The lower paleolithic landscape of 'Ayoun Qedim,al‐Jafr Basin,Jordan

The 'Ayoun Qedim locality includes seven deflated Acheulian sites within and around a limestone box canyon, Juwit el Ghuweir, in the northern al‐Jafr Basin, Jordan. Survey of these sites identified dense scatters of Acheulian bifaces ( _ 1650) along with debris, cores, and reduction material from their production and maintenance. Although there is a clear Levallois component in the assemblages, reflecting a Late Acheulian occupation, strictly Middle and Upper Paleolithic sites are uncommon in this locality. Analysis of the geology and geomorphology of the northern al‐Jafr Basin indicates the area is strongly influenced by shallow subsurface groundwater flow and discharge, and Juwit el Ghuweir displays classic features of a canyon formed by groundwater seepage and sapping, except for the lack of a perennial spring within the modern canyon. The authors suggest that the extreme density of Lower Paleolithic material at 'Ayoun Qedim is associated with perennial groundwater discharge at Juwit el Ghuweir during the Middle Pleistocene and that the dearth of later Paleolithic material is attributable to the cessation of perennial spring discharge. The cause of the spring's cessation is unknown, but may have been related to local geomorphic factors, such as head migration of adjacent streams, or to more regional geomorphic factors, such as the lowering of theregional water table in the area of al‐Jafr Basin. © 2007 Wiley Periodicals, Inc.     

Incorporation of Non-Linear Effective Cross-Section Parameterizations into a Fast Photolysis Computation Code (Fast-J)

We have investigated several methods of incorporating laboratorymeasurements of effective cross-sections (quantum yield timesabsorption cross-section) that are non-linear functions oftemperature, pressure, and wavelength, into the Fast-J photolysis codeof Wild et al. (2000). The best method was found to beparameterization of the solar weighted effective cross-section usingthe form of the effective cross-section, with numerical fitting of theparameterization constants. Using this technique on the acetone dataof Gierczak et al. (1998) produces aparameterization which fits all points to within 1%. This methodshould also benefit other photolysis codes with large wavelength bins.     

Global Warming and Tropical Land-Use Change: Greenhouse Gas Emissions from Biomass Burning, Decomposition and Soils in Forest Conversion, Shifting Cultivation and Secondary Vegetation

Tropical forest conversion, shiftingcultivation and clearing of secondary vegetation makesignificant contributions to global emissions ofgreenhouse gases today, and have the potential forlarge additional emissions in future decades. Globally, an estimated 3.1×10⁹ t of biomasscarbon of these types is exposed to burning annually,of which 1.1×10⁹ t is emitted to the atmospherethrough combustion and 49×10⁶ t is converted tocharcoal (including 26–31×10⁶ t C of blackcarbon). The amount of biomass exposed to burningincludes aboveground remains that failed to burn ordecompose from clearing in previous years, andtherefore exceeds the 1.9×10⁹ t of abovegroundbiomass carbon cleared on average each year. Above-and belowground carbon emitted annually throughdecomposition processes totals 2.1×10⁹ t C. Atotal gross emission (including decomposition ofunburned aboveground biomass and of belowgroundbiomass) of 3.41×10⁹ t C year^-1 resultsfrom clearing primary (nonfallow) and secondary(fallow) vegetation in the tropics. Adjustment fortrace gas emissions using IPCC Second AssessmentReport 100-year integration global warming potentialsmakes this equivalent to 3.39×10⁹ t ofCO₂-equivalent carbon under a low trace gasscenario and 3.83×10⁹ t under a high trace gasscenario. Of these totals, 1.06×10⁹ t (31%)is the result of biomass burning under the low tracegas scenario and 1.50×10⁹ t (39%) under thehigh trace gas scenario. The net emissions from allclearing of natural vegetation and of secondaryforests (including both biomass and soil fluxes) is2.0×10⁹ t C, equivalent to 2.0–2.4×10⁹ t of CO₂-equivalent carbon. Adding emissions of0.4×10⁹ t C from land-use category changesother than deforestation brings the total for land-usechange (not considering uptake of intact forest,recurrent burning of savannas or fires in intactforests) to 2.4×10⁹ t C, equivalent to 2.4–2.9×10⁹ t of CO₂-equivalent carbon. The totalnet emission of carbon from the tropical land usesconsidered here (2.4×10⁹ t C year^-1)calculated for the 1981–1990 period is 50% higherthan the 1.6×10⁹ t C year^-1 value used by the Intergovernmental Panel on Climate Change. The inferred (= `missing') sink in the global carbonbudget is larger than previously thought. However,about half of the additional source suggested here maybe offset by a possible sink in uptake by Amazonianforests. Both alterations indicate that continueddeforestation would produce greater impact on globalcarbon emissions. The total net emission of carboncalculated here indicates a major global warmingimpact from tropical land uses, equivalent toapproximately 29% of the total anthropogenic emissionfrom fossil fuels and land-use change.     

