Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition

 Calculations of the Rigid Unit Modes (RUMs) allowed in the nepheline structure are used to explain the diffuse scattering previously seen in electron diffraction experiments. The RUM calculations also show that the modulation wavelength for incommensurate nephelines is essentially determined by the framework topology. X-ray diffraction is used to measure the intensity of the diffuse scattering as a function of temperature. The diffuse intensity increases sharply at 308 K. This effect is interpreted as being due to the softening of a phonon mode, indicating a phase transition. Measurements of this phase transition below the transition temperature are made using hard mode infrared spectroscopy. Received: 17 February 1999 / Revised, accepted. 15 October 1999     

Speleothems from Mawsmai and Krem Phyllut caves,Meghalaya, India: some evidences on biogenic activities

The Mawsmai cave and Krem Phyllut caves, East Khasi hills, Meghalaya, India has so far not yet attracted the attention of geomicrobiologists. Observations and hypotheses on the possible influence of identified microorganisms for speleothem formations in Meghalaya are reported for the first time. XRD studies identified calcite in speleothems and gypsum in cave wall deposits as the dominant minerals. SEM-EDAX showed interesting microfabric features showing strong resemblance with fossilised bacteria, calcified filaments, needle calcite and numerous nano scale calcite crystals, highly weathered and disintegrated crystals of calcite, that point towards a significant microbial influence in its genesis. Thin section petrography showed laminated stromatolitic features. The microorganisms identified by conventional isolation and further evaluation of isolates by molecular techniques include Bacillus cereus, Bacillus mycoides, Bacillus licheniformis, Micrococcus luteus, and Actinomycetes. Microscopic observations also showed unidentifiable cocci and four unidentifiable strains of CaSO₄ (gypsum) precipitating bacteria. Experimental studies confirmed that these bacteria are able to precipitate calcium minerals (calcite, gypsum, minor amounts of dolomite) in the laboratory. These results allow us to postulate that species like these may contribute to active biogenic influence in the cave formations at Meghalaya.     

The effect of anatase, rutile and sodium titanate on the dissolution of boehmite and gibbsite at 90 °C

Industrial plants that refine bauxite to alumina using the high temperature process have always held the belief that anatase was detrimental to the extraction of boehmite while rutile was not. This study shows that this effect is real and that it is observable at temperatures as low as 90 °C. The extraction of gibbsite is shown to be unaffected which leads us to believe that the kinetics of both the Ti-bearing mineral and the Al-bearing mineral is important in this phenomenon. In addition, it is shown that not only is the presence of anatase an issue in boehmite extraction but so too is the presence of sodium titanate. Rutile was found to have the least impact of the three mineral phases.     

Converted phases analysis of the Campi Flegrei caldera using active seismic data

We applied a type of depth migration for converted seismic phases to active and passive seismic data sets from the Campi Flegrei volcanic region in southern Italy. The migration method is based on the diffraction summation migration technique. Travel times to grid points in a volume were calculated in smooth P and S-velocity models and trace energy near the calculated converted phase time was stacked over multiple sources at one receiver. Weighting factors based on Snell's Law at an arbitrarily oriented local interface were applied to better focus trace energy. PP reflection images from the active data set provide increased detail to images of the caldera rim from other studies. The migrated images also show features near 2–3 km in depth beneath Pozzuoli City, which may be associated with an over-pressured gas volume, as suggested by other geophysical investigations. Possible deeper features near 4 km depth may be related to the presence of the carbonate basement or may image a previously undetected feature, such as a small body of strongly thermometamorphosed volcanic rock. The current passive earthquake data set from the 1984 ground uplift episode was not well suited to the converted phases analysis due to narrow P–S windows and high noise levels in the traces. However, two stations provide confirmation and extension of imaged features in the active data.     

Mesoproterozoic (1.47–1.44 Ga) orogenic magmatism in Fennoscandia; Baddeleyite U–Pb dating of a suite of massif-type anorthosite in S. Sweden

The Jönköping Anorthositic Suite (JAS) in S. Sweden has characteristics typical for (Proterozoic) massif-type anorthosites. The interstitial liquid of these plagioclase-porphyritic rocks solidified at 1,455 ± 6 Ma, as determined by U–Pb isotope analysis of baddeleyite. The JAS developed during a regional 1.47–1.44 event in Fennoscandia that generated widespread mafic magmatism (basalts, and diabase dykes and sills) in the north and emplacement of felsic plutons in the south. The event of 1.47–1.44 Ga magmatism in Fennoscandia largely coincides in age with dynamic high-grade metamorphism in SW Sweden and was probably related to convergent active-margin processes during the Danopolonian orogeny.     

