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61.
Boubacar KANE Pierre Y. JULIEN 《国际泥沙研究》2007,22(2):114-119
An extensive database of reservoir sedimentation surveys throughout continental United States is compiled and analyzed to determine specific degradation SD relationships as function of mean annual rainfall R, drainage area A, and watershed slope S. The database contains 1463 field measurements and specific degradation relationships are defined as function of A, R and S. Weak trends and significant variability in the data are noticeable. Specific degradation measurements are log normally distributed with respect to R, A, and S and 95% confidence intervals are determined accordingly. The accuracy of the predictions does not significantly increase as more independent variables are added to the regression analyses. 相似文献
62.
Innovative Germicidal UV and Photocatalytic System Dedicated to Aircraft Cabin Eliminates Volatile Organic Compounds and Pathogenic Micro‐Organisms 下载免费PDF全文
63.
Osmium-strontium-neodymium-lead isotopic covariations in mid-ocean ridge basalt glasses and the heterogeneity of the upper mantle 总被引:4,自引:0,他引:4
Pierre Schiano Jean-Louis Birck Claude J. Allgre 《Earth and Planetary Science Letters》1997,150(3-4):363-379
Osmium, strontium, neodymium, and lead isotopic data have been obtained for 30 hand picked samples of basaltic glass from the Pacific, Atlantic and Indian mid-oceanic ridges. Large variations in Os isotopic ratios exist in the glasses, from abyssal peridotite-like values to radiogenic compositions similar to oceanic island basalts (187Os/186Os and 187Os/188Os ratios range from 1.06 to 1.36 and from 0.128 to 0.163, respectively). Os isotopic and elemental data suggest the existence of mixing correlations. This relationship might be ascribed to secondary contamination processes; however, such a hypothesis cannot account for the negative correlation observed between Os and Nd isotopes and the existence of complementary covariations between Os and SrPb isotopes. In this case, OsSrNdPb isotopic variations are unrelated to late post-eruption or shallow level contamination. These relationships provide strong evidence that the Os isotopic composition of the samples are derived from the mantle and thus implies a global chemical heterogeneity of the oceanic upper mantle. The results are consistent with the presence of recycled oceanic crust in the mantle sources of mid-ocean ridge basalts, and indicate that the unique composition of the upper mantle below the Indian ocean results from its contamination by a mantle component characterized by radiogenic Os and particularly unradiogenic Nd and Pb isotopic compositions. 相似文献
64.
The application of trichloroacetic acid (TCA) as a shell extractant for preparation of soft body parts with reference to tissue metal concentrations (Cd, Cu, Pb, Zn) in shellfish has been evaluated on the example of the mud snail Hydrobia ulvae, a small marine prosobranch densely present in rocky and soft-bottom habitats of the eastern Atlantic. A solution of 0.1 M TCA was tested on individuals treated according to two different protocols: (1) thawed after freezing ("non-dried") and (2) thawed and air-dried to a constant weight ("dried"). Two points were investigated in detail to improve the method: individual soft tissue dry weight and tissue metal concentration following a standard digestion method. In both instances, the results were compared with those from manually dissected snails. Conditions for total shell decalcification of 60 individuals (3-4 mm long) were 5.5 h in 20 ml of 0.1 M TCA.No differences in individual soft tissue weight were observed between the treatments, indicating good efficiency of the TCA extraction with respect to weight of soft body parts. In contrast, tissue metal concentrations varied among treatments. The TCA extraction of the dried animals had a good recovery for Cd, most likely due to the lower solubility of Cd vital cellular components (proteins and mineral concretions) from the dried tissue. Satisfactory recoveries of the tissue concentrations of Cu and Pb were obtained for the non-dried individuals. This might be related to the specific distribution of metals in the organism (namely in the digestive glands and gonads) and their different chemical reactivity with TCA after the tissue was dried. Limited susceptibility of Zn-bearing protein bindings to complexing with TCA also accounts for significantly lower concentrations of Zn in the mud snail's soft tissue that was extracted. The 0.1 M TCA solution is therefore recommended for extraction of the shells of Hydrobia ulvae for tissue determination of Cd, Cu and Pb; however the treatment protocol does affect metal recovery and thus a consistent procedure should be followed.The extracted metals from the soft tissues and shells of the mud snails (on the basis of both metal concentrations and contents) were ranked in order of increasing contribution of soft body parts to the total (shell+tissue): Pb相似文献
65.
