Chemistry of marine resources-ⅩⅨ. The molecule design and synthesis of crow-link type alkyd resin and its enrichment behaviour for potassium ion in sea water

This paper first presents the molecule design and synthesis of crown-link type alkyd resin,and its enrichment behaviour for potassium ion in low concentration solution and sea water.On the basis of some theory concepts of Host-Guest chemistry developed in recent years,we have designed and synthesized a new polymer enrichment agent of crow-link resin for potassiumion,i.e.,polymacrocyclic ether bislactone of diethylene glycolpyromyllitic acid(briefly called crown-link type alkyd resin or PBL resin).The yield was about 97.4%,almost quantitatively.     

冰层厚度传感器及其检测方法

水结冰和冰融化过程中的电阻、电容、温度物理参数与被检测冰表面以上的空气层或冰下水层的电阻、电容、温度有一定的差异,有些差异在数值上比较明显。基于这一特点,笔者提出了利用空气、冰与水的物理特性差异实现对冰层厚度及冰下水位接触式检测的新思路,对含有导电杂质的冰、冰-水混合物、水、空气的电阻、电容特性随温度的变化规律进行了初步分析,并得到冰的弱导电性质和冰与水的电容区间单调特性,据此提出了冰层厚度传感器结构及其冰厚检测原理,介绍了新型冰层厚度传感器在实践中的应用。     

基于投影网格的大面积水面生成算法

本文主要研究在现代硬件条件下,如何为渲染生成一个大面积的水面。为了达到摄像机高低不同时对分辨率的要求,同时保持空间的可量测性,现在经常使用的生成算法是各种"层次细节"的方法。但层次细节也存在存储数据量大以及接边等问题。本文介绍了一种替代的算法:投影网格算法。投影网格从我们希望在投影后得到的网格入手,反向找出网格在投影前的位置,更有目的性,有自己的优势。     

Main Controlling Factors on Hydrocarbon Accumulation and Distribution in Marine Sedimentary Sequences in South China

Multiple source rock assemblages were deposited in the sedimentary provinces in South China in geologic history,and some of them were destructed by and some survived against multiple tectonic movements.Therefore,multiple sources,mixed sources,and uneven distribution of sources occurred in the marine sedimentary basins in South China during the late stage of hydrocarbon pooling.Epidiagenesis of the marine carbonate reservoirs and its modification to reservoir poroperm characteristics determined the formation and the scale of natural gas pools.The exploration practices show that the large to medium gas fields mainly occur in areas with high-quality reservoirs.Detailed study of the paleo-oil accumulations and typical oil and gas reservoirs reveals that the basins experienced multiphase superimposition and modification,leading to the distribution of the Paleozoic paleo-oil accumulations and bitumen in the peripheral areas.The phenomenon that oil and gas production concentrates in the Sichuan basin indicates that the overall sealing conditions of a basin determine the oil/gas potentials and the scale of oil and gas production.This is a critical factor controlling the accumulation and distribution of gas in the marine sequences in South China.The early oil and gas pools in the Yangtze platform left billions of bitumen in the peripheral areas due to the destruction of seals.Since the Himalayan,"late-generation and late-accumulation" gas pools represented by the gas pools in the Sichuan (四川) basin were formed in the marine sedimentary sequences in South China as a result of the change of the sealing conditions.Current gas discoveries appear to be "paleo-generation and paleo-accumulation" gas pools but actually are "late-generation and late-accumulation" gas pools.These patterns of hydrocarbon pooling clearly depict themselves in western Sichuan basin and Weiyuan (威远)gas field.It is revealed that the gas pools in the Sichuan basin were mainly formed as a result of hydrocarbon phase change (thermal cracking of oil to gas),miscible migration,and dynamic equilibration since the Himalayan.A large number of gas pools were formed in the Himalayan and the gas pools in the marine sequences are characterized by late pooling; this kind of gas fields/pools are controlled by:(1) effectiveness of modification and superimposition of the marine basins,(2) effectiveness of the source rocks,(3) effectiveness of the overall preservation conditions,and (4) effectiveness of plays.     

