Carbon Budget and Molecular Structure of Natural Organic Matter in Bank Infiltrated Groundwater

Managed aquifer recharge (MAR) provides means to remove natural organic matter (NOM) from surface waters. Recent studies have explored the degree of NOM removal in groundwater. In this study, we further elaborate the NOM removal at a lakeside natural bank infiltration site that functions as a surrogate for MAR. Our objective was to quantify the carbon budget in the aquifer based on concentration measurements of dissolved (in)organic carbon, and the molecular changes in NOM using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). According to the carbon budget, only 25% of the dissolved carbon entering the aquifer was organic, and it predominantly originated from lake water. Of the inorganic majority, on average 40% was produced in the vadose zone above the groundwater table, 31% in the lake bank, 22% in the aquifer as a result of degrading organic matter of lake water, and 7% in the lake. Seasonal concentration variations suggested that the lake bank was the main carbon source in the summer, increasing the carbon concentration of infiltrating lake water, that is, 3.0 mg/L to 7.9 mg/L. FT-ICR MS results showed 4960 to 5330 individual compounds in lake and groundwater. NOM removal in the aquifer was selective: the relative abundance of oxygen-containing species decreased from 75 to 31%, while the relative abundance of sulfur-containing species increased from 15 to 57%. The average molecular weights of both species remained unchanged. The study highlighted the role of lake bank processes and sulfur-containing species in groundwater quality.     

The hydrochemical facies and anomalous fluoride content in the Serra Geral aquifer system,southern Brazil: a GIS approach with tectonic and principal component analysis

Groundwater with high fluoride content and water mixture patterns were studied in Serra Geral aquifer system (SGAS) using three aspects, principal component analysis (PCA), tectonic scenery and hydrochemical interpretation from 309 groundwater chemical data information from deep wells. A four-component model is suggested and explains 81% of total variance in the PCA. Six hydrochemical facies were identified. These facies suggest two different fluoride sources. Tectonic approach shows the relationship between defined hydrochemical facies and regional fracture control. The applied methodology reveals a minimum level to understand hydrochemical mixtures. The fluoride enrichment mechanisms into the groundwater are comprised in advance to guide the future uses of SGAS to the public supply.     

Estuarine flooding in urban areas: enhancing vulnerability assessment

The assessment of vulnerability provides valuable knowledge in the risk assessment steps of a risk governance process. Given the multiscale, multilevel, and multisectorial aspects of flood risk, the diversified entities that directly and indirectly intervene in risk management require specific outputs from the assessment studies. Urban areas in estuarine margins are particularly exposed and vulnerable to flooding. Such interface conditions are found in the Old City Centre of the Seixal, located in the Tagus estuary, Portugal. Here, two distinct methodologies were applied for the assessment of territorial vulnerability. A regional, lower-scale, methodology explores the application of the statistical procedure based on the SoVI^® at the statistical block level. A second, local and higher-scale, methodology is based in data collected through field matrices at the building and statistical sub-block level. Comparison of results revealed that the lower-scale assessment provides information on the vulnerability drivers at the regional and municipal level. Nevertheless, only at a higher-scale, it is possible to characterize and differentiate the smaller geographical units of analysis that compose the Old City Centre of Seixal. The lower-scale vulnerability assessment allows a strategic response, based on adaptation measures such as spatial planning, institutional capacity building and public awareness. The local level assessment provides more accurate knowledge to support local emergency planning and the allocation of operational and material resources at the urban level. Nevertheless, rather than antagonistic, both models can be considered as complementary, having in mind the requirements of an holistic flood risk governance model.

     

The Legacy of Agricultural Reclamation on Channel and Pool Networks of Bay of Fundy Salt Marshes

We assess the status of channel networks and pools of two tidal salt marshes recovering from more than a century of agricultural reclamation on the Bay of Fundy, Canada. A process of largely unmanaged restoration occurred at these sites since abandonment of agricultural activities during the first half of the twentieth century. Each recovering marsh was compared to a reference marsh that was never drained or ditched. We field mapped channel networks at all marshes and used aerial photographs to map the pre-abandonment channel network at one of the sites. The recovering marshes have hybrid channel networks that feature highly variable channel morphologies, loss of original channels, and incorporation of drainage ditches. Although channel networks in recovering marshes integrate agricultural ditches, the recovering marsh networks may not be substantially increased in length or density. Our aerial photograph analysis shows that channel density at one of the recovering marshes is comparable to the pre-abandonment density, but with reduced sinuosity. Field mapping of permanent tidal pools on the lower Bay marshes revealed that pools cover 13% of the recovering marsh, compared to ∼5% of the reference marsh. This study demonstrates that these essential marsh features can be regained through restoration or simple abandonment of drainage infrastructure.     

Environmental issues in urban groundwater systems: a multidisciplinary study of the Paranhos and Salgueiros spring waters,Porto (NW Portugal)

This study presents the results of a multidisciplinary approach, using hydrogeochemical, isotopic and ecotoxicological analyses, performed to assess the nature and suitability for use of Paranhos and Salgueiros spring waters (Porto city, NW Portugal). Based on the surface activities located along the course of the springs, 23 water samples were collected. All the samples were analysed for major element concentrations. The isotopic techniques employed included δ²H, δ¹⁸O and ³H. Standard acute bioassays with Daphnia magna were also performed. The hydrogeochemical analyses showed a nitrate and sulphate-enriched composition for these groundwaters, resulting mainly from urban drainage and sewer leakage. In the ecotoxicological analyses, no significant mortality was observed in any of the tests performed. The results obtained in this study suggest that Porto urban groundwater could be suitable for irrigation uses.     