66.
Our understanding on how ash particles in volcanic plumes react with coexisting gases and aerosols is still rudimentary, despite the importance of these reactions in influencing the chemistry and dynamics of a plume. In this study, six samples of fine ash (<100 m) from different volcanoes were measured for their specific surface area, as, porosity and water adsorption properties with the aim to provide insights into the capacity of silicate ash particles to react with gases, including water vapour. To do so, we performed high-resolution nitrogen and water vapour adsorption/desorption experiments at 77 K and 303 K, respectively. The nitrogen data indicated as values in the range 1.1–2.1 m2/g, except in one case where a as of 10 m2/g was measured. This high value is attributed to incorporation of hydrothermal phases, such as clay minerals, in the ash surface composition. The data also revealed that the ash samples are essentially non-porous, or have a porosity dominated by macropores with widths >500 Å. All the specimens had similar pore size distributions, with a small peak centered around 50 Å. These findings suggest that fine ash particles have relatively undifferentiated surface textures, irrespective of the chemical composition and eruption type. Adsorption isotherms for water vapour revealed that the capacity of the ash samples for water adsorption is systematically larger than predicted from the nitrogen adsorption as values. Enhanced reactivity of the ash surface towards water may result from (i) hydration of bulk ash constituents; (ii) hydration of surface compounds; and/or (iii) hydroxylation of the surface of the ash. The later mechanism may lead to irreversible retention of water. Based on these experiments, we predict that volcanic ash is covered by a complete monolayer of water under ambient atmospheric conditions. In addition, capillary condensation within ash pores should allow for deposition of condensed water on to ash particles before water reaches saturation in the plume. The total mass of water vapour retained by 1 g of fine ash at 0.95 relative water vapour pressure is calculated to be ~10–2 g. Some volcanic implications of this study are discussed.Editorial responsibility: J. Gilbert 相似文献
67.
The present field study uses Spongia officinalis for assessing trace metals occurrence in time and space within Mediterranean rocky communities. Nine sites were selected in the Marseille area for studying spatial trends in 12 metal concentrations. Long term changes in 8 metal concentrations were assessed at sites that had been sampled before and 12 years after the opening of a treatment plant. Spongia officinalis highly concentrated all the trace metal surveyed excepted Hg and Cd. The overall contamination level registered provided a classification of the study sites which is congruent with that given by other studies on pollutant accumulation in neighbouring sandy-bottoms or benthic assemblages. Among the metals studied, Fe, Pb, Cr are those that best highlighted a pollution gradient. In the present study, only Cd concentration did not vary in space. Except for Ni, all pollutant concentrations clearly decreased between 1984 and 1999. This very impressive decrease in heavy metal concentrations within the Marseille area represents an indisputable evidence of the improvement of the seawater quality resulting from 12 years' operation of the Marseille sewage plant. Moreover, the significant decrease also recorded in the reference population at Port-Cros might reflect an overall improvement in the seawater quality of the NW Mediterranean. 相似文献
68.
