Geochemistry and Metallogeny of Phosphorus in the Russian Platform during the Jurassic–Cretaceous

The composition and metallogeny of igneous rocks and relevant weathering crusts of Jurassic–Cretaceous provenances of the Russian Platform are considered. It is shown that the association of metals that accumulated in the process of weathering and erosion of ancient substratum includes P, Fe, Ti, V, and Cr. This process is reflected in the formation of nodular phosphorites, Ti and Zr placers, and iron ore deposits in the Jurassic–Cretaceous seas of the platform.     

Structural controls on Quaternary deepwater sedimentation, mud diapirism, and hydrocarbon distribution within the actively evolving Columbus foreland basin, eastern offshore Trinidad

Eastward migration of the Caribbean plate relative to the South American plate has caused lithospheric loading along the northern margin of South America, which is recorded by an 1100-km-long foreland basin which is oldest in the west (Maracaibo basin, 65-55 Ma) and youngest in the east (Columbus basin, eastern offshore Trinidad, 15-0 Ma). The Orinoco River has been the primary source of sediment for the basin since early Miocene. We have integrated approximately 775 km of deep-penetration 2D seismic lines acquired in the area of eastern offshore Trinidad as part of the 2004 “Broadband Ocean-Land Investigations of Venezuela and the Antilles arc Region” (BOLIVAR) project, 8000 km² of shallow industry 3D seismic data, and published industry well data from offshore eastern Trinidad. Active mud diapirism in the Columbus basin is widespread and is related to overthrusting and tectono-sedimentary loading of upper Miocene-lower Pliocene age mud. Analysis of the shallow 3D seismic data reveals the presence of extensive gravity-flow depositional elements on the Columbus basin slope and the deepwater area. These stacked gravity-flow deposits are characterized by mass-transport deposits at the base, turbidite frontal-splay deposits, leveed-channel deposits, and capped by fine-grained condensed-section deposits. Exploration targets in the deepwater area are located towards the center of the Columbus basin, where northeast-trending fault-propagation folds are important Plio-Pleistocene trap-forming elements. Deep basin wells drilled in recent years have proven that turbidites were transported into the deepwater Columbus basin during the Plio-Pleistocene. Analysis of these well results suggests that a deeper oil charge is present within the deepwater Columbus basin area. The primary uncertainty for this variable hydrocarbon system is whether fault or diapiric pathways connect or divert the petroleum charge at depth with shallower reservoir rocks.     

The Middle Miocene to Recent Davis Strait Drift Complex: implications for Arctic�CAtlantic water exchange

A large-scale contourite drift complex has been recognised on multi-channel 2D reflection seismic data acquired in the south-eastern Davis Strait and adjacent Labrador Sea slope offshore West Greenland between 63°?C66°N. Based on well-tie data, the drift complex developed from the Middle Miocene to the Recent. It has been mapped in a wide variety of water depths ranging from about 700?m, at a NNW-ESE-elongated crest located above structural highs in the Davis Strait, to more than 2,000?m beyond the slope to the Labrador Sea. The overall drift geometry has been described by subdivision into two first-order seismic units, enabling the generation of time-isochore maps. The reflection patterns demonstrating current-related deposition are illustrated by seismic examples. The time-isochores of the two first-order seismic units show lateral changes in their depocentres: the lower unit is absent in a zone slightly displaced south-westwards of the present-day crest, indicating changes in the prevailing deepwater current system during the Early Pliocene. The observations can be explained by two alternative palaeoceanographic scenarios: (1) either the present-day oceanographic setting with Arctic?CAtlantic water exchange across the Davis Strait was largely established by the mid-Miocene, with only minor adjustments during the Early Pliocene caused by tectonic movements, or (2) it became established during the Early Pliocene as a consequence of enhanced northward flow across the Davis Strait due to lowering of the sill depth.     

Mineral assemblages occurring around hydrocarbon vents in the northern Gulf of Mexico

Magnesian calcites are the most abundant authigenic minerals associated with hydrocarbon vents at 25 sites, in water depths ranging from 100 to 600 m in the Green Canyon area and about 2200 m in the Alaminos Canyon area on the Continental Slope of the northern Gulf of Mexico. The most frequently encountered magnesian calcites have 10–15 mol% MgCO₃ and the apparent structural disorder revealed by XRD peak widths increases with Mg substitution. There are no systematic variations in Mg content with respect to water depth or geographic location. The calcite saturation state of the precipitating fluid is primarily determined by the nature of the fluids escaping from the vents, not the ambient seawater.     

Carbon balance in a salt marsh: Interactions of diffusive export, tidal deposition and rainfall-caused erosion

Studies of the concentrations of particulate and dissolved organic carbon in the Duplin River, of the tidal exchange of POC and DOC in the marsh, of the standing stock and movement of Spartina alterniflora wrack in the Duplin, and of the removal of carbon from the surface of the marsh by rain were conducted at Sapelo Island, Georgia in order to test three hypotheses about export of carbon from the Duplin River watershed. We found that the gradients in POC and DOC concentrations are such that carbon is being transported down the Duplin River throughout the year, although in smaller quantities than previously believed. In contrast, almost all tidal exchanges within the marsh result in deposition of carbon. Most of this deposited carbon is subsequently eroded as a result of rain falling on the exposed marsh surface, and is washed back into the tidal creeks. This cycle of deposition and erosion is a possible mechanism keeping POC in the thin aerobic surface layer of the marsh, thus increasing its availability to detritivores and aerobic microbes. The standing stock of wrack is only a fraction of the S. alterniflora produced each year, and its export is a negligible term in the carbon balance equation.     

