The Australia Telescope 20-GHz (AT20G) Survey: the Bright Source Sample

The Australia Telescope 20-GHz (AT20G) Survey is a blind survey of the whole southern sky at 20 GHz (with follow-up observations at 4.8 and 8.6 GHz) carried out with the Australia Telescope Compact Array from 2004 to 2007.
The Bright Source Sample (BSS) is a complete flux-limited subsample of the AT20G Survey catalogue comprising 320 extragalactic     ) radio sources south of  δ=−15°  with      Jy. Of these, 218 have near simultaneous observations at 8 and 5 GHz.
In this paper we present an analysis of radio spectral properties in total intensity and polarization, size, optical identifications and redshift distribution of the BSS sources. The analysis of the spectral behaviour shows spectral curvature in most sources with spectral steepening that increases at higher frequencies (the median spectral index α, assuming   S ∝ν^α  , decreases from  α^8.6_4.8= 0.11  between 4.8 and 8.6 GHz to  α²⁰_8.6=−0.16  between 8.6 and 20 GHz), even if the sample is dominated by flat spectra sources (85 per cent of the sample has  α²⁰_8.6 > −0.5)  . The almost simultaneous spectra in total intensity and polarization allowed us a comparison of the polarized and total intensity spectra: polarized fraction slightly increases with frequency, but the shapes of the spectra have little correlation. Optical identifications provided an estimation of redshift for 186 sources with a median value of 1.20 and 0.13, respectively, for QSO and galaxies.     

Activation volumes for oxygen exchange between the GaO4Al12(OH)24(H2O)127+(aq) (GaAl12) polyoxocation and aqueous solution from variable pressure O NMR spectroscopy

Activation volumes for exchange of oxygen between bulk aqueous solution and sites in the GaO₄Al₁₂(OH)₂₄(H₂O)₁₂⁷⁺(aq) (GaAl₁₂) complex were measured by variable-pressure ¹⁷O NMR techniques. Near 322 K, rates of exchange for the less labile set of bridging hydroxyls in the GaAl₁₂ decrease by a factor of about two with increasing pressure from 0.1 to 350 MPa. These data indicate a substantially positive activation volume of ΔV^‡ = +7 ± 1 cm³/mol, which is the first activation volume measured for a bridging hydroxyl in a polynuclear complex. This result suggests significant bond-lengthening in the activation step. Electrostriction effects should be small because exchange occurs via a pH-independent path under the experimental conditions. The second, more labile set of bridging hydroxyls exchange too rapidly for the variable-pressure techniques employed here. The exchange of bound-water molecules on the GaAl₁₂ was observed at P = 350 MPa using the ¹⁷O-NMR line-broadening technique. Comparison with previous measurements at 0.1 MPa indicates decreasing line width from 0.1 to 350 MPa for temperatures at which exchange dominates, yielding an activation volume of ΔV^‡ = +3(± 1) cm³/mol. This activation volume is smaller than the value for the Al(H₂O)₆³⁺ complex, suggesting that water exchange on the larger GaAl₁₂ complex has less dissociative character although the average charge density is lower.     

Wind erodibility of soils at Fort Irwin,California (Mojave Desert), USA,before and after trampling disturbance: implications for land management

Recently disturbed and ‘control’ (i.e. less recently disturbed) soils in the Mojave Desert were compared for their vulnerability to wind erosion, using a wind tunnel, before and after being experimentally trampled. Before trampling, control sites had greater cyanobacterial biomass, soil surface stability, threshold friction velocities (TFV; i.e. the wind speed required to move soil particles), and sediment yield than sites that had been more recently disturbed by military manoeuvres. After trampling, all sites showed a large drop in TFVs and a concomitant increase in sediment yield. Simple correlation analyses showed that the decline in TFVs and the rise in sediment yield were significantly related to cyanobacterial biomass (as indicated by soil chlorophyll a). However, chlorophyll a amounts were very low compared to chlorophyll a amounts found at cooler desert sites, where chlorophyll a is often the most important factor in determining TFV and sediment yield. Multiple regression analyses showed that other factors at Fort Irwin were more important than cyanobacterial biomass in determining the overall site susceptibility to wind erosion. These factors included soil texture (especially the fine, medium and coarse sand fractions), rock cover, and the inherent stability of the soil (as indicated by subsurface soil stability tests). Thus, our results indicate that there is a threshold of biomass below which cyanobacterial crusts are not the dominant factor in soil vulnerability to wind erosion. Most undisturbed soil surfaces in the Mojave Desert region produce very little sediment, but even moderate disturbance increases soil loss from these sites. Because current weathering rates and dust inputs are very low, soil formation rates are low as well. Therefore, soil loss in this region is likely to have long‐term effects. Published in 2006 by John Wiley & Sons, Ltd.     

