Analytical models of contaminant transport in coastal aquifers

The Henry formulation, which couples subsurface flow and salt transport via a variable-density flow formulation, can be used to evaluate the extent of sea water intrusion into coastal aquifers. The coupling gives rise to nontrivial flow patterns that are very different from those observed in inland aquifers. We investigate the influence of these flow patterns on the transport of conservative contaminants in a coastal aquifer. The flow is characterized by two dimensionless parameters: the Péclet number, which compares the relative effects of advective and dispersive transport mechanisms, and a coupling parameter, which describes the importance of the salt water boundary on the flow. We focus our attention on two regimes – low and intermediate Péclet number flows. Two transport scenarios are solved analytically by means of a perturbation analysis. The first, a natural attenuation scenario, describes the flushing of a contaminant from a coastal aquifer by clean fresh water, while the second, a contaminant spill scenario, considers an isolated point source.     

Biomarker characterisation and hydrous pyrolysis of bitumens from Tertiary volcanics, queen Charlotte islands, British Columbia, Canada

A number of bitumen samples have been recovered from vugs and fractures in outcropping Tertiary basalts of the Queen Charlotte Islands off the west coast of British Columbia, Canada. n-Alkanes and acyclic isoprenoids are not present and the polycyclic biomarker distribution of the four samples analyzed by GC and GC-MS has been altered. One sample contains no remaining recognizable biomarkers. Two bitumens were also obtained from Lower Jurassic potential source rocks, including one from the Sandilands Formation, which was considered previously to be the most likely source of the Tertiary bitumens. Although these two bitumens were also taken from outcrops, they are considerably less biodegraded. The Sandilands Formation bitumen contains 28, 30-bisnorhopanes and since these compounds were not detected in the Tertiary bitumens, there is no evidence from the initial results for a Sandilands Formation contribution to the hydrocarbons in the Tertiary basalts. The presence of 18α(H)-oleanane in the saturate fraction of two of the Tertiary bitumens from widely separated locations indicates that they are at least partially sourced from Tertiary organic matter.Because the distribution of biomarkers in some samples has been severely affected by biodegradation, the asphaltenes of the bitumens were hydrously-pyrolysed and the saturate fractions of the resulting pyrolysates analysed for possible additional information on the origin of the bitumens. The pyrolysates from the more degraded samples contain compounds not detected in the saturate fractions of the original bitumen and show some of the expected characteristics of the original non-degraded bitumen. However, the compounds most useful for correlation are not present in the pyrolysates apparently due to their non-incorporation into the kerogen macromolecule. Our results suggest that hydrous-pyrolysis of asphaltenes is of limited use in the correlation of biodegraded samples and in determining their origins.     

Shallow seismicity, stress distribution and crustal deformation pattern in the Andaman-West Sunda arc and Andaman Sea, northeastern Indian Ocean

Shallow seismicity and available source mechanisms in the Andaman–westSunda arc and Andaman sea region suggest distinct variation in stressdistribution pattern both along and across the arc in the overriding plate.Seismotectonic regionalisation indicates that the region could be dividedinto eight broad seismogenic sources of relatively homogeneousdeformation. Crustal deformation rates have been determined for each oneof these sources based on the summation of moment tensors. The analysisshowed that the entire fore arc region is dominated by compressive stresseswith compression in a mean direction of N23^°, and the rates ofseismic deformation velocities in this belt decrease northward from 5.2± 0.65 mm/yr near Nias island off Sumatra and 1.12 ±0.13 mm/yr near Great Nicobar islands to as much as 0.4 ±0.04 mm/yr north of 8^°N along Andaman–Nicobar islandsregion. The deformation velocities indicate, extension of 0.83 ±0.05 mm/yr along N343^° and compression of 0.19 ±0.01 mm/yr along N73^° in the Andaman back arc spreadingregion, extension of 0.18 ± 0.01 mm/yr along N125^° andcompression of 0.16 ± 0.01 mm/yr along N35^° in NicobarDeep and west Andaman fault zone, compression of 0.84 ±0.12 mm/yr N341^° and extension of 0.77 ± 0.11 mm/yralong N72^° within the transverse tectonic zone in the Andamantrench, N-S compression of 3.19 ± 0.29 mm/yr and an E-Wextension of 1.24 ± 0.11 mm/yr in the Semangko fault zone ofnorth Sumatra. The vertical deformation suggests crustal thinning in theAndaman sea and crustal thickening in the fore arc and Semangko faultzones. The apparent stresses calculated for all major events range between0.1–10 bars and the values increase with increasing seismic moment.However, the apparent stress estimates neither indicate any significantvariation with faulting type nor display any variation across the arc, incontrast to the general observation that the fore arc thrust events showhigher stress levels in the shallow subduction zones. It is inferred that theoblique plate convergence, partial subduction of 90^°E Ridge innorth below the Andaman trench and the active back arc spreading are themain contributing factors for the observed stress field within the overridingplate in this region.     

