Cyclical salt efflorescence weathering: an invisible threat to the recovery of underground mine environment for tourist exploitation

Enhancing the value of an underground mine environment for tourist exploitation involves altering the physico-chemical balance of stone materials whose original mechanical properties guaranteed the structural stability of the site’s galleries and chambers. Humidity and temperature changes caused by the public exhibition of this kind of assets are the main causes of such disorders. After the intervention in the Agrupa-Vicenta mine in La Union (Spain) there were still runoff-water leaks into the mine. These water runoffs through the fault and schistosity planes of the enclosing rock mass give rise to salt precipitation over time. Adapting this mine and turning it into a museum have meant a decrease in relative indoors humidity and an increase in temperature. These variations have caused rocks, which were stable in the original conditions, to increase their rate of physico-chemical weathering due to the polycyclic supergene alteration of the metal sulfides they contain. The resulting release of sulfates into the solution and their subsequent precipitation as single and double salt efflorescence causes haloclasty, deteriorating the rock’s mechanical properties and diminishing the structural stability of the operation. This paper presents the results of characterizing the supergene mineral phases of salt efflorescence in the rock bed enclosing an underground sulfide mine value enhanced for tourist exploitation. Dangers for the structural stability of this type of architectural intervention, associated to the formation of efflorescences, are also identified; these efflorescences are caused by the weathering of rocks that make up its supporting structure.     

Climate changes and human activities recorded in the sediments of Lake Estanya (NE Spain) during the Medieval Warm Period and Little Ice Age

A multi-proxy study of short sediment cores recovered in small, karstic Lake Estanya (42°02?? N, 0°32?? E, 670 m.a.s.l.) in the Pre-Pyrenean Ranges (NE Spain) provides a detailed record of the complex environmental, hydrological and anthropogenic interactions occurring in the area since medieval times. The integration of sedimentary facies, elemental and isotopic geochemistry, and biological proxies (diatoms, chironomids and pollen), together with a robust chronological control, provided by AMS radiocarbon dating and ²¹⁰Pb and ¹³⁷Cs radiometric techniques, enabled precise reconstruction of the main phases of environmental change, associated with the Medieval Warm Period (MWP), the Little Ice Age (LIA) and the industrial era. Shallow lake levels and saline conditions with poor development of littoral environments prevailed during medieval times (1150?C1300 AD). Generally higher water levels and more dilute waters occurred during the LIA (1300?C1850 AD), although this period shows a complex internal paleohydrological structure and is contemporaneous with a gradual increase of farming activity. Maximum lake levels and flooding of the current littoral shelf occurred during the nineteenth century, coinciding with the maximum expansion of agriculture in the area and prior to the last cold phase of the LIA. Finally, declining lake levels during the twentieth century, coinciding with a decrease in human pressure, are associated with warmer climate conditions. A strong link with solar irradiance is suggested by the coherence between periods of more positive water balance and phases of reduced solar activity. Changes in winter precipitation and dominance of NAO negative phases would be responsible for wet LIA conditions in western Mediterranean regions. The main environmental stages recorded in Lake Estanya are consistent with Western Mediterranean continental records, and show similarities with both Central and NE Iberian reconstructions, reflecting a strong climatic control of the hydrological and anthropogenic changes during the last 800 years.     

UAV RGB,thermal infrared and multispectral imagery used to investigate the control of terrain on the spatial distribution of dryland biocrust

Biocrusts (topsoil communities formed by mosses, lichens, bacteria, fungi, algae, and cyanobacteria) are a key biotic component of dryland ecosystems. Whilst climate patterns control the distribution of biocrusts in drylands worldwide, terrain and soil attributes can influence biocrust distribution at landscape scale. Multi-source unmanned aerial vehicle (UAV) imagery was used to map and study biocrust ecology in a typical dryland ecosystem in central Spain. Red, green and blue (RGB) imagery was processed using structure-from-motion techniques to map terrain attributes related to microclimate and terrain stability. Multispectral imagery was used to produce accurate maps (accuracy > 80%) of dryland ecosystem components (vegetation, bare soil and biocrust composition). Finally, thermal infrared (TIR) and multispectral imagery was used to calculate the apparent thermal inertia (ATI) of soil and to evaluate how ATI was related to soil moisture (r² = 0.83). The relationship between soil properties and UAV-derived variables was first evaluated at the field plot level. Then, the maps obtained were used to explore the relationship between biocrusts and terrain attributes at ecosystem level through a redundancy analysis. The most significant variables that explain biocrust distribution are: ATI (34.4% of variance, F = 130.75; p < 0.001), Elevation (25.8%, F = 97.6; p < 0.001), and potential solar incoming radiation (PSIR) (52.9%, F = 200.1; p < 0.001). Differences were found between areas dominated by lichens and mosses. Lichen-dominated biocrusts were associated with areas with high slopes and low values of ATI, with soil characterized by a higher amount of soluble salts, and lower amount of organic carbon, total phosphorus (P_tot) and total nitrogen (N_tot). Biocrust-forming mosses dominated lower and moister areas, characterized by gentler slopes and higher values of ATI with soils with higher contents of organic carbon, P_tot and N_tot. This study shows the potential to use UAVs to improve our understanding of drylands and to evaluate the control that the terrain has on biocrust distribution.     

Integrating Hydrogeological and Geophysical Methods for the Characterization of a Deltaic Aquifer System

Groundwater management needs detailed aquifer characterization, especially in semiarid costal aquifer systems that are under hydrological pressure. Our study area is in the Tordera delta, northeastern coast of Spain, where a detrital fluvio-deltaic aquifer system has been developed above granitic basement. The main purpose of this study is to characterize the complex lithological structure and the seawater intrusion state by combining hydrological information, audiomagnetotelluric (AMT) and seismic reflection and refraction models. This allowed us to provide spatially continuous information about aquifer properties and processes. Thus, we have determined the thickness and continuity of the aquifer units, as well as the morphology and depth to the basement. The models revealed that the main seawater intrusion main path is found in the western deltaic area that coincides with an existing buried paleochannel. This new result explains the anomalously high chlorine concentrations observed in the deep semiconfined aquifer more than 1,500 m inland.     

