Stable isotope studies of fluid inclusions in speleothems and their paleoclimatic significance

Fluid inclusions found trapped in speleothems (cave deposited travertine) are interpreted as samples of seepage water from which enclosing calcium carbonate was deposited. The inclusions are assumed to have preserved their D/H ratios since the time of deposition. Initial ¹⁸O/¹⁶O ratios can be inferred from δD because rain- and snow-derived seepage waters fall on the meteoric water line (δD = 8δ¹⁸O + 10). Estimates of temperature of deposition of the carbonate can be calculated from inclusion D/H ratios and δ¹⁸O of enclosing calcite in Pleistocene speleothems. For most speleothems investigated (0–200,000 yr old) δ¹⁸O of calcite appears to have decreased with increasing temperature of deposition indicating that the dominant cause of climate-dependent change in δ¹⁸O of calcite was the change in K_cw, the isotope fractionation equilibrium constant, with temperature; δ¹⁸O of meteoric precipitation generally increased with increasing temperature, but not sufficiently to compensate for the decrease in K_cw.     

Über die Vertikalverteilung und jahreszeitliche Entwicklung der Larvendichte vonDreissena polymorpha Pallas im Pelagial des unteren Zürichseebeckens im Jahre 1974

The freshwater musselDreissena polymorpha Pallas was sighted for the first time in Lake Zürich about 1969. This meant a real problem for the water treatment of lake water. By means of a pump and vertical net hauls it was tried to add more information to the scarce results on Lake Zürich. Additional dates about temperature, depth of Secchi disk visibility and beam transmittance were collected. There was a first appearance of the larvae ofD. polymorpha at the beginning of June. Following the mean temperature of the epilimnion the number of individuals/m² reached max. 210,000. The greatest concentration measured in 1974 of larvae/m³ was 54,375 at a depth of 4 m. The last appearance ofD. polymorpha was observed at the end of October.

     

Plumes,subaxial pipe flow,and topography along the Mid-Oceanic Ridge

If plate thickness depends on crustal age, the region of extensive partial melting below the spreading axis will be wider around fast-spreading ridges. The melt region creates a subaxial conduit channeling partial melts away from ridge-centered hot spots. The channel is here modeled by an elliptical pipe of semiminor (vertical) axis 2 × 10⁶ cm (20 km) and semimajor (horizontal) axis KS, where S is spreading half-rate (cgs) and K is a constant of magnitude 10¹⁴ to 10¹⁵ seconds. This simple analytical model is used to explain the observation that maximum hot spot elevations on the Mid-Oceanic Ridge fall dramatically with increasing spreading rate (there are no Icelands or Afars on the East Pacific Rise!). A hot spot under a fast-spreading ridge has a broad pipe in which to discharge its partial melts; hence, only a slight topographic gradient and a low elevation is needed to discharge the mass flux rising out of the deeper mantle at the hot spot center. A second factor is that partial melts are “used up” faster in the accretion process on fast-spreading ridges. In the simple analytical model, both factors operating together explain the rapid fall of hot spot heights with increasing spreading half-rate. This result indirectly helps confirm the idea of horizontal pipe flow below the Mid-Oceanic Ridge.A theoretical topographic profile through a hot spot on the Mid-Oceanic Ridge is derived from the assumption that the pressure — i.e., topographic — gradient at a distance x from the hot spot is sufficient to supply all the accreting lithosphere downstream of x, out to x_n, the limit of topographic hot spot influence. The predicted profile is quadratic in x and concave upward, and resembles several observed profiles where neighboring hot spots are not so close as to confuse the profiles. Some observed profiles are more nearly linear or even convex upward. This could be explained, for example, by downstream increases in viscosity or decreases in pipe dimensions.A hot spot on a ridge spreading at much less than 1 cm/yr half-rate would produce an enormous elevation of the ridge axis, according to our model, because the pipe would be very narrow. Such a large topographic high would create a large gravity potential which would cause the plates to move apart faster, thereby widening the pipe, and reducing the topographic high. The system of ridges and hot spots may thus be self-regulating with respect to plate speeds; this could explain why spreading half-rates on the Mid-Oceanic Ridge are in many areas as low as 1.0 cm/yr but very rarely as low as 0.5 cm/yr.     

Aircraft observations in the planetary boundary layer under stable conditions

An analysis of observations of airflow over Lake Ontario in a stably stratified atmosphere is presented. The relationship with theory is mentioned only in terms of what may be important to future work. Detailed air motion, potential temperature and mixing-ratio measurements are presented which show pervasive variability in the horizontal. There is no evidence of gravity waves. It is suggested that vertical mixing of the atmosphere may occur in stable conditions by a mechanism quite apart from the usual concept of the small-scale random eddy motion usually associated with surface convection. Vertical soundings are analyzed as well as two long constant-height observational runs.     

Effects of a variable sun at the beginning of the Cenozoic era

Periodic bursts of increased ultraviolet radiation, possibly caused by a long-term breakdown of the ozone layer in late Cretaceous to early Tertiary time, can explain the staggered extinctions of terrestrial, marine and flying reptiles, of invertebrate plankton feeders. Inherited protective devices and habits of surviving genera support this hypothesis. Increased radiation also explains the concurrent decrease in aridity indicated by the world-wide absence of marine salt and potash deposits from Maestrichtian, Danian, Paleocene and Eocene sediments, the poleward displacement of marine tropical faunas and the warm-temperate forests in high latitudes. A magnetic reversal is too brief an event to be responsible for the faunal changes; variations in solar radiation of the order of the Kelvin-Helmholtz time, or 30–40 million years, with superimposed shorter periodicities are a probable cause.     

Magnetic and microstructural properties of some lodestones

An iron ore which behaves as a permanent magnet is lodestone. The intrinsic magnetic properties and the microstructual characteristics which are responsible for the permanent-magnet properties of the lodestone have never been described or explained. Iron ores capable of being charged sufficiently strongly to behave as permanent magnets are defined here as proto-lodestones and fall into two categories — Class I which contains Fe as the only significant cation, and Class II which contains considerable Ti, Mg and Al as well. Proto-Lodestones are magnetically hardened by oxidation and precipitation processes which produce the microstructure responsible for the permanent-magnet properties. Lodestones are charged proto-lodestone iron ores. Lodestones have R_H values (ratio of remanent coercive force, H_R, to coercive force, H_C) between 2.0 and 2.5; R_I values (ratio of saturation remanence, I_SR, to saturation magnetization, I_S) >0.1–0.25 and the ratio of NRM/SIRM (natural remanence to saturation remanence) is 0.15–0.7. The intrinsic magnetic properties and microstructural characteristics of proto-lodestones and other iron ores are described and explained. The mechanism of charging the proto-lodestone appears to be either transient magnetic fields associated with lightning-discharge currents or presently obscure aspects of magnetization intensity enhancement associated with maghemitization of massive iron ores.     

Eastern Altantic fracture zones as potential disposal sites for radioactive waste

Disposal of radioactive waste in the sea floor of fracture zones associated with the flanks of the Mid-Atlantic Ridge may be a satisfactory alternative to land disposal. Effective physiographic, sedimentary, chemical, and oceanographic barriers exist in these aseismic deep canyons, especially in the eastern Atlantic. In addition, the major producers of radioactive wastes are likely to be near the Atlantic Ocean. If such a disposal strategy is adopted, intensive study of the sedimentologic and oceanographic properties of oceanic fracture zones will be necessary.     

Pallasite meteorites—mineralogy,petrology and geochemistry

Pallasites are highly differentiated meteorites and provide a unique sample from the deep interiors of solar system parent bodies. They contain evidence of the former existence of one or more residual melts. Olivine is a major phase. Its primary shape is rounded; the angular crystals in many pallasites are secondary. Tubular inclusions are widespread. They perhaps are the residence of CO₂, released during laboratory heating experiments. Phosphoran olivine, a new variety of olivine containing 4–5 wt% P₂O₅, occurs in a few pallasites. Its Fe/Mg ratio is apparently independent of the host olivine composition.Pyroxene (not previously described from pallasites) occurs in symplectic intergrowths in seven meteorites. Compositionally, it lies in the gap between pyroxenes in chondrites and most irons. There are two groups: Fs_{11.6 ± 0.2} and Fs_{16.7 ± 0.2} The pyroxene contains exceptionally low Ca (< 0.1–0.2 wt%) and there is an indication of an inverse relation between Fe and Ca.Modal analyses and density measurements were made on all available specimens and bulk compositions were calculated. The ‘average’ pallasite contains 65 vol. % olivine and 50.5 wt % total Fe. Many of the densities of pallasites cluster around that calculated for close-packed olivine.Pallasites are exotic cumulates. Their textures resemble terrestrial cumulates, as does the presence of olivine and chromite. The metal texture resembles a solidified intercumulus liquid. Those pallasites containing olivine in excess of close-packing were subjected to adcumulus growth, thereby also explaining the widespread mutual borders.There is abundant evidence of deformation. For olivines this includes their fragmental shape and kink banding. Troilite formed a eutectic-like melt with kamacite: pieces of spalled olivine and schreibersite were injected into and captured by this melt. Troilite polycrystallinity resulted from the deformation. This deformation occurred while the pallasites were still deeply buried, resulting in incipient spheroidization of olivine fragments, including the formation of elongate, rounded crystals. A later, lower temperature deformation disrupted plessite.Pallasites formed in multiple parent bodies by processes that recurred in several places within the solar system, as shown by the mineralogical and textural similarities between pallasites that differ in their isotopic and trace element compositions. Type IIIB irons still seem the most likely associated meteorites.Two new pallasites, Dora and Rawlinna, are described briefly.     

Interaction of organic compounds with calcium carbonate—III. Amino acid composition of sorbed layers

Nitrogenous organic compounds in sorbed surface layers and in calcified organic matter associated with calcium carbonate sediment particles consist of 40–50% amino acids, 2% amino sugars and 25% ammonia. In grain size classes > 20 μm these compounds are mainly contained in the calcified protein of carbonate secreting organisms but with smaller grain sizes—and consequently increased specific surface area—they are contained in sorbed layers at the mineral surface. The composition of the sorbed layer is characterized by a predominance of neutral amino acids, a relative enrichment of basic and weakly polar amino acids, and a deficiency of acidic amino acids in comparison with the proteinaceous matter of calcifying organisms. The respective abundances for sorbed and calcified matter are: 505 and 380 Res./ of neutral amino acids, 262 and 450 Res./1000 of acidic amino acids, 92 and 51 Res./l000 of basic amino acids, and 141 and 129 Res./1000 of weakly polar amino acids.The composition of the sorbed layer appears to be the result of sorption of proteinaceous matter from solution since it reflects the free and peptide-bound amino acid composition of seawater. The characteristic amino acid assemblage could also be the result of preferential decomposition of protein and subsequent enrichment of neutral and basic amino acids; however, sorption from solution appears more likely since the total amount of amino acids sorbed to calcium carbonate (0.58 mg m ^?2) corresponds closely to the amount of protein known to cover one m² of aqueous substrate in monolayer arrangement. Sorption from solution is further supported by the low arginine/ornithine ratios in both the sorbed layer and the natural dissolved organic matter. This process might lead to a characteristic amino acid spectrum in fine grained calcareous sediments that reflects the composition of the dissolved organic matter in seawater rather than that of the carbonate secreting proteinaceous matter.