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61.
Significant boron isotope fractionation occurs in nature (?70 ‰ to +75 ‰) due to the high geochemical reactivity of boron and the large relative mass difference between 10B and 11B. Since the 1990s, reconstruction of ancient seawater pH using the isotopic composition of boron in bio-carbonates (δ 11Bcarb), and then calculation of the past pCO2 have become important issues for the international isotope geochemistry community, and are called the δ 11B-pH proxy. Although many achievements have been made by this proxy, various aspects of boron systematics require rigorous evaluation. Based on the previous researches, mechanism of boron isotope fractionation, variation of boron isotope (δ 11B) in nature (especially in bio-carbonates) and controlling factors of the δ 11B-pH proxy, such as the dissociation constant of B(OH)3 in seawater (pKa), the δ 11B of seawater (δ 11BSW), the boron isotopic fractionation factor between B(OH) 4 ? and B(OH)3 (α 4–3), and the incorporated species of boron into bio-carbonates, are reviewed in detail and the research directions of this proxy are proposed. Generally, the controversy about pKa, δ 11Bsw, and α 4–3 is relatively less, but whether boron incorporated into bio-carbonates only in the form of B(OH) 4 ? remains doubtful. In the future, it is required that the physicochemical processes that control boron incorporation into carbonates be rigorously characterized and that the related chemical and isotopic fractionation be quantified. It is also necessary and important to establish a “best-fit empirically equation” between δ 11Bcarb and pH of seawater based on the precipitation experiments of inorganic or culture experiments of corals or foraminifera. In addition, extended application of the δ 11B-pH proxy to the earlier part of the Phanerozoic relying on the Brachiopods is worthy of studying. Like other geochemical indicators, there are limiting factors of δ 11B; however, it remains a very powerful tool in the reconstruction of past seawater pH at present. 相似文献
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Yan‐Dong Ma Jing‐Bo Zhao Xiao‐Qing Luo Tian‐Jie Shao Zhi‐Bao Dong Qi Zhou 《水文研究》2017,31(18):3255-3268
The hydrology and water balance of megadunes and lakes have been investigated in the Badain Jaran Desert of China. Field observations and analyses of sand layer water content, field capacity, secondary salt content, and grain size reveal 3 types of important natural phenomenon: (a) vegetation bands on the leeward slope of the megadunes reflect the hydrological regime within the sandy vadose zone; (b) seepage, wet sand deposits, and secondary salt deposits indicate the pattern of water movement within the sandy vadose zone; (c) zones of groundwater seeps and descending springs around the lakes reflect the influence of the local topography on the hydrological regime of the megadunes. The seepage exposed on the sloping surface of the megadunes and gravity water contained within the sand layer confirm the occurrence of preferential flow within the vadose zone of the megadunes. Alternating layers of coarse and fine sand create the conditions for the formation of preferential flows. The preferential flows promote movement of water within the sand layer water that leads to deep penetration of water within the megadunes and ultimately to the recharging of groundwater and lake water. Our results indicate that a positive water balance promotes recharge of the megadunes, which depends on the high permeability of the megadune material, the shallow depth of the surface sand layer affected by evaporation, the occurrence of rainfall events exceeding 15 mm, and the sparse vegetation cover. Water balance estimates indicate that the annual water storage of the megadunes is about 7.5 mm, accounting for only 8% of annual precipitation; however, the shallow groundwater per unit area under the megadunes receives only 3.6% of annual precipitation, but it is still able to maintain a dynamic balance of the lake water. From a water budget perspective, the annual water storage in the megadunes is sufficient to serve as a recharge source for lake water, thereby enabling the long‐term persistence of the lakes. Overall, our findings demonstrate that precipitation is a significant component of the hydrological cycle in arid deserts. 相似文献
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2020年长江流域发生了历史第二大洪水,大通站洪峰流量达到84 500 m3/s。本文基于2020年7月长江口特大洪水期间最大浑浊带多站位的水沙观测数据,重点分析了悬沙粒度组分的时空分布特征,并与常态水文条件下的粒度数据进行对比。结果表明:(1)最大浑浊带悬沙垂向平均中值粒径为10.4μm,变化范围为6~27μm,以黏性细颗粒泥沙为主;其中核心区南槽、北槽及北港的中值粒径分别为8.4μm、7.6μm和8.5μm,过渡区分别为7.2μm、16.4μm和14.5μm。(2)悬沙中值粒径垂向分布受不同组分影响,核心区底层中值粒径为8.8~9.6μm;底层黏土含量在28%~31%之间,粉砂含量在61%~64%之间,中值粒径主要受黏土及粉砂组分影响;过渡区北港和北槽垂向平均砂组分高达19%,南槽砂组分平均仅占5%,中值粒径主要受砂组分影响。(3)对比2013年洪季浑浊带数据,2020年粒径整体增大5.4μm,核心区黏土含量相较2013年减少12.7%,砂增加6.3%;过渡区北槽与北港平均粒径增大10μm。 相似文献
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高应变法检测是基桩检测技术的一种重要手段,但是该方法检测承载力存在误差,因此受到许多争议。本文以广东惠州地区两项工程的检测实践为例,分别采用前后两组不同拟合参数,对检测数据进行了承载力拟合计算,分别得出了前后两种不同的计算结果。并通过动、静两种方法的对比检测,分析了高应变法检测承载力误差产生的主要原因,粗略探讨了对高应变法检测的一些认识。 相似文献
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INTRODUCTIONAquiculturearearedtidesignalsoceanpollutionanddisaster.Althoughenvironmentscientistshaveconductedmanyin depthresearchesonthecauseandformationmechanismofredtide ,manyofitsaspectsarestillunknownbecauseredtideisacomplexphenomenonandtheecologic… 相似文献
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桶形基础沉贯室内模型试验研究 总被引:3,自引:0,他引:3
桶形基础采用负压沉贯法施工,其贯入阻力与压桩,打桩等施工方法显著不同。本文介绍了在粉土和粉质粘土地层中的一组模型试验情况,认为负压法施工可显著降低粉土的抗贯阻力,但在粉质粘土中减阻效果不明显。 相似文献