Late Quaternary marine terraces in the Mediterranean coastal area of Syria: Geochronology and neotectonics

In order to provide new data on the neotectonics and geodynamic properties of western Syria, studies of marine terraces have been carried out. The most attention was paid to the lower terraces in the range of 3–5 to 30–35 m above sea level, because they have more complete distributions along the shore. The lower terraces were examined along the coastal area from Tartus to Latakia, and along the carbonate cliff on Arwad Island. Seven ²³⁰Th/U dates for these terraces are in the range of 85–130 ka, suggesting the age interval of the last interglacial (MIS 5). New dates on the lower terraces provide a basis for stratigraphical and geomorphological interpretation as well as neotectonic reconstruction. According to the geomorphological data and lithological composition of those terraces, two main uplifted blocks can be established. One coincides with the Latakia block, and another corresponds to the western margin of the Banias volcanic plateau. These blocks are divided by a subsided structure corresponding to the Nahr el Kebir graben. The amplitude of neotectonic uplifting in the Latakia and Banias blocks reaches 15–20 m for the Late Pleistocene.     

Temporal and tectonic evolution of the granulite-eclogite association from the Bergen Arcs, western Norway

The U-Pb and Sm-Nd dating of deep crustal rocks from the Bergen Arcs system helps resolve enigmatic aspects of the tectonic evolution of the Caledonian Orogen in western Norway and yields insights into the arrested stages of eclogite development within the granulites of the area. The U-Pb dating of zircon from one of the eclogite facies shear zones yields an upper intercept age of 945 ± 5 Ma [all errors two standard deviations (2σ)], which is similar to other zircon ages from the granulite facies protolith. The age is interpreted to represent the time of late Proterozoic (Sveconorwegian) granulite metamorphism. The U-Pb ages of sphene and epidote show that the eclogites formed early in the evolution of the Caledonian Orogen (pre-Scandian phase) at about 460 Ma. An eclogite facies quartz vein yields a Sm-Nd whole rock-garnet isochron of 440 ± 12 Ma that may reflect the onset of cooling immediately after peak eclogite facies conditions, although the Sm-Nd systematics reveal some isotopic disequilibrium within the sample. In tandem with previous ⁴⁰Ar/³⁹Ar age determinations from, an adjacent eclogite of 450 Ma for hornblende and 430 Ma for muscovite, these data indicate that < 30 Ma elapsed between formation of the eclogites and the initial stages of cooling and exhumation to at least mid-crustal levels. This corresponds to minimum cooling rates of 14 °C/m.y. The timing relations suggest that the formation and exhumation of these eclogites from the overlying Caledonian Nappe wedge in western Norway are related to an early phase of crustal subduction during or somewhat before the major phase of continent-continent collision.

The short period of time between the formation of the eclogites and the initial stages of exhumation and rapid cooling is consistent with the only partial and localized transformation of the granulite to eclogite. Isolated occurrences of eclogite within the granulite, the formation of eclogite along metasomatic fronts and the formation of hydrous eclogite facies minerals within the “dry” granulite all point to the importance of fluids in the transformation and re-equilibration of the granulite to eclogite. Together, field and isotopic data demonstrate that both the localized and limited access of fluids and the rapid cycling of continental crust through the deepest portions of the orogen to upper crustal levels resulted in the preservation of the arrested stages of eclogite formation and survival of the granulites metastably through eclogite facies conditions.     

Temporal deconvolution of the hydrogen coma: II. Pre- and post-perihelion activity of Comet Hyakutake (1996 B2)

Comet 1996 B2 (Hyakutake) displayed strong evidence for break-up, with a prominent antisunward dust spike and fragments traveling antisunward for many days after an eruptive event in late March 1996. Because of its high orbital inclination and rapid southward motion after perihelion, its post-perihelion activity was not well monitored from the ground. The SWAN all-sky Lyman-alpha camera on the SOHO spacecraft was ideally placed for long-term monitoring of the hydrogen coma of Comet Hyakutake both before and after perihelion. The SWAN images were analyzed with a new time-resolved model (TRM) that provides daily averages of the water production rate and an estimate of the hydrogen atom lifetime (dominated by charge exchange with solar wind protons) during extended periods throughout the apparition. A long-term variation of water production rate of , where r is the heliocentric distance in AU was found. The daily average values of the production rate covered the March 19 outburst and two more outbursts seen in the April before perihelion, which had progressively shorter durations at respectively smaller heliocentric distances. The long-term variation of the production rate was found to be consistent with the seasonal effect predicted by the jet rotation model of Schleicher and Woodney [2003. Analyses of dust coma morphology of Comet Hyakutake (1996 B2) near perigee: Outburst behavior, jet motion, source region locations, and the nucleus pole orientation. Icarus 162, 190-213] when added to a more steady source that is about two-thirds of the maximum of the jet source. The seasonal effect in their model found the dust jet source largely not illuminated after perihelion, coinciding with somewhat reduced overall activity and the absence of outbursts and fragmentation. The locations of the dust jets appear to be responsible for the outbursts and fragmentation before perihelion. The erratic behavior of the pre-perihelion jet sources as contrasted with the smoother variation from the rest of the surface after perihelion indicates there is a strong heterogeneity in the physical make-up of active areas on the nucleus.     

Depositional setting,provenance, and tectonic-volcanic setting of Eocene–Recent deep-sea sediments of the oceanic Izu–Bonin forearc,northwest Pacific (IODP Expedition 352)

New biostratigraphical, geochemical, and magnetic evidence is synthesized with IODP Expedition 352 shipboard results to understand the sedimentary and tectono-magmatic development of the Izu–Bonin outer forearc region. The oceanic basement of the Izu–Bonin forearc was created by supra-subduction zone seafloor spreading during early Eocene (c. 50–51 Ma). Seafloor spreading created an irregular seafloor topography on which talus locally accumulated. Oxide-rich sediments accumulated above the igneous basement by mixing of hydrothermal and pelagic sediment. Basaltic volcanism was followed by a hiatus of up to 15 million years as a result of topographic isolation or sediment bypassing. Variably tuffaceous deep-sea sediments were deposited during Oligocene to early Miocene and from mid-Miocene to Pleistocene. The sediments ponded into extensional fault-controlled basins, whereas condensed sediments accumulated on a local basement high. Oligocene nannofossil ooze accumulated together with felsic tuff that was mainly derived from the nearby Izu–Bonin arc. Accumulation of radiolarian-bearing mud, silty clay, and hydrogenous metal oxides beneath the carbonate compensation depth (CCD) characterized the early Miocene, followed by middle Miocene–Pleistocene increased carbonate preservation, deepened CCD and tephra input from both the oceanic Izu–Bonin arc and the continental margin Honshu arc. The Izu–Bonin forearc basement formed in a near-equatorial setting, with late Mesozoic arc remnants to the west. Subduction-initiation magmatism is likely to have taken place near a pre-existing continent–oceanic crust boundary. The Izu–Bonin arc migrated northward and clockwise to collide with Honshu by early Miocene, strongly influencing regional sedimentation.     

Structural controls on the formation of BSR over a diapiric anticline from a dense MCS survey offshore southwestern Taiwan

A dense seismic reflection survey with up to 250-m line-spacing has been conducted in a 15 × 15 km wide area offshore southwestern Taiwan where Bottom Simulating Reflector is highly concentrated and geochemical signals for the presence of gas hydrate are strong. A complex interplay between north–south trending thrust faults and northwest–southeast oblique ramps exists in this region, leading to the formation of 3 plunging anticlines arranged in a relay pattern. Landward in the slope basin, a north–south trending diapiric fold, accompanied by bright reflections and numerous diffractions on the seismic profiles, extends across the entire survey area. This fold is bounded to the west by a minor east-verging back-thrust and assumes a symmetric shape, except at the northern and southern edges of this area, where it actively overrides the anticlines along a west-verging thrust, forming a duplex structure. A clear BSR is observed along 67% of the acquired profiles. The BSR is almost continuous in the slope basin but poorly imaged near the crest of the anticlines. Local geothermal gradient values estimated from BSR sub-bottom depths are low along the western limb and crest of the anticlines ranging from 40 to 50 °C/km, increase toward 50–60 °C/km in the slope basin and 55–65 °C/km along the diapiric fold, and reach maximum values of 70 °C/km at the southern tip of the Good Weather Ridge. Furthermore, the local dips of BSR and sedimentary strata that crosscut the BSR at intersections of any 2 seismic profiles have been computed. The stratigraphic dips indicated a dominant east–west shortening in the study area, but strata near the crest of the plunging anticlines generally strike to southwest almost perpendicular to the direction of plate convergence. The intensity of the estimated bedding-guided fluid and gas flux into the hydrate stability zone is weaker than 2 in the slope basin and the south-central half of the diapiric fold, increases to 7 in the northern half of the diapiric fold and plunging anticlines, and reaches a maximum of 16 at the western frontal thrust system. Rapid sedimentation, active tectonics and fluid migration paths with significant dissolved gas content impact on the mechanism for BSR formation and gas hydrate accumulation. As we begin to integrate the results from these studies, we are able to outline the regional variations, and discuss the importance of structural controls in the mechanisms leading to the gas hydrate emplacements.