Optical characteristics of coastal waters and atmosphere near the south coast of the crimea at the end of summer 2008

We present the results of measurements of optical characteristics of waters (the beam attenuation coefficient, volume scattering function, sea water reflectance, and Secchi depth) and optical characteristics of the atmosphere (aerosol optical thickness, content of vapors, and the ?ngstr?m exponent) carried out in September 2008 on the oceanographic platform near Katsiveli. We carried out the comparative analysis of hydrooptical characteristics measured in various years. The optical type of sea waters in the period of observations is determined.     

Geochemical and microbiological characteristics of sediments near the Malenky mud volcano (Lake Baikal, Russia), with evidence of Archaea intermediate between the marine anaerobic methanotrophs ANME-2 and ANME-3

Detailed lithological, biogeochemical and molecular biological analyses of core sediments collected in 2002–2006 from the vicinity of the Malenky mud volcano, Lake Baikal, reveal considerable spatial variations in pore water chemical composition, with total concentrations of dissolved salts varying from 0.1 to 1.8‰. Values of methane δ¹³С in the sediments suggest a biogenic origin (δ¹³С_min. ?61.3‰, δ¹³С_max. ?72.9‰). Rates of sulphate reduction varied from 0.001 to 0.7 nmol cm^?3 day^?1, of autotrophic methanogenesis from 0.01 to 2.98 nmol CH₄ cm^?3 day^?1, and of anaerobic oxidation of methane from 0 to 12.3 nmol cm^?3 day^?1. These results indicate that methanogenic processes dominate in gas hydrate-bearing sediments of Lake Baikal. Based on clone libraries of 16S rRNA genes amplified with Bacteria- and Archaea-specific primers, investigation of microbial diversity in gas hydrate-bearing sediments revealed bacterial 16S rRNA clones classified as Deltaproteobacteria, Gammaproteobacteria, Chloroflexi and OP11. Archaeal clone sequences are related to the Crenarchaeota and Euryarchaeota. Baikal sequences of Archaea form a distinct cluster occupying an intermediate position between the marine groups ANME-2 and ANME-3 of anaerobic methanotrophs.     

Contributions to atmospheric methane by natural seepages on the U.K. continental shelf [Mar. Geol. 137 (1997) 165–189]

Natural gas seepages occur on the United Kingdom's continental shelf and although published reports suggest that they are very rare, the petroleum industry has identified, but not publicly reported, many more. There is also very little data on the flux of gas from seabed seepages, and even less on the contribution of seepages to atmospheric concentrations of gases such as methane.

Potential gas source rocks include Quaternary and Tertiary peats as well as petroliferous source rocks such as the Carboniferous Coal Measures and the Upper Jurassic Kimmeridge Clays. There are also other organic-rich sediments which are potential source rocks. Together these cover a considerable part of the U.K. continental shelf.

Analogue seismic reflection (pinger) profiles acquired during the British Geological Survey's regional mapping programme have been reviewed to identify water column targets including fish and plumes of gas bubbles. The ability to distinguish targets is critical to an assessment of the distribution of gas seepages. Both theoretical predictions of target identity and the habits of shoaling fish have been investigated in order to identify a method of distinction.

Data from seabed seepages and measurements of seepage rates have been used to establish likely ranges of gas flux rates and the sizes of gas bubbles. The likelihood that a rising bubble will survive and escape into the atmosphere is determined primarily by bubble size and water depth; methane, the principal constituent of seepage gas, is relatively unreactive and sparingly soluble.

The studies have enabled a new estimate of the distribution of gas seepages on the U.K. continental shelf, and of the contribution to atmospheric methane levels. The results suggest that natural gas seepages are significantly more important as a source of methane than had hitherto been established. It is estimated that between 120,000 and 3.5 mtonnes of methane per year come from a continental shelf area of about 600,000 km². This represents between 2% and 40% of the total United Kingdom methane emission. It is suggested that similar contributions arise from other continental shelf areas worldwide, and that geological sources of atmospheric methane are more significant than is generally acknowledged.     

Errors in recent ocean tide models: possible origin and cause

Recently, the TOPEX/POSEIDON Science Working Team has recommended the FES95.2.1 and CSR3.0 ocean tide models for reprocessing the TOPEX/POSEIDON Geophysical Data Records. Without doubt, the performance of these models, especially in the deep oceans, is excellent. However, from a comparison of these hydrodynamically consistent models with the purely empirical DW3.2 and DEOS96.1 models, it appears that FES95.2.1 and CSR3.0 are affected by basin boundary related errors which are caused by the basin-wise solution procedure of the FES ocean tide model series. In their turn, the empirical DW3.2 and DEOS96.1 models seem to suffer from significant errors in the Antarctic seas due to the seasonal growth and decay of Antarctic sea ice. Also, bathymetry-induced differences were found between the hydrodynamically consistent models and the empirical models. Concerning these differences, TOPEX/POSEIDON and ERS-1 crossover statistics unfortunately do not provide conclusive results on which models are in error.     

