Application of organic petrology and geochemistry to coal waste studies

Coal wastes produced during mining activities are commonly deposited in nearby dumps. These wastes mostly composed of minerals and variable amounts (usually 20-30%) of organic matter start to weather immediately after deposition. Oxidation of the organic matter can lead to self heating and self combustion as a result of organic and mineral matter transformations. The degree of alteration depends on the properties of the wastes, i.e., the maceral and microlithotype composition of the organic matter and its rank.Alteration of wastes also depends on the heating history, i.e., the rate of heating, final heating temperature, duration of heating, and the degree of air access. Although air is probably necessary to initiate and drive the heating processes, these usually take place under relatively oxygen depleted conditions. With slow heating, color of organic matter particles changes, irregular cracks and oxidation rims develop around edges and cracks, and bitumen is expelled. As a result, massive and detritic isotropic and strongly altered organic matter forms. On the other hand, higher heating rates cause the formation of devolatilization pores, oxidation rims around these pores and along cracks, vitrinite-bands-mantling particles, and bitumen expulsions.Organic compounds generated from the wastes include n-alkanes, iso-alkanes, alkylcyclohexanes, acyclic isoprenoids, mainly pristane, phytane and, in some cases, farnesane, sesquiterpanes, tri- and tetracyclic diterpanes, tri- and pentacyclic triterpanes, and steranes, polycyclic aromatic hydrocarbons (mostly with two- to five rings, rarely six rings), and phenols. The compounds formed change during the heating history. The fact that phenols are found in dumps where heating has not yet been completed, but are absent in those where heating ceased previously suggests the presence of water washing. The organic compounds formed may migrate within the dumps. However, when they migrate out of the dumps, they become a hazard to environment.This paper is a review on transformations of organic matter (both maceral composition and reflectance and chemical composition) in coal wastes deposited in coal waste dumps. Immediately after deposition the wastes are exposed to weathering conditions and sometimes undergo self heating processes.     

Early Carboniferous (Viséan) emplacement of the collisional Kłodzko–Złoty Stok granitoids (Sudetes, SW Poland): constraints from geochemical data and zircon U–Pb ages

Sensitive high-resolution ion microprobe zircon U–Pb dating and geochemical data of igneous rocks from the composite K?odzko–Z?oty Stok (KZS) Granite Pluton, Sudetic Block, indicate that the granitoids represent an Early Carboniferous Viséan phase of Variscan metaluminous, high-K, I-type, syn-collisional granite magmatism within the Saxothuringian Zone of the Central European Variscides. Igneous zircon records hypabyssal magmatism that produced various granitoids and lamprophyre (spessartite) emplaced from ca. 340 to 331 Ma. The KZS granitoids have compositions ranging from granodiorite to monzonite, low A/CNK ratios (<1), and are associated with abundant mafic members. Most of them are alkaline, highly potassic, and moderately evolved. The major and trace element contents of the KZS granitoids suggest geochemical heterogeneity, and the hybrid nature of magmas derived from a range of sources in the middle crust, with a strong input of material from the upper mantle. Mixing of magmas of mantle origin with high-K material from partly melted continental crust was probably a more important factor than fractional crystallization, in controlling the evolution of the magmas. The mean Pb–U ages of the main population of igneous zircon from a quartz monzodiorite (?elazno) and hornblende monzonite (Droszków) are 340.2 ± 2.5 Ma and 339.5 ± 3.1 Ma, respectively. A slightly younger biotite-hornblende granodiorite from Chwalis?aw, 336.7 ± 2.5 Ma, was cut by a spessartite dyke at 333.1 ± 3.1 Ma. This indicates that mafic magmas were immediately intruded into fractured, probably incompletely solidified, granodiorites. The lamprophyric dyke also contains igneous zircon of Neoproterozoic age, 566.3 ± 6.4 Ma, typical of the crust in the Saxothuringian Zone. Tonalite from Ptasznik Hill near Droszków is of similar age to the spessartite, 331.5 ± 2.6 Ma. High REE contents in the tonalite and its igneous zircon indicate advanced differentiation of granitic magma, producing a more leucocratic melt associated with post-magmatic activity including abundant late crosscutting pegmatites and quartz veins, and contact metasomatic mineralization. The KZS granitoids have rather similar petrographic and geochemical characteristics to granitoids from other parts of the Central European Variscides, where a thickened orogenic root caused a substantial rise in crustal temperatures, producing granitoid magmas closely correlated with regional tectonic activity between the Saxothuringian and Brunovistulia Terranes at the NE margin of the Bohemian Massif.     

