Scales of nutrient-limited phytoplankton productivity in Chesapeake Bay

The scales on which phytoplankton biomass vary in response to variable nutrient inputs depend on the nutrient status of the plankton community and on the capacity of consumers to respond to increases in phytoplankton productivity. Overenrichment and associated declines in water quality occur when phytoplankton growth rate becomes nutrient-saturated, the production and consumption of phytoplankton biomass become uncoupled in time and space, and phytoplankton biomass becomes high and varies on scales longer than phytoplankton generation times. In Chesapeake Bay, phytoplankton growth rates appear to be limited by dissolved inorganic phosphorus (DIP) during spring when biomass reaches its annual maximum and by dissolved inorganic nitrogen (DIN) during summer when phytoplankton growth rates are highest. However, despite high inputs of DIN and dissolved silicate (DSi) relative to DIP (molar ratios of N∶P and Si∶P>100), seasonal accumulations of phytoplankton biomass within the salt-intruded-reach of the bay appear to be limited by riverine DIN supply while the magnitude of the spring diatom bloom is governed by DSi supply. Seasonal imbalances between biomass production and consumption lead to massive accumulations of phytoplankton biomass (often>1,000 mg Chl-a m^?2) during spring, to spring-summer oxygen depletion (summer bottom water <20% saturation), and to exceptionally high levels of annual phytoplankton production (>400 g m^?2 yr^?1). Nitrogen-dependent seasonal accumulations of phytoplankton biomass and annual production occur as a consequence of differences in the rates and pathways of nitrogen and phosphorus cycling within the bay and underscore the importance of controlling nitrogen inputs to the mesohaline and lower reaches of the bay.     

Coupled thermal, hydraulic and geochemical evolution of pyritic tailings in unsaturated column experiments

The evolution of pore-water and the composition of solid phases in the vadose zone of pyritic tailings was studied by means of unsaturated column experiments. Several columns of water-saturated mine tailings were dried during 125 days under controlled laboratory conditions. The columns were dismantled at four successive drying stages and the evolution of pore-water, mineralogy, water content and temperature