Aussiedler migration and its impact on Braşov's ethnic German population and built environment

The expression of different ethnic identities in the landscape is a product of the creation, destruction and preservation of the built environment. This may illustrate the changing processes over the evolution of a landscape. In the case of Braşov, Romania, it is possible to see in the urban landscape a reflection of the changing nature of the relationship between the ethnic German and Romanian populations, and the German and Romanian governments. This paper will demonstrate the persistence of ethnic German culture in the built environment and social organisation of Braşov in spite of the exodus of the ethnic German population. This revised version was published online in July 2006 with corrections to the Cover Date.     

Determination of High Field Strength Elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g−1 Levels in Geological Reference Materials by Magnetic Sector ICP-MS after HF/HClO4 High Pressure Digestion

Six low abundance rock reference materials (basalt BIR-1, dunite DTS-1, dolerite DNC-1, peridotite PCC-1, serpentine UB-N and basalt TAFAHI) have been analysed for high field strength elements (Zr, Nb, Hf, Ta, Th and U), Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels (in rock) by magnetic sector inductively coupled plasma-mass spectrometry after HF/HClO₄ high pressure decomposition. The adopted method uses only indium as an internal standard. Detection limits were found to be in the range of 0.08 to 16.2 pg ml⁻¹ in solution (equivalent to 0.08 to 16.2 ng g⁻¹ in rock). Our data for high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi for the six selected low abundance geological reference materials show general agreement with previously published data. Our Ta values in DTS-1 and PCC-1 (1.3 and 0.5 ng g⁻¹) are lower than in previously published studies, providing smooth primitive mantle distribution patterns. Lower values were also found for Tl in BIR-1, DTS-1 and PCC-1 (2, 0.4 and 0.8 ng g⁻¹). Compared with quadrupole ICP-MS studies, the proposed magnetic sector ICP-MS method can generally provide better detection limits, so that the measurement of high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels can be achieved without pre-concentration, ion exchange separation or other specialised techniques.     

Sediment waves on the Moroccan continental rise

A nearly continuous zone of sediment waves is present on the lower continental rise off western Morocco which parallels the regional bathymetric trends. The individual sediment waves within the zone migrate upslope with time and, in general, also trend parallel to the regional bathymetric contours. These observations suggest that geostrophic contour currents are responsible for the formation of sediment waves. Physical oceanographic measurements and sea-floor photographs indicate only a very weak bottom circulation in this region. This suggests either that strong bottom currents are not essential for the formation of sediment waves or that relatively stronger bottom currents flowed along the continental margin of Morocco in the recent past. Turbidity flows may also influence the distribution of these sediment waves.     