Adam Carter Benjamin van Wyk de Vries Karim Kelfoun Patrick Bachèlery Pierre Briole 《Bulletin of Volcanology》2007,69(7):741-756
A clear model of structures and associated stress fields of a volcano can provide a framework in which to study and monitor
activity. We propose a volcano-tectonic model for the dynamics of the summit of Piton de la Fournaise (La Reunion Island,
Indian Ocean). The summit contains two main pit crater structures (Dolomieu and Bory), two active rift zones, and a slumping
eastern sector, all of which contribute to the actual fracture system. Dolomieu has developed over 100 years by sudden large
collapse events and subsequent smaller drops that include terrace formation. Small intra-pit collapse scars and eruptive fissures
are located along the southern floor of Dolomieu. The western pit wall of Dolomieu has a superficial inward dipping normal
fault boundary connected to a deeper ring fault system. Outside Dolomieu, an oval extension zone containing sub-parallel pit-related
fractures extends to a maximum distance of 225 m from the pit. At the summit the main trend for eruptive fissures is N80°,
normal to the north–south rift zone. The terraced structure of Dolomieu has been reproduced by analogue models with a roof
to width ratio of approximately 1, suggesting an original magma chamber depth of about 1 km. Such a chamber may continue to
act as a storage location today. The east flank has a convex–concave profile and is bounded by strike-slip fractures that
define a gravity slump. This zone is bound to the north by strike-slip fractures that may delineate a shear zone. The southern
reciprocal shear zone is probably marked by an alignment of large scoria cones and is hidden by recent aa lavas. The slump
head intersects Dolomieu pit and may slide on a hydrothermally altered layer known to be located at a depth of around 300 m.
Our model has the summit activity controlled by the pit crater collapse structure, not the rifts. The rifts become important
on the mid-flanks of the cone, away from pit-related fractures. On the east flank the superficial structures are controlled
by the slump. We suggest that during pit subsidence intra-pit eruptions may occur. During tumescence, however, the pit system
may become blocked and a flank eruption is more likely. Intrusions along the rift may cause deformation that subsequently
increases the slump’s potential to deform. Conversely, slumping may influence the east flank stress distribution and locally
control intrusion direction. These predictions can be tested with monitoring data to validate the model and, eventually, improve
monitoring. 相似文献
69.
Michel Westphal Evgueni L. Gurevitch Boris V. Samsonov Hugues Feinberg & Jean Pierre Pozzi 《Geophysical Journal International》1998,134(1):254-266
The deep drill hole SG6 in western Siberia (66°N, 78.5°E) penetrated 1.1 km of lower Triassic basalts, which are possibly an extension of the central Siberian Permo– Triassic flood basalt province. About 300 samples of these basalts were progressively demagnetized and measured. Principal component analysis often shows multiple magnetizations carried by haematite and magnetite. The corrected mean inclinations are +77° and −77° for the haematite component. A magnetostratigraphic scale was derived and showed a N–R–N–R–N succession. This is quite different from the Noril'sk and Taimyr typical polarity scale, R–N.
The basalts found in the SG6 deep drill hole are slightly younger than those of central Siberia and Taimyr. They correspond to middle–upper Induan age, whereas the Noril'sk and Taimyr sections correspond to an uppermost Permian and lower Induan age. Altogether they indicate that, after a high output rate of volcanic material near the Permo–Triassic boundary, this activity slowed down drastically on the Siberian platform and Taimyr, but persisted for several million years in western Siberia. 相似文献
The basalts found in the SG6 deep drill hole are slightly younger than those of central Siberia and Taimyr. They correspond to middle–upper Induan age, whereas the Noril'sk and Taimyr sections correspond to an uppermost Permian and lower Induan age. Altogether they indicate that, after a high output rate of volcanic material near the Permo–Triassic boundary, this activity slowed down drastically on the Siberian platform and Taimyr, but persisted for several million years in western Siberia. 相似文献
70.
Chantal Guillard Hervé Delprat Can Hoang-van Pierre Pichat 《Journal of Atmospheric Chemistry》1993,16(1):47-59
The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO2, Fe2O3, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO2 (mainly anatase, nonporous, 50 m2 g–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm–2 h–1 (>340 nm, radiant fluxca. 22 mW cm–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O2. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO2, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe2O3. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO2. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed. 相似文献