Wetlands and low-gradient topography are associated with longer hydrologic transit times in Precambrian Shield headwater catchments

The estimation of hydrologic transit times in a catchment provides insights into the integrated effects of water storage, mixing dynamics, and runoff generation processes. There has been limited effort to estimate transit times in southern boreal Precambrian Shield landscapes, which are characteristically heterogeneous with surface cover including till, thin soils, bedrock outcrops, and depressional wetland features that play contrasting hydrologic roles. This study presents approximately 3.5 years of precipitation and streamflow water isotope data and estimates mean transit times (MTTs) and the young water fraction (p_y) across six small catchments in the Muskoka-Haliburton region of south-central Ontario. The main objectives were to define a typical range of MTTs for headwater catchments in this region and to identify landscape variables that best explain differences in MTTs/p_y using airborne light detection and ranging and digital terrain analysis. Of the transit time distributions, the two parallel linear reservoir and gamma distributions best describe the hydrology of these catchments, particularly because of their ability to capture more extreme changes related to events such as snowmelt. The estimated MTTs, regardless of the modelling approach or distribution used, are positively associated with the percent wetland area and negatively with mean slope in the catchments. In this landscape, low-gradient features such as wetlands increase catchment scale water storage when antecedent conditions are dryer and decrease transit times when there is a moisture surplus, which plausibly explains the increases in MTTs and mean annual runoff from catchments with significant coverage of these landscape features.     

Changes in dissolved organic matter (DOM) amount and composition along nested headwater stream locations during baseflow and stormflow

Amount and composition of dissolved organic matter (DOM) were evaluated for multiple, nested stream locations in a forested watershed to investigate the role of hydrologic flow paths, wetlands and drainage scale. Sampling was performed over a 4‐year period (2008–2011) for five locations with drainage areas of 0.62, 3.5, 4.5, 12 and 79 ha. Hydrologic flow paths were characterized using an end‐member mixing model. DOM composition was determined using a suite of spectrofluorometric indices and a site‐specific parallel factor analysis model. Dissolved organic carbon (DOC), humic‐like DOM and fluorescence index were most sensitive to changes with drainage scale, whereas dissolved organic nitrogen, specific UV absorbance, Sr and protein‐like DOM were least sensitive. DOM concentrations and humic‐like DOM constituents were highest during both baseflow and stormflow for a 3.5‐ha catchment with a wetland near the catchment outlet. Whereas storm‐event concentrations of DOC and humic DOM constituents declined, the mass exports of DOC increased with increasing catchment scale. A pronounced dilution in storm‐event DOC concentration was observed at peak stream discharge for the 12‐ha drainage location, which was not as apparent at the 79‐ha scale, suggesting key differences in supply and transport of DOM. Our observations indicate that hydrologic flow paths, especially during storms, and the location and extent of wetlands in the catchment are key determinants of DOM concentration and composition. This study furthers our understanding of changes in DOM with drainage scale and the controls on DOM in headwater, forested catchments. Copyright © 2014 John Wiley & Sons, Ltd.     

Quantifying anthropogenic influence on recent near-surface temperature change

We assess the extent to which observed large-scale changes in near-surface temperatures over the latter half of the twentieth century can be attributed to anthropogenic climate change as simulated by a range of climate models. The hypothesis that observed changes are entirely due to internal climate variability is rejected at a high confidence level independent of the climate model used to simulate either the anthropogenic signal or the internal variability. Where the relevant simulations are available, we also consider the alternative hypothesis that observed changes are due entirely to natural external influences, including solar variability and explosive volcanic activity. We allow for the possibility that feedback processes, other than those simulated by the models considered, may be amplifying the observed response to these natural influences by an unknown amount. Even allowing for this possibility, the hypothesis of no anthropogenic influence can be rejected at the 5% level in almost all cases. The influence of anthropogenic greenhouse gases emerges as a substantial contributor to recent observed climate change, with the estimated trend attributable to greenhouse forcing similar in magnitude to the total observed warming over the 20th century. Much greater uncertainty remains in the response to other external influences on climate, particularly the response to anthropogenic sulphate aerosols and to solar and volcanic forcing. Our results remain dependent on model-simulated signal patterns and internal variability, and would benefit considerably from a wider range of simulations, particularly of the responses to natural external forcing.     

Quaternary volcanism and faulting at O’A caldera,central ethiopian rift

O’a is the largest of the Quaternary caldera volcanoes that punctuate the axis of the Ethiopian rift valley. The known volcanic history of O’a is brief: eruptions of restricted ash-flow tuffs and «tufolavas» were followed by extensive pumice deposition with intervening paleosols, lacustrine sediments, and flows of occasional welded tuffs and rare basalts. Ensuing caldera collapse at c. 0.24 m.y. ago was accompanied by emplacement of two massive ignimbrite flow units comprising a single cooling unit: the first was much more severely welded than the second which shows lahar characteristics. Post-caldera volcanism at O’a has been sparse compared with most other Ethiopian rift centres. O’a volcano exemplifies the common rift association of a caldera set tightly between two offset segments of the Wonji fault belt. The Wonji fault belt marks the youngest tectonism of the rift floor, and in the vicinity of O’a has been active in a major way since caldera subsidence. This faulting is clearly younger than the massive rift margin faulting, which to the northeast of O’a occurred during a tectonic climax dated at c. 1.0 m.y. ago. Radiometric analysis suggests a rather regular level of initial⁴⁰Ar in O’a basalt lavas sampled near to their original vents. If this level also applies to near-vent basalts dated from other parts of the Ethiopian rift, a regional rift paroxysm of crustal extension and related silicic and basaltic volcanism is evident at c. 0.30–0.20 m.y. ago. Episodic dilatation and associated volcano-tectonism separated by long periods of quiescence appears to be a general feature of continental rift valleys.     

Bacterial and Virus‐Like Particle Abundances in Purged and Unpurged Groundwater Depth Profiles

Bacteria and viruses are ubiquitous in subterranean aquatic habitats. Bacterial abundance is known to vary with depth in aquifers; however, whether viral abundance varies with depth is less well known. Here we use flow cytometry (FCM) to enumerate bacteria and virus‐like particles (VLP) from groundwater depth profiles. Groundwater samples were obtained from a set of nested piezometers from depths of 15, 30, 45, 60, 80, and 90 m and bacteria and VLP abundances were determined in purged aquifer water and unpurged water at each slot depth. Mean bacterial abundance (cells / mL) was not significantly different in unpurged water (3.2 × 10⁵) compared to purged water (1.4 × 10⁵); however, mean VLP abundance (particles / mL) was significantly greater in unpurged water (4.4 × 10⁵) compared to purged water (2.3 × 10⁵). Purged water was used to investigate the aquifer depth profile and bacterial and VLP abundances were observed to vary significantly between depths. The virus‐bacteria ratio was determined and was observed to steadily increase with depth. Overall, our data indicate the dynamic nature of bacterial and viral abundances in subsurface environments which should be considered when designing groundwater microbial sampling methodologies.