Dynamical features of near-inertial motions in global ocean based on the GDP dataset from 2000 to 2019

Based on the latest oceanic surface drifter dataset from the global drifter program during 2000–2019, this study investigated the global variation of relative frequency shift(RFS), near-inertial energy(NIE) and inverse excess bandwidth(IEB) of near-inertial motions, and analyzed their relations with oceanic mesoscale dynamics, relative vorticity and strain. Compared with previous works, we have some new findings in this study:(1) the RFS was high with negative values in some regions in which we found a significant blue shift of the RFS in the equatorward of 30°N(S) and from 50°N to 60°N in the Pacific, and a red shift in the western boundary currents and their extension regions, the North Atlantic and the Antarctic Circumpolar Current regions;(2) more peak values of the NIE were found in global regions like the South Indian Ocean, the Luzon Strait and some areas of the South Ocean;(3) the global distribution of the IEB were characterized by clear zonal bands and affected by vorticity and wind field;(4)the RFS was elevated as the absolute value of the gradient of vorticity increased, the IEB did not depend on the gradient of vorticity, and the eddy kinetic energy(EKE) weakened with the decrease of the absolute value of RFS;(5) the NIE decreased with increasing absolute value of the relative vorticity and the gradient of vorticity, but it increased with increasing strain and EKE when EKE was larger than 0.003 2 m~2/s~2.     

Compositional controls on spinel clouding and garnet formation in plagioclase of olivine metagabbros,Adirondack Mountains,New York

Olivine metagabbros from the Adirondacks usually contain both clear and spinel-clouded plagioclase, as well as garnet. The latter occurs primarily as the outer rim of coronas surrounding olivine and pyroxene, and less commonly as lamellae or isolated grains within plagioclase. The formation of garnet and metamorphic spinel is dependent upon the anorthite content of the plagioclase. Plagioclase more sodic than An_38±2 does not exhibit spinel clouding, and garnet rarely occurs in contact with plagioclase more albitic than An_36±4. As a result of these compositional controls, the distribution of spinel and garnet mimics and visually enhances original igneous zoning in plagioclase. Most features of the arrangement of clear (unclouded) plagioclase, including the shells or moats of clear plagioclase which frequently occur inside the garnet rims of coronas, can be explained on the basis of igneous zoning. The form and distribution of the clear zones may also be affected by the metamorphic reactions which have produced the coronas, and by redistribution of plagioclase in response to local volume changes during metamorphism.Authors listed alphabeticallyPublished by permission of the Director, New York State Museum, Journal Series Number 299     

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.     

Mesozoic thermal evolution of the southern African mantle lithosphere

The thermal structure of Archean and Proterozoic lithospheric terranes in southern Africa during the Mesozoic was evaluated by thermobarometry of mantle peridotite xenoliths erupted in alkaline magmas between 180 and 60 Ma. For cratonic xenoliths, the presence of a 150–200 °C isobaric temperature range at 5–6 GPa confirms original interpretations of a conductive geotherm, which is perturbed at depth, and therefore does not record steady state lithospheric mantle structure.

Xenoliths from both Archean and Proterozoic terranes record conductive limb temperatures characteristic of a “cratonic” geotherm (40 mW m⁻²), indicating cooling of Proterozoic mantle following the last major tectonothermal event in the region at 1 Ga and the probability of thick off-craton lithosphere capable of hosting diamond. This inference is supported by U–Pb thermochronology of lower crustal xenoliths [Schmitz and Bowring, 2003. Contrib. Mineral. Petrol. 144, 592–618].

The entire region then suffered a protracted regional heating event in the Mesozoic, affecting both mantle and lower crust. In the mantle, the event is recorded at 150 Ma to the southeast of the craton, propagating to the west by 108–74 Ma, the craton interior by 85–90 Ma and the far southwest and northwest by 65–70 Ma. The heating penetrated to shallower levels in the off-craton areas than on the craton, and is more apparent on the southern margin of the craton than in its western interior. The focus and spatial progression mimic inferred patterns of plume activity and supercontinent breakup 30–100 Ma earlier and are probably connected.

Contrasting thermal profiles from Archean and Proterozoic mantle result from penetration to shallower levels of the Proterozoic lithosphere by heat transporting magmas. Extent of penetration is related not to original lithospheric thickness, but to its more fertile character and the presence of structurally weak zones of old tectonism. The present day distribution of surface heat flow in southern Africa is related to this dynamic event and is not a direct reflection of the pre-existing lithospheric architecture.