Systematic Methodology for Velocity-dependent Gravity Modelling of Density Crustal Cross-Sections, using an Optimization Procedure

The paper describes a new method of gravity modelling of the density cross section along a DSS profile. We propose a systematic procedure of gravity interpretation using structural information contained both in the velocity distribution of the seismic model and the geometry of its layers. The procedure is based on the optimisation of the density parameters of the model. The values of the parameters are limited by relationships between the seismic velocity and the density (optimisation with inequalities). The formulation of the method allows for discussion of the presence of isostasy and the distribution of compensating masses. The discussion is very important for the considered crust-lithosphere system. The presented calculations are done for one Carpathian profile (CEL01). The analysis of the properties of the fitting procedure provides the characteristic depth of subcrustal compensating density structures, the position of crucial tectonic boundaries along the profiles, locations of the crustal areas having exceptional lithology, the regional density differences of subcrustal matter and the estimation of regional deviations from the isostatic equilibrium.     

Meltwater discharge through the subglacial bed and its land‐forming consequences from numerical experiments in the Polish lowland during the last glaciation

Numerical experiments suggest that the last glaciation severely affected the upper lithosphere groundwater system in NW Poland: primarily its flow pattern, velocities and fluxes. We have simulated subglacial groundwater flow in two and three spatial dimensions using finite difference codes for steady‐state and transient conditions. The results show how profoundly the ice sheet modifies groundwater pressure heads beneath and some distance beyond the ice margin. All model runs show water discharge at the ice forefield driven by ice‐sheet‐thickness‐modulated, down‐ice‐decreasing hydraulic heads. In relation to non‐glacial times, the transient 3D model shows significant changes in the groundwater flow directions in a regionally extensive aquifer ca. 90 m below the ice–bed interface and up to 40 km in front of the glacier. Comparison with empirical data suggests that, depending on the model run, only between 5 and 24% of the meltwater formed at the ice sole drained through the bed as groundwater. This is consistent with field observations documenting abundant occurrence of tunnel valleys, indicating that the remaining portion of basal meltwater was evacuated through a channelized subglacial drainage system. Groundwater flow simulation suggests that in areas of very low hydraulic conductivity and adverse subglacial slopes water ponding at the ice sole was likely. In these areas the relief shows distinct palaeo‐ice lobes, indicating fast ice flow, possibly triggered by the undrained water at the ice–bed interface. Owing to the abundance of low‐permeability strata in the bed, the simulated groundwater flow depth is less than ca. 200 m. Copyright © 2009 John Wiley & Sons, Ltd.     

Comparison of source parameters estimated in the frequency and time domains for seismic events at the Rudna copper mine,Poland

Source parameters estimated in the frequency domain for 100 selected seismic events from the Rudna copper mine, with moment magnitude ranging from 1.4 to 3.6, were collected to study their scaling relations and to compare them with the parameters estimated in the time domain. The apparent stress and static stress drop, corrected for the limited bandwidth recording, increase slightly in a similar manner with increasing seismic moment. The ratio of apparent stress to static stress drop, a measure of radiation efficiency, is practically constant and its mean value is close to 0.1. For 37 seismic events, with moment magnitude between 1.9 and 3.4, source parameters were estimated in the time domain from relative source time functions, that displayed unilateral rupture propagation, and their rupture velocity could be estimated. It ranges from 0.23 to 0.80 of shear wave velocity and is almost independent of seismic moment. The fault length, estimated from the average source pulse width and rupture velocity, is clearly dependent on seismic moment and is smaller than the source radius estimated from the corner frequency on the average by about 25 percent. There is no correlation between the values of static stress drop estimated in the frequency and time domains, but the time domain stress drop is in general similar to that estimated in the frequency domain. The apparent stress increases with increasing rupture velocity, and the ratio of apparent stress to static stress drop seems also to depend on rupture velocity.     

A high‐resolution Lateglacial and Holocene palaeoceanographic record from the Greenland Sea

We present an unprecedented multicentennial sediment record from the foot of Vesterisbanken Seamount, central Greenland Sea, covering the past 22.3 thousand years (ka). Based on planktic foraminiferal total abundances, species assemblages, and stable oxygen and carbon isotopes, the palaeoenvironments in this region of modern deepwater renewal were reconstructed. Results show that during the Last Glacial Maximum the area was affected by harsh polar conditions with only episodic improvements during warm summer seasons. Since 18 ka extreme freshwater discharges from nearby sources occurred, influencing the surface water environment. The last major freshwater event took place during the Younger Dryas. The onset of the Holocene was characterized by an improvement of environmental conditions suggesting warming and increasing ventilation of the upper water layers. The early Holocene saw a stronger Atlantic waters advection to the area, which began around 10.5 and ended quite rapidly at 5.5 ka, followed by the onset of Neoglacial cooling. Surface water ventilation reached a maximum in the middle Holocene. Around 3 ka the surface water stratification increased leading to subsequent amplification of the warming induced the North Atlantic Oscillation at 2 ka.     

