{soln}} $>CDGT>$ {{C}}_{{\text{CaCl}}_{\text{2}}} $>$ {{C}}_{{\text{F}}_{\text{1}}\text{+}{\text{F}}_{\text{2}}\text{+}{\text{F}}_{\text{3}}} $,旱地土壤测得的有效Cd与小白菜相关关系：CDGT >$ {{C}}_{{\text{CaCl}}_{\text{2}}} $>$ {{C}}_{{\text{F}}_{\text{1}}\text{+}{\text{F}}_{\text{2}}\text{+}{\text{F}}_{\text{3}}} $>$ {{C}}_{\text{soln}} $。综合比较不同土壤有效Cd测定方法的优缺点,DGT技术可以模拟植物体对Cd的动态吸收过程,更能准确地反映土壤Cd生物有效性,预测作物Cd含量水平,这与已有研究成果一致。此外,本文研究成果表明DGT技术评价土壤Cd生物有效性,不仅适用于人为污染区,也可应用于地质高背景区。     

东昆仑拉陵高里河沟脑地区晚三叠世花岗闪长斑岩年代学、岩石地球化学及Hf同位素特征

本文对东昆仑拉陵高里河沟脑花岗闪长斑岩开展详细的全岩地球化学、LA- ICP- MS锆石U- Pb年代学、锆石Hf同位素研究,确定其形成时代,并探讨其岩石成因及成岩构造背景。结果显示,花岗闪长斑岩LA- ICP- MS锆石U- Pb年龄为231. 1±1. 2 Ma,指示其侵位于晚三叠世早期。全岩K2O/Na2O值为0. 69～0. 71,Mg#值为40. 5～41. 6,里特曼指数σ为1. 90～2. 09,A/CNK=1. 01～1. 03,属弱过铝质中—高钾钙碱性岩石系列。岩石的轻重稀土元素分异明显,(La/Yb)N值为19. 54～25. 52,具弱负Eu异常（δEu为0. 96～0. 97）,富集大离子亲石元素K、Rb、Ba、Th,亏损高场强元素Nb、Ta、Ti等,具有高的Sr含量(606. 0×10-6～647. 9×10-6)和Sr/Y值(60. 38～62. 99),较低的Y(9. 62×10-6～10. 66×10-6)和Yb(0. 86-6～0. 92×10-6)含量,显示Adakite（高锶低钇中酸性岩）的地球化学特征。锆石Hf同位素εHf(t)值介于-6. 93~-2. 94,地壳模式年龄（TDM2）范围为1. 45~1. 70 Ga。综合分析表明,拉陵高里河沟脑花岗闪长斑岩形成于东昆仑洋壳俯冲末期至局部碰撞的转换阶段,岩浆源于高压条件下的加厚下地壳部分熔融。     

昆明呈贡石灰岩上覆红黏土干缩裂隙的温度效应

温度是影响土体干缩开裂的重要外部环境因素之一。为研究温度对红黏土干缩裂隙的影响,以昆明呈贡石灰岩上覆红黏土为对象,经风干、碾碎和筛分后,选取2 mm以下的细颗粒,用正方形钢化玻璃容器制备9个厚度为10 mm的饱和泥浆样,分成3组,每组3个平行样,利用控温烘箱分别进行30℃、50℃和70℃的干燥试验,试验过程中定时称重试样和对土样表面进行拍照,然后用PCAS软件对照片进行图像处理。结果表明：红黏土的蒸发过程可分为3个阶段,干缩裂隙的形成和发展可分为5个阶段;温度升高,干燥完成时间减短,常速率阶段的蒸发速率和蒸发量增大,最终含水率降低;初始临界含水率随温度升高而增大;随着土体含水率持续减小,表面裂隙率先缓慢增加,然后快速增大,最后趋于稳定;温度升高,裂隙交点数、裂隙条数、裂隙总长度和土块数减少,裂隙平均长度、裂隙平均宽度、表面裂隙率、土块平均面积、土块最大面积、干缩厚度和干密度增大。温度显著影响红黏土的水分蒸发过程,干缩裂隙的形成和发展,以及表面裂隙结构和形态。     

河南省栾川县大竹园沟钨钼矿地质特征及找矿标志

在野外地质调查的基础上,开展了商业合作性的进一步深部探矿工作.通过物化探手段及钻孔布设验证了深部地质、矿化情况.矿区深部新发现多组隐伏的钨钼矿体,矿体呈似层状、脉状产出,岩性控矿特征较为明显.综合分析认为该矿床成因类型应为斑岩型.     

熔融制样-X射线荧光光谱法测定电气石中12种主次量元素

电气石是一类含硼的铝硅酸盐矿物,化学成分复杂、化学稳定性强,不易湿法分解,B_2O_3含量较高,导致其主次量元素的同时测定存在一定困难。本文采用熔融法制样,建立了X射线荧光光谱法测定电气石Na_2O、MgO、Al_2O_3、SiO_2、P_2O_5、K_2O、CaO、TiO_2、V_2O_5、Cr_2O_3、MnO、TFe_2O_3等主次量元素的分析方法。样品与四硼酸锂-偏硼酸锂-氟化锂(质量比为4.5∶1∶0.4)混合熔剂的稀释比例为1∶10,消除了粒度效应和矿物效应;在缺少电气石标准物质的情况下,选择土壤、水系沉积物及多种类型的地质标准物质绘制校准曲线,利用含量与电气石类似的标准物质验证准确度,测定结果的相对标准偏差小于4.2%。采用所建方法测定四种不同类型电气石实际样品,测定值与经典化学法基本吻合。本方法解决了电气石不易湿法分解和硼的干扰问题,测定结果准确可靠,与其他方法相比操作简便,分析周期短。     

河道再生水利用安全问题

2010年《永定河绿色生态走廊建设规划》拟利用北京城市段的门城湖、莲石湖、晓月湖和宛平湖,采用＂生态补水型＂的治理模式,建成1500km2的生态走廊,新增水面1000ha,绿化面积9000ha,每年回补地下水1亿m3,发挥再生水的＂生态功能＂。本文构建三个不同水文地质单元的溶质运移数值模型,模拟预测了河道利用再生水对周边地下水的影响。     

Carbon emission mitigation through regulatory policies and operations adaptation in supply chains: theoretic developments and extensions

Along with carbon emission regulations launched by governments and consumers’ rising concerns about climate changes and global carbon footprint, interests of academia and industry have risen in carbon-efficient supply chain management. This research focuses on some product supply chain to make a literature review-based investigation on proposing a theoretical framework. We also solve potential research issues of how diverse carbon emission regulations can work on supply chain performance as well as emission; in what way we can find coordination mechanisms and optimal policies for supply chain operations to abate emission and enhance system profitability within different scenarios; and also to evaluate the effect on emission reduction for each emission regulation aforementioned through comparing their associated supply chain performances and system emission. Both practitioners in industry and academia might find this study useful, as it generates concepts with a formal framework of potential and values theoretical issues in the emerging field of carbon-efficient supply chain management which combines carbon emission regulations with mature operation management to enrich the theory of supply chain management. This study is perhaps to be valuable and constructive both for operational decisions in firms and for the enactment as well as implementation of emission-reduction regulations. This study should activate further potential researches.