Social networks and trade of services: modelling interregional flows with spatial and network autocorrelation effects

Recent literature on border effect has fostered research on informal barriers to trade and the role played by network dependencies. In relation to social networks, it has been shown that intensity of trade in goods is positively correlated with migration flows between pairs of countries/regions. In this article, we investigate whether such a relation also holds for interregional trade of services. We also consider whether interregional trade flows in services linked with tourism exhibit spatial and/or social network dependence. Conventional empirical gravity models assume the magnitude of bilateral flows between regions is independent of flows to/from regions located nearby in space, or flows to/from regions related through social/cultural/ethic network connections. With this aim, we provide estimates from a set of gravity models showing evidence of statistically significant spatial and network (demographic) dependence in the bilateral flows of the trade of services considered. The analysis has been applied to the Spanish intra- and interregional monetary flows of services from the accommodation, restaurants and travel agencies for the period 2000–2009, using alternative datasets for the migration stocks and definitions of network effects.     

Zone design of specific sizes using adaptive additively weighted Voronoi diagrams

Territory or zone design processes entail partitioning a geographic space, organized as a set of areal units, into different regions or zones according to a specific set of criteria that are dependent on the application context. In most cases, the aim is to create zones of approximately equal sizes (zones with equal numbers of inhabitants, same average sales, etc.). However, some of the new applications that have emerged, particularly in the context of sustainable development policies, are aimed at defining zones of a predetermined, though not necessarily similar, size. In addition, the zones should be built around a given set of seeds. This type of partitioning has not been sufficiently researched; therefore, there are no known approaches for automated zone delimitation. This study proposes a new method based on a discrete version of the adaptive additively weighted Voronoi diagram that makes it possible to partition a two-dimensional space into zones of specific sizes, taking both the position and the weight of each seed into account. The method consists of repeatedly solving a traditional additively weighted Voronoi diagram, so that each seed's weight is updated at every iteration. The zones are geographically connected using a metric based on the shortest path. Tests conducted on the extensive farming system of three municipalities in Castile-La Mancha (Spain) have established that the proposed heuristic procedure is valid for solving this type of partitioning problem. Nevertheless, these tests confirmed that the given seed position determines the spatial configuration the method must solve and this may have a great impact on the resulting partition.     

Evidences for multiple remagnetization of Proterozoic dykes from Iguerda inlier (Anti-Atlas Belt,Southern Morocco)

No paleomagnetic data exist for Paleo-Mesoproterozoic times of the West African Craton (WAC). Therefore, paleogeographic reconstructions for such old geological times are difficult to constrain. Gaps on the sedimentary record and intense remagnetizations are the major problems that paleomagnetic studies come across. Recent geochronological results for dyke swarms that intrude several Proterozoic inliers of WAC in the Anti-Atlas Belt (southern Morocco) revealed ages between Paleoproterozoic and early Neoproterozoic, opening for the first time a window of opportunity to conduct paleomagnetic studies and tentatively infer about the paleoposition of WAC during Proterozoic. On this scope we conducted a paleomagnetic study on seven Proterozoic dykes of the Iguerda inlier. The meaning of the obtained paleomagnetic directions was evaluated by rock magnetic and mineral analyses, complemented by petrographic observations. Our samples record the presence of a complex history of remagnetization, mostly assigned to several Phanerozoic thermal/chemical events, in particular to the late stages of Pan African orogeny (s.l.), to the Late Carboniferous Variscan orogeny, and even to more recent events. The recognized remagnetization processes are related to widespread metamorphic events under greenschist facies followed by low-temperature oxidation, both responsible for the formation of new magnetic phases, like magnetite and hematite. These events obliterated the primary (magmatic) thermo-remanent magnetization and promoted multiple remagnetizations of the dykes, thermally and chemically. For only one dyke the presence of primary magnetization is possible to infer, though not to confirm, and would place WAC at an equatorial position around 1750 Ma.     

The spatial distribution of galaxies within the cosmic microwave background cold spot in the Corona Borealis supercluster

We study the spatial distribution and colours of galaxies within the region covered by the cold spot in the cosmic microwave background recently detected by the Very Small Array interpherometer (VSA) towards the Corona Borealis supercluster (CrB-SC). The spot is in the northern part of a region with a radius  ∼1° (∼5 Mpc  at the redshift of CrB-SC) enclosing the clusters Abell 2056, 2065, 2059 and 2073, and where the density of galaxies, excluding the contribution from those clusters, is approximately two times higher than the mean value in typical intercluster regions of the CrB-SC. Two of such clusters (Abell 2056 and 2065) are members of the CrB-SC, while the other two are in the background. This high-density intercluster region is quite inhomogeneous, being the most remarkable feature a large concentration of galaxies in a narrow filament running from Abell 2065 with a length of ∼35 arcmin (  ∼3 Mpc  at the redshift of CrB-SC) in the SW–NE direction. This intercluster population of galaxies probably results from the interaction of clusters Abell 2065 and 2056. The area subtended by the VSA cold spot shows an excess of faint  (21 < r < 22)  and red  (1.1 < r − i < 1.3)  galaxies as compared with typical values within the CrB-SC intercluster regions. This overdensity of galaxies shows a radial dependence and extends out to ∼15 arcmin. This could be the signature of a previously unnoted cluster in the background.