Deglacial to postglacial palaeoenvironments of the Celtic Sea: lacustrine conditions versus a continuous marine sequence

Recent work on the last glaciation of the British Isles has led to an improved understanding of the nature and timing of the retreat of the British?Irish Ice Sheet (BIIS) from its southern maximum (Isles of Scilly), northwards into the Celtic and Irish seas. However, the nature of the deglacial environments across the Celtic Sea shelf, the extent of subaerial exposure and the existence (or otherwise) of a contiguous terrestrial linkage between Britain and Ireland following ice retreat remains ambiguous. Multiproxy research, based on analysis of 12 BGS vibrocores from the Celtic Deep Basin (CDB), seeks to address these issues. CDB cores exhibit a shell‐rich upward fining sequence of Holocene marine sand above an erosional contact cut in laminated muds with infrequent lonestones. Molluscs, in situ Foraminifera and marine diatoms are absent from the basal muds, but rare damaged freshwater diatoms and foraminiferal linings occur. Dinoflagellate cysts and other non‐pollen palynomorphs evidence diverse, environmentally incompatible floras with temperate, boreal and Arctic glaciomarine taxa co‐occurring. Such multiproxy records can be interpreted as representing a retreating ice margin, with reworking of marine sediments into a lacustrine basin. Equally, the same record may be interpreted as recording similar conditions within a semi‐enclosed marine embayment dominated by meltwater export and deposition of reworked microfossils. As assemblages from these cores contrast markedly with proven glaciomarine sequences from outside the CDB, a glaciolacustrine interpretation is favoured for the laminated sequence, truncated by a Late Weichselian transgressive sequence fining upwards into fully marine conditions. Reworked rare intertidal molluscs from immediately above the regional unconformity provide a minimum date c. 13.9 cal. ka BP for commencement of widespread marine erosion. Although suggestive of glaciolacustrine conditions, the exact nature and timing of laminated sediment deposition within the CDB, and the implications this has on (pen)insularity of Ireland following deglaciation, remain elusive.     

Flood‐plain responses to contemporary climate change in small High‐Arctic basins (Svalbard,Norway)

Changes in the supply of water and sediment to high‐latitude rivers related to contemporary climate change and glacier fluctuations largely determine the activity of fluvial processes. This study reconstructs fluvial dynamics since the end of the Little Ice Age (LIA) in two small, partially glaciated basins in the southern part of Spitsbergen, Svalbard Archipelago. We use a combination of aerial photograph interpretation, field mapping and dendrochronological analysis. Sequences of abandoned channels and glacifluvial terraces are distinctly visible in middle and lower parts of the Brattegg and Arie basins in this area. The advance of glaciers during the LIA in the upper part of the basins led to the development of a braiding pattern and to channel aggradation corresponding to the highest glacifluvial levels. The decreasing activity of these braidplains occurred at the turn of the 19th and 20th centuries, immediately prior to a significant incision period. A second generation of braided channels developed during the first half of the 20th century. Ice‐marginal lake development, less input of fine‐grained sediment to the river channel, and fast incision began from the second half of the 20th century onward. During the last two decades, the main fluvial response to the climatic warming has been contraction of flow within a narrower channel and the abandonment of braidplains. The increased lateral erosion and rate of downcutting and the formation of the most downstream reaches of the modern valley bottom occurred in the 1980s and 1990s. This process was intensified under flood conditions generated by extreme rainfall events. These micro‐scale (small partially glaciated basins) observations concerning the changes of the activity of fluvial processes since the end of LIA may be helpful for the reconstruction of past fluvial changes over longer time scales.     

High‐precision U–Pb age and duration of the latest Devonian (Famennian) Hangenberg event,and its implications

Precise U–Pb zircon dates from three volcanic ash beds that bracket the Hangenberg Shale in the Holy Cross Mountains, Poland, constrain the age and duration of one of the most significant palaeobiological events of the Palaeozoic Era, the Hangenberg Event. It is linked to a terminal Devonian global shift from greenhouse to icehouse climate conditions, a global transgression, and widespread black shale deposition. Our results constrain the Hangenberg Event to between 358.97 ± 0.11 Ma and 358.89 ± 0.20 Ma, with a calculated duration of 0.05 +0.14/?0.05 Ma. A third, underlying ash bed yielded a distinctly older age of 359.97 ± 0.46 Ma. The duration of ~50–100 ka. for the event is comparable to those of Quaternary glaciations, and is consistent with both a glacio‐eustatic origin for the eustatic fluctuations and changes in ocean chemistry that led to this major reorganization of the biosphere.