The role of archaeological and cultural-historical records in long-range coastal fisheries resources management strategies and policies in the Pacific Islands

The usefulness of conventional fisheries science for long-term fisheries management and policies in the resource-poor islands of the Pacific is very limited. Fishery managers can, however, make use of such alternative sources of information as archaeological and historical data to develop fishery management initiatives. Most Pacific Islands were settled by humans over the last three millennia, although human settlement in Western Melanesia dates from the late Pleistocene, a period of about 40 millennia. Archaeological studies over the past half-century contain information on the long-term subsistence exploitation of fish and invertebrates from nearshore coral reefs and lagoons. Molluscs appear to have been a very important food source for early human colonists in the Pacific Islands, but declines in abundance through harvest pressure and environmental changes forced a greater reliance on fin-fish capture and on agriculture. There is no firm evidence from the archaeological record to suggest that long-term subsistence exploitation of reef fish populations has had any serious negative effects on abundance or structure of reef fish communities. Sources for more recent historical information are also exemplified and briefly examined for their usefulness in assessing the impacts of commercial fishing. It is argued that fishery managers who adopt a data-less approach to fishery management could profitably use these sources of information to enrich their assessment of the impacts of various management scenarios.     

Automated threshold selection methods for extreme wave analysis

The study of the extreme values of a variable such as wave height is very important in flood risk assessment and coastal design. Often values above a sufficiently large threshold can be modelled using the Generalized Pareto Distribution, the parameters of which are estimated using maximum likelihood. There are several popular empirical techniques for choosing a suitable threshold, but these require the subjective interpretation of plots by the user.In this paper we present a pragmatic automated, simple and computationally inexpensive threshold selection method based on the distribution of the difference of parameter estimates when the threshold is changed, and apply it to a published rainfall and a new wave height data set. We assess the effect of the uncertainty associated with our threshold selection technique on return level estimation by using the bootstrap procedure. We illustrate the effectiveness of our methodology by a simulation study and compare it with the approach used in the JOINSEA software. In addition, we present an extension that allows the threshold selected to depend on the value of a covariate such as the cosine of wave direction.     

Distribution and spatial variation of hydrothermal faunal assemblages at Lucky Strike (Mid-Atlantic Ridge) revealed by high-resolution video image analysis

Whilst the fauna inhabiting hydrothermal vent structures in the Atlantic Ocean is reasonably well known, less is understood about the spatial distributions of the fauna in relation to abiotic and biotic factors. In this study, a major active hydrothermal edifice (Eiffel Tower, at 1690 m depth) on the Lucky Strike vent field (Mid-Atlantic Ridge (MAR)) was investigated. Video transects were carried out by ROV Victor 6000 and complete image coverage was acquired. Four distinct assemblages, ranging from dense larger-sized Bathymodiolus mussel beds to smaller-sized mussel clumps and alvinocaridid shrimps, and two types of substrata were defined based on high definition photographs and video imagery. To evaluate spatial variation, faunal distribution was mapped in three dimensions. A high degree of patchiness characterizes this 11 m high sulfide structure. The differences observed in assemblage and substratum distribution were related to habitat characteristics (fluid exits, depth and structure orientation). Gradients in community structure were observed, which coincided with an increasing distance from the fluid exits. A biological zonation model for the Eiffel Tower edifice was created in which faunal composition and distribution can be visually explained by the presence/absence of fluid exits.     

The oxygen isotope composition of water masses within the North Sea

Based on measurements of the ¹⁸O isotope composition of 247 samples collected over a 3-year period we have assessed the oxygen isotope composition of water masses in the North Sea. This is the first δ¹⁸O data set that covers the entire North Sea basin. The waters lie on a mixing line: δ¹⁸O (‰_VSMOW) = −9.300 + 0.274(S) with North Atlantic sub-polar mode water (SPMW) and surface waters, and Baltic Sea water representing the saline and freshwater end members respectively. Patterns exhibited in surface and bottom water δ¹⁸O distributions are representative of the general circulation of the North Sea. Oxygen-18 enriched waters from the North Atlantic enter the North Sea between Scotland and Norway and to a lesser extent through the English Channel. In contrast, oxygen-18 depleted waters mainly inflow from the Baltic Sea, the rivers Rhine and Elbe, and to a lesser degree, the Norwegian Fjords and other river sources. Locally the δ¹⁸O–salinity relationship will be controlled by the isotopic composition of the freshwater inputs. However, the range of local freshwater compositions around the North Sea basin is too narrow to characterise the relative contributions of individual sources to the overall seawater composition. This dataset provides important information for a number of related disciplines including biogeochemical research and oceanographic studies.