The aqueous photochemical transformation of acrylic acid

Acrylic acid in sea water is thought to occur mostly as the product of microbial cleavage of dimethylsulphoniopropionate (DMSP), but could also be a pollutant introduced by waste waters of the organic chemical industry. Solutions of acrylic acid in natural and artificial sea water, and distilled and riverine water were photolyzed using a photochemical reactor and exposure to sunlight. The transformation of acrylic acid comprises the decarboxylation of the carboxylic group and subsequent polymerization to a polyethylene type molecule. Kinetic studies showed the lowest reaction rate in distilled water and somewhat higher and very similar rates in other aqueous media. The approximately similar reaction rates in all natural waters studied suggest that inorganic ions, especially Na⁺, Mg²⁺ and halides, and dissolved organic matter (probably humics) enhance the reaction rates. On studying the influence of different concentration ranges on the reaction kinetics, an exponential increase of rates with decreasing concentration was found. The reaction rate in the sea water solution in field conditions is rather slow. In thirty days exposure about 15% of the reactant was transformed. This reaction seems to be important in the marine environment in specific conditions, especially in phycospheres and macroaggregates where higher concentrations of acrylic acid inhibit the bacterial metabolism.     

Scour at the head of a vertical-wall breakwater

This paper presents the results of an experimental investigation on the near-bed flow patterns, the bed shear stress amplification and scour around the head of a vertical-wall breakwater, using regular waves. The Keulegan-Carpenter number (KC), based on the diameter of the breakwater head, is found to be the major parameter that governs the flow and the equilibrium scour depth. Basic flow structures are identified as function of KC. The scour depth is found to increase with increasing the Keulegan-Carpenter number. The necessary extent of the conventional stone protection is studied. An empirical formula is worked out for the width of the protection layer as function of KC. Also, the effects of head shape, the angle of attack and the presence of a co-directional current are investigated. The results indicate that the scour depth is increased considerably in the presence of a current. Likewise, the scour depth is increased when the head shape is changed from a round shape to a sharp-edged one. It is found that the angle of attack is also an influencing factor as regards the scour depth.     

REDOX POTENTIAL MEASUREMENTS AS AN INDICATION OF BIOCHEMICAL WELL PLUGGING

Abstract. Hydrogeologic and geochemical investigations have recently been made at an existing municipal supply well in the Town of Pembroke, Massachusetts, to determine the feasibility of using the Vyredox Method (Hallberg and Martinell, 1976) to remove iron and manganese from the ground water. The unique Vyredox testing procedures confirmed the existence of an active iron and manganese precipitating bacteria colony in the productive zone of the aquifer, which was causing rapid plugging of the well.     

Microseismicity and tectonics of Sinai

Five microearthquake seismographs were used at 11 sites in northern Sinai in the period February 1987 to February 1988 to study the microseismicity of the area around the Maghara coal mine for mine-development studies. A total of 270 events were recorded on 850 records. The magnitude, epicenter and depth of each event were calculated using suitable software for an Egyptian Geological Survey and Mining Authority's (EGSMA) XT computer. The interpretation of the seismic activity in the area is given in view of plate tectonics, the Sinai subplate boundary follows the Gulf of Aqaba and the Dead Sea. The plate and subplate boundaries are presently active, and there seems to be a diffuse zone of deformation between “NW Africa” and “Nubia” affecting the Cairo-Suez district.     

Trends in marine debris along the U.S. Pacific Coast and Hawai'i 1998-2007

We assessed amounts, composition, and trends of marine debris for the U.S. Pacific Coast and Hawai'i using National Marine Debris Monitoring Program data. Hawai'i had the highest debris loads; the North Pacific Coast region had the lowest debris loads. The Southern California Bight region had the highest land-based debris loads. Debris loads decreased over time for all source categories in all regions except for land-based and general-source loads in the North Pacific Coast region, which were unchanged. General-source debris comprised 30-40% of the items in all regions. Larger local populations were associated with higher land-based debris loads across regions; the effect declined at higher population levels. Upwelling affected deposition of ocean-based and general-source debris loads but not land-based loads along the Pacific Coast. LNSO decreased debris loads for both land-based and ocean-based debris but not general-source debris in Hawai'i, a more complex climate-ocean effect than had previously been found.