Trace Elements Analysis of Geological Samples by Laser Ablation Inductively Coupled Plasma Mass Spectrometry

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A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.     

粉喷桩处理软基的变形及固结测试分析

以广珠准高速铁路软土路堤试验粉喷桩处理段的变形及孔压测试数据为基础 ,对用粉喷桩处理深厚软土地基的沉降、基底横向差异沉降、边桩变形、孔压分布规律及固结进行了分析     

安徽拂晓地区地物化特征及找矿意义

拂晓地区位于苏鲁超高压变质带安徽段的张八岭地区,地质构造条件与山东段的胶东金矿矿集区类似,具有较好的成矿地质条件和找矿前景。为探索拂晓地区金矿找矿前景,我们系统的开展地物化工作,以面积性的磁法、化探异常为依据,圈定隐伏岩体范围,提供多目标的直接找矿信息,减小找矿范围,预测出两个重点找矿远景区。在重点找矿远景区内,部署了两条可控源音频大地电磁和频谱激电剖面对重点区域的深部纵向结构特征进行探索。综合研究拂晓地区的地物化资料,提出以“弱磁异常-化探异常中心-中等强度的电性异常”为特征的物化探找矿标志;“煌斑岩脉-闪长质脉岩”为特征的地质直接找矿标志;“次级断裂带-不同岩体间的接触带区域”为重点找矿区域的地物化综合找矿方法,有效的增强了找矿能力。为安徽拂晓地区及其邻区的矿产勘查工作提供一定的指示。     

地下水源热泵系统热平衡预测三维数值模拟

为了准确模拟预测地下水源热泵系统运行期间的地下水渗流场与温度场的变化规律,避免未来地下水源热泵系统运行期间出现的冷热贯通现象与堆积问题,科学合理地设计地下水源热泵系统。以江苏南通益兴集团地下水源热泵示范工程为例,建立了地下水渗流与热量运移三维耦合数值模型,并结合地下水源热泵系统的设计运行方案,预测分析了未来地下水源热泵系统的热平衡发展趋势。结果表明,该工程按设计方案运行,整个区域地下水温度逐渐升高,出现热堆积问题。采用春秋季与冬季多加热生活用水增加制热负荷量的方法,可有效缓解热堆积问题。     

超前锚杆短循环法在砂砾石隧洞挂口施工中的应用

介绍了在支洞工程的施工中,利用超前锚杆短循环法解决在砂砾石地层中挂口难题的具体措施和关键技术,实现了工程自身及周围围道公路,升压站等重要建筑物的安全技术要求。     

Radioactive elements in natural gas: a case study on distribution of gaseous 222radon and its origin mechanism

As natural gas becomes increasingly important in our daily life, studies have been carried out on trace elements such as mercury and arsenic within it. Other than those, the existence of radioactive gaseous radon from the combustion of natural gas indoors can cause severe diseases and damages to body organs, putting a hazardous impact on human health. At the same time, the radon can also corrode gas production and transportation equipment. A review of the literature on radon concentrations in natural gas produced from gas reservoirs in China and other countries have been studied. Radon is a decay product from ²³⁸U, which is closely related to the accumulation and migration of organic matter during diagenesis. Gas recovered from reservoirs with higher than average natural ²³⁸U contains higher than average levels of ²²²Rn. Massive fault systems and fracture zones appear to play a significant role in radon concentrations in natural gas.