Mass balance simulation and principal components analysis applied to groundwater resources: Essaouira basin (Morocco)

The water resources of the Essaouira coastal basin (west of Marrakesh) are characteristic of a semi-arid climate and are severely impacted by the climate in terms of quantity and quality. Considering the importance of the Essaouira aquifer in the groundwater supply of a vast region (nearly 1,200 km²), a research study was conducted in order to better understand groundwater evolution in this aquifer system. It is a coastal aquifer located on the Atlantic coastline, southern Morocco, and salinization problems have been reported. Covering the Palaeozoic bedrock, the sedimentary series range from the Triassic to the Quaternary. Besides the possibility of seawater intrusion problems, the geological structures delineate a syncline bordered by the Tidzi diapir (of Triassic age) outcropping to the east and south. This is a recharge area for the aquifer, whereas the main groundwater flow direction is from SE to NW towards the Atlantic Ocean. In spite of the occurrence of calcareous and dolomitic levels, all waters in the Essaouira basin are of the Na–Cl-type. Based on a range of experimental methodologies, combined with PCA and geochemical modelling, it was possible to identify the mineralization processes occurring in the groundwater system, and the importance of the water–rock interaction in the water chemistry. Scenarios were tested using a simple mass balance model through the PHREEQC programme. The reaction path was assumed to be such that waters observed at shallow depths evolved to more mineralized waters. An important contribution of water–rock interaction in groundwater mineralization was found, corroborating the influence of preferential recharge from the Tidzi diapir in the water’s signature. Anthropogenic contamination was also identified and could lead to serious problems with groundwater degradation in the near future, in a country with scarce water resources.     

On Mathematical Aspects of a Combined Inversion of Gravity and Normal Mode Variations by a Spline Method

This paper provides a brief overview of two linear inverse problems concerned with the determination of the Earth’s interior: inverse gravimetry and normal mode tomography. Moreover, a vector spline method is proposed for a combined solution of both problems. This method uses localised basis functions, which are based on reproducing kernels, and is related to approaches which have been successfully applied to the inverse gravimetric problem and the seismic traveltime tomography separately.     

Nontronit vom Hohen Hagen und Chloropal vom Meenser Steinberg bei Göttingen

Zusammenfassung Von dem in der tertiären Sandunterlage des Hohen-Hagen-Basaltes ausgeschiedenen Nontronitmineral wurde eine chemische Analyse angefertigt und daraus die Strukturformel (Fe³⁺ _1,80Al_0,13Mg_0,10)_2,03[(OH)₂| Al_0,30Si_3,70O₁₀]^–0,31 aufgestellt, die einem Nontronit mit 90% Fe-Endglied entspricht. Die Bildung des Nontronitvorkommens erfolgte unter Mitwirkung des durch den Basaltaufstieg erhitzten und die übergeflossene Lava am Entweichen gehinderten Grundwassers der Sande. Der Stoffbestand entstammt dem Mobilisat der Basaltzersetzung. Die Ausfällung wurde durch E_h und p_H der sich mischenden Lösungen gesteuert. Die Transportbedingungen der Ionen und das Verhalten einiger Spurenelemente werden diskutiert. — Die chemische Analyse des Chloropals vom Meenser Steinberg ergibt für diesen einen Anteil von rund 1/4 Nontronit und 3/4 Opal-Cristobalit.

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Summary A chemical analysis was made of a nontronite mineral found in the tertiary sands below the basalt of the Hoher Hagen. Basing on this analysis, the structural formula is: (Fe³⁺ _1,80Al_0,13Mg_0,10)_2,03[(OH)₂| Al_0,30Si_3,70O₁₀]^–0,31. Thus, the mineral consists of 90% Fe-Nontronite. The formation of the nontronite was caused by the action of the ground water in the sands, which was heated by the basaltic magma and kept from escaping by the overflown lava. The chemical components were derived from the basalts through decomposition. The precipitation was caused by the differences in E_h and p_H of the solutions which were mixed during this process. The conditions for the transport of the ions and for the distribution of the trace elements are discussed. — From the chemical analysis of the Chloropale from the location Meenser Steinberg a mineralogical composition of 1/4 nontronite and 3/4 opale-cristobalite is calculated.

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Der Nontronit ist ... wohl ein Montmorillonit mit fast vollständigem Ersatz von Al³⁺ durch Fe³⁺ ... Als Zersetzungsprodukt eisenhaltiger Silikate weit verbreitet, ebenso wie der grüne Chloropal, der ein Gemenge von Nontronit mit Opalkieselsäure darstellt.Felix Machatschki, Spezielle Mineralogie auf geochemischer Grundlage (1953).

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Herrn Professor Dr.F. Machatschki zum 70. Geburtstag gewidmet.     

Pb isotope signatures of sediments from Guanabara Bay, SE Brazil: Evidence for multiple anthropogenic sources

Sediments from Guanabara Bay and two rivers were analyzed for Pb isotope composition. The results define linear groups interpreted as different sources of Pb. The samples from Iriri and Surui rivers present different Pb compositions probably resulting from two active pollutants which are transported in the waters to the Guanabara Bay, where they are mixed. The ²⁰⁶Pb/²⁰⁷Pb values of 1.151 and 1.091 presented here are in the range of Brazilian galena ore signature.