基于色层图与纹理融合的地形晕渲

针对三维地形晕渲的具体需求和存在问题,提出了一种基于色层图与纹理融合的晕渲方法。根据自定义或色层表主色调插值生成色彩连续的色层图,对地形高程进行着色;在地表材质分块的基础上,通过计算相邻材质边界上的多重纹理坐标,使用多重纹理映射进行融合过渡;最后给出了实验结果。     

GPS单点测速的误差分析及精度评价 (英文)

Error sources which decrease the accuracy of GPS in absolute velocity determination have been changed since SA was turned off. Firstly, quantities of all kinds of error sources that influence velocity determination are analyzed. The potential accuracy of GPS absolute velocity determination is derived from both theory and field GPS data simulation. After that, two tests were carried out to evaluate the performance of GPS absolute velocity determination in the case of a static and an airborne GPS receiver and INS （Inertial Navigation System） instrument in kinematic mode. In static mode, the receiver velocity has been estimated to be several mm/s with the carrier-phase derived Doppler measurements, and several cm/s with the receiver generated Doppler measurements. In kinematic mode, GPS absolute velocity estimates are compared with the synchronized measurements from the high accuracy INS. The root mean square statistics of the velocity discrepancies between GPS and INS come up to dm/s. Moreover, it has a strong correlation with the acceleration or jerk of the aircraft.     

多视处理对SAR船只探测的影响

合成孔径雷达(Synthetic Aperture Radar, SAR)成像过程中会出现斑点噪声,一般用多视处理减少图像的斑点噪声,这对合成孔径雷达船只探测造成了一定的影响.本文对不同视数SAR图像的等效视数、空间分辨率和船只海面对比度进行了分析,结果表明:一方面,多视处理增加了等效视数,改善了图像质量,更有利于船只探测;但另一方面,多视处理又降低了图像空间分辨率和船只海面对比度,对船只探测产生不利影响.最后本文选取了窗口滤波法和K分布法两种典型的SAR船只探测方法对多视处理的SIR-C SAR图像进行了船只探测试验,得到了最适合船只探测的多视处理的视数.     

同位素示踪剂在流域水文模拟中的应用

主要目的是通过对同位素在流域水文模拟应用中的一些假定、限制条件以及方法进行澄清和系统化,从而促进同位素在流域水文模拟中一些新的研究方向和研究热点.主要从三个方面,即同位素流量过程线分割、流域平均滞时与不同水源混合、与水文模型耦合,讨论同位素示踪剂在流域水文模拟中的研究进展情况.同时指出了同位素在流域水文模拟中应用存在的一些主要问题,包括:①降雨同位素含量的时空变化;②不同径流成分的采样;③径流输出同位素含量的空间变化;④流域平均滞时分布函数的确定;⑤水文同位素耦合模型.     

基于BERN5．0软件计算的北京地区GPS可降水量研究

收集了2002-2007年6年期间的北京房山站（BJFS）连续观测数据,利用BERN高精度GPS数据处理软件计算出该站的对流层延迟,再利用该站的气象观测资料分离干延迟获得2mm精度的湿延迟,计算出BJFS站的可降水量（PWV）,组成长达6年的时间序列,初步探讨北京地区的季节性降水量变化,特别是第三季度的可降水量影响,通过数据走势,预测计算不同季度的降水概率。     

基于相关系数匹配的混合像元分解算法

遥感影像中的混合像元不仅影响地物识别和分类的精度,而且已成为遥感科学向定量化发展的主要障碍.为此,人们已经提出了多种混合像元分解算法,其中应用最为广泛的是最小二乘法.该方法虽然具有意义明确、简单易行等特点,但也易受局部噪声、大气效应、环境辐射等因素的影响.本文将混合像元分解问题归结为一个基于光谱匹配的非线性最优化问题,并针对最小二乘法的不足提出了一种新的基于相关系数匹配(spectral correlation matching, SCM)的混合像元分解技术.通过在北京市北三环及其以北区域内案例的研究表明:在城市区域内,利用图像选取终端端元的办法,基于相关系数匹配的混合像元分解算法的总体精度高于带全约束的最小二乘法(LS)的分解结果.对比分析表明:在目标光谱的绝对值整体放大或缩小而光谱形状得到了很好的保持、及局部噪声使得光谱值显著变化但光谱形状得到了一定程度保持时,基于光谱形状的相关系数法可以得到比基于光谱绝对值的最小二乘法精度更高的分解结果.