Giant pulses of PSR B0531+21 at 112 MHz

Three series of 111.88 MHz observations of giant pulses of PSR B0531+21 have been carried out in 2005 and 2007. The scattering of pulses observed in various series varies by a factor of 1.7: 10.6±0.5 ms in November 2005, 18±1 ms in January 2007, and 16±0.8 ms in June 2007. The cumulative probability distribution for the peak intensities of the giant pulses for each of these series shows that the distribution is stable and is a power law with a single slope (n = 2.3). This testifies to stability of the mechanism generating the giant pulses. The distribution functions for the 2005 and 2007 data can be superposed after correcting the intensities with a coefficient equal to the ratio of the effective pulse widths. Consequently, in the range of 23MHz-9GHz the energy in the pulses is conserved; i.e., the increase in the pulse intensity is proportional to the decrease in the scattering. Refractive scintillations at low frequencies in measurements with large time separation lead to variations in the number of giant pulses exceeding a given amplitude, proportional to the ratio of the mean flux densities of the pulsar in the corresponding observational series. The maximum energy of the recorded giant pulses is 2.5 × 10⁷ Jy µs. A comparison with the statistical properties of the giant pulses observed at other frequencies shows that the frequency dependence of the maximum energy of the giant pulses in the range of 23 MHz-9GHz is a power-law with index 2.2±0.2. The degree of linear polarization of the giant pulses at 112 MHz does not exceed 12%.     

Geochemical characterization of karst groundwater in the cradle of humankind world heritage site,South Africa

The karst of the Cradle of Humankind World Heritage Site plays a major role in the assimilation or carrying of acid mine drainage, sewage effluent return flow and agricultural run-off. Infiltration of contaminated water has altered the chemical composition of the natural waters of the karst system. A multivariate statistical method in combination with conventional geochemical and spatial analysis was applied on groundwater and surface water quality samples to determine the spatial extent of hydrochemical impacts from different anthropogenic sources. The application of hierarchical cluster analysis of the major ions (148 samples) recognised three distinct hydrochemical regimes. Cluster 1 is moderately mineralized, especially with regard to chloride, nitrate and sulphate, cluster 2 has a low mineralization with all elements well within the recommended drinking water limits of South Africa and cluster 3 represents highly mineralized samples taken in the vicinity of decanting mineshafts. The cluster solution is confirmed by a simple mixing model, indicating varying contributions of three identified end members (acid mine drainage, treated sewage effluents and pristine dolomitic groundwater) to the groundwater quality in the catchment. The combination of statistical, geochemical and spatial methods in conjunction with end-member mixing analysis provides a reliable method to understand the processes responsible for the groundwater quality variations and to assist in the identification of anthropogenic impacts.     

The major-ion composition of silurian seawater

One-hundred fluid inclusions in Silurian marine halite were analyzed in order to determine the major-ion composition of Silurian seawater. The samples analyzed were from three formations in the Late Silurian Michigan Basin, the A-1, A-2, and B Evaporites of the Salina Group, and one formation in the Early Silurian Canning Basin (Australia), the Mallowa Salt of the Carribuddy Group. The results indicate that the major-ion composition of Silurian seawater was not the same as present-day seawater. The Silurian ocean had lower concentrations of Mg²⁺, Na⁺, and SO₄²⁻, and much higher concentrations of Ca²⁺ relative to the ocean’s present-day composition. Furthermore, Silurian seawater had Ca²⁺ in excess of SO₄²⁻. Evaporation of Silurian seawater of the composition determined in this study produces KCl-type potash minerals that lack the MgSO₄-type late stage salts formed during the evaporation of present-day seawater. The relatively low Na⁺ concentrations in Silurian seawater support the hypothesis that oscillations in the major-ion composition of the oceans are primarily controlled by changes in the flux of mid-ocean ridge brine and riverine inputs and not global or basin-scale, seawater-driven dolomitization. The Mg²⁺/Ca²⁺ ratio of Silurian seawater was ∼1.4, and the K⁺/Ca²⁺ ratio was ∼0.3, both of which differ from the present-day counterparts of 5 and 1, respectively. Seawaters with Mg²⁺/Ca²⁺ <2 facilitate the precipitation of low-magnesian calcite (mol % Mg < 4) marine ooids and submarine carbonate cements whereas seawaters with Mg²⁺/Ca²⁺ >2 (e.g., modern seawater) facilitate the precipitation of aragonite and high-magnesian calcite. Therefore, the early Paleozoic calcite seas were likely due to the low Mg²⁺/Ca²⁺ ratio of seawater, not the pCO₂ of the Silurian atmosphere.     

Problems of Paleogene–Neogene stratigraphy of the Zerkal’naya depression,East Sikhote Alin

The Paleogene–Neogene stratigraphic scale of the Zerkal’naya River basin is modified with account for new isotopic and paleobotanical data. It is established that the Tadushi Formation and underlying volcanics, which were previously considered as representing transitional Cretaceous–Paleocene strata, are separated in the section of the Ustinovka quarry by a significant stratigraphic hiatus. According to the new data, the volcanics and the Tadushi Formation are established as Campanian and Late Paleocene in age, respectively. The Bogopol Formation in the type section is dated back to the Middle–Late Paleocene. The Svetlyi Formation is now considered to be Early Eocene in age, rather than Late Eocene–Oligocene as previously thought. A new variant of the stratigraphic scale is proposed for the Paleogene–Neogene deposits of the Zerkal’naya depression.