Dissolved carbon in pore waters from the carbonate barrier reef of Tahiti (French Polynesia) and its basalt basement

This paper deals with dissolved inorganic carbon (DIC) and organic carbon (DOC) in pore waters from a 150 m deep hole drilled through the carbonate barrier reef of Tahiti and its underlying basalt basement. Alkalinity-pH measurements were used to calculate the DIC species concentration, and DOC was analysed according to the high temperature catalytic oxidation technique. Salinity was used as a conservative tracer to help identify water origin and mixing within the hole. Water mixing, calcium carbonate dissolution and mineralization of organic carbon combined to form three distinct groups of pore water. In the deeper basalt layers, pore water with alkalinity of 1.4 meq kg^–1 pH of 7.6 and p(CO₂) of 1.2 mAtm was undersaturated with respect to both aragonite and calcite. In the intermediate carbonate layer, pore water with alkalinity of more than 2.0 meq kg^–1, pH of 7.70 and p(CO₂) of 1.4 mAtm was supersaturated with respect to both aragonite and calcite. The transition zone between those two groups extended between 80 and 100 m depth. The shift from aragonite undersaturation to supersaturation was mainly attributed to the mixing of undersaturated pore waters from the basalt basement with supersaturated pore waters from the overlaying limestone. In the top of the reef, inputs from a brackish water lens further increased p(CO₂) up to 5.6 times the atmospheric P(CO₂).     

Damage model for jointed rock mass and its application to tunnelling

This paper establishes an anisotropic nonlinear damage model in strain space to describe the behavior of jointed rock and applies it to mechanical analysis of tunnelling. This work focuses on rate-independent and small-deformation behavior during static isothermal processes. The prime results include: (1) the properties of damage-dependent elasticity tensors based on geological information of the jointed rock mass; (2) the damage evolution law presented on the basis of thermodynamics and combined with endochronic theory; and (3) the global damage tensor based on the work-equivalence principle and the local geological data of multi-joint sets. Finally the numerical results of a tunnel intersection in jointed rock is presented to illustrate the mechanical behavior of this model.     

Effect of polychromatic X‐ray microtomography imaging on the amino acid content of the Murchison CM chondrite

X‐ray microcomputed tomography (μCT) is a useful means of characterizing cosmochemical samples such as meteorites or robotically returned samples. However, there are occasional concerns that the use of μCT may be detrimental to the organic components of a chondrite. Small organic compounds such as amino acids comprise up to ~10% of the total solvent extractable carbon in CM carbonaceous chondrites. We irradiated three samples of the Murchison CM carbonaceous chondrite under conditions akin to and harsher than those typically used during typical benchtop X‐ray μCT imaging experiments to determine if detectable changes in the amino acid abundance and distribution relative to a nonexposed Murchison control sample occurred. After subjecting three meteorite samples to ionizing radiation dosages between ~300 Gray (Gy) and 3 kGy with bremstrahlung X‐rays, we analyzed the amino acid content of each sample. Within sampling and analytical errors, we cannot discern differences in the amino acid abundances and amino acid enantiomeric ratios when comparing the control samples (nonexposed Murchison) and the irradiated samples. We conclude that a polychromatic X‐ray μCT experiment does not alter the abundances of amino acids to a degree greater than how well those abundances are measured with our techniques and therefore any damage to amino acids is minimal.     

Neutron monitor observations of high-energy solar particles during the new cycle

After a lapse of five years, the first solar events in which particles were emitted with sufficiently high energies to produce intensity enhancements in ground-based neutron monitors occurred on July 7, 1966, and January 28, 1967. Although the magnitude of the first of these increases was too small (<2%) to permit detailed analysis, the later event, which exceeded 18% at sea-level stations in the polar regions, displayed unusual characteristics. The January 28 event is anomalous in that either it represents the first observation of solar particles reaching the earth from the back side of the sun, or it is associated with a feeble flare (1-) in the unfavored eastern hemisphere of the visible disk. The propagation of solar particles in this event was evidently controlled by a diffusion mechanism, and the observations are consistent with predictions based on alternative theoretical models of this process.This work was supported by the U.S. National Science Foundation and the U.S. Air Force Cambridge Research Laboratories, Office of Aerospace Research.     

Über die Verteilung der aus Gezeitenbeobachtungen bestimmten gravimetrischen Faktoren in Europa

auamaumuu am, n u a¶rt;u nuu n ¶rt;a ₂, ₂, ₁ u ₁ (u. 1–4). na ¶rt;a ¶rt;am au ¶rt;um au an¶rt;u mu naam. a n¶rt;aam unam nu nuu nna m uu u u mmu mam ¶rt; uu u a a mau n.

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Vorgetragen am 2. Internationalen Symposium Geodäsie und Physik der Erde, Potsdam, Mai 1973.     

Geomagnetic Field Variations during the Total Solar Eclipse of 2 July 2019 in La Serena,Chile

Geomagnetism and Aeronomy - The total solar eclipse on July 2, 2019, has been studied by using data of the La Serena ground magnetic station in Chile located in the path of the totality (at...     

A dispersion scale effect in model calibrations and field tracer experiments

Field tracer experiments and model calibrations indicate that the magnitude of dispersivity increases as a function of the scale at which observations are made. Calculations presented in this study suggest that some part of this scaling may be explained as an artifact of the models used. Specifically, a scaling-up of dispersivity will occur whenever an (n − 1)-dimensional model is calibrated or otherwise employed to describe an n-dimensional system. The calibrated coefficients for such models will depend not only on size of the contaminant plume or tracer experiment at the time of calibration, but will exhibit a size dependency beyond the calibration period. The magnitude of scaling appears to be sufficient to encompass the range of differences between laboratory measurements of dispersivity and model calibrations.