Geomorphic and hydraulic unit richness and complexity in a coastal plain river

Geomorphic and hydraulic units in river channels are closely linked to geodiversity and habitats, and thus to biodiversity. In a ~ 200 km reach of the lower Sabine River, in the northern Gulf of Mexico Coastal Plain, 72 different hydraulic units (HU) were identified in six geomorphic zones or river styles. Richness–area relationships indicate a linear or logarithmic increase of HUs, as opposed to the less steep power functions generally found in biogeographic species–area curves or in soil richness–area analyses. Different results are obtained when starting from the upstream or downstream end of the study area, indicating the importance of directionality in such analyses. These results show that HUs (and related habitats and biotopes) are both richer and more variable than a repeated sequence of units. The number of HUs inundated increases linearly with flow stage categories, indicating the importance of high within‐bank flows in maintaining and activating HUs. Aggregated HUs (AHUs) associated with similar geomorphic units are highly connected, both with respect to patterns of spatial adjacency and potential connectivity at similar flow levels. Spectral graph theory metrics applied to a graph representation of spatial adjacency shows a highly complex network with a high potential for rapid propagation of changes—and even more so for a graph based on flow connectivity. The flow connectivity graph shows far higher synchronization as indicated by algebraic connectivity. Thus suggests more rapid and coherent changes for processes driven by river flow, as opposed to phenomena driven by other factors between flow events. These findings have important implications for understanding relationships between geodiversity and habitat diversity, managing habitat and biodiversity, and linking the latter to instream flows. Copyright © 2017 John Wiley & Sons, Ltd.     

Mineralisation from Vall de Ribes area (Eastern Pyrenees,Spain)

Vein mineralisation with no preferred orientation, cutting lower Palaeozoic rocks, and local replacement deposits in dolomite show a zoning in tungsten-bismuth, arsenic and antimony minerals away from the adjacent late-Hercynian Costabona granite. A local reversed zoning is related to higher temperatures indicated by fluid inclusion study. Many of the minerals have not previously been reported from this area.     

A new 40Ar/39Ar eruption age for the Mount Widderin volcano,Newer Volcanic Province,Australia, with implications for eruption frequency in the region

The Mount Widderin shield volcano is located near Skipton, western Victoria, in the Western Plains subprovince of the monogenetic Pliocene–Holocene Newer Volcanic Province (NVP). Radiometric ages for lavas in the Hamilton–Skipton–Derrinallum area are few, owing to limited suitable outcrop for K–Ar or ⁴⁰Ar/³⁹Ar geochronology studies. Existing age constraints for flows in this area have been inferred from Regolith Landform Units (RLUs), complemented by a small number of K–Ar studies on ≥1 Ma flows. Although the RLU approach provides a valuable overview of relative eruption ages across the NVP, it is of limited use in eruption frequency studies. Additional radio-isotopic ages are required to refine age ranges for individual RLUs, and to validate previous assignment of individual flows to specific RLUs. We report a new, high-precision ⁴⁰Ar/³⁹Ar age of 389 ± 8 ka (2σ) for a Mount Widderin basalt sample. Based on this age and geomorphic observations, we propose that both the Widderin and Elephant lava flows be reassigned from the Eccles RLU to the Rouse RLU. We use the 389 ± 8 ka (2σ) age for Widderin, along with published K–Ar ages, to anchor a stratigraphic sequence of 15 individual flows in the Hamilton–Skipton–Derrinallum area, demonstrating that intermittent volcanism has occurred in this area from ≥3 Ma to ≤0.389 Ma. Within the limits of available data for the NVP, this time span of volcanic activity is second only to that of the Melbourne area. We consider the significance of the Widderin eruption age, in conjunction with published age constraints for maars and scoria cones of the Western Plains subprovince, building on previous studies that have focused solely on lava flow ages. The inclusion of the additional data weakens the argument for a decrease in volcanic activity after ca 0.9 Ma as implied by published ages for lava flows only. Additional detailed combined geochronology–geomorphology studies of lavas, scoria cones and maars in strategically selected small areas are advocated to better understand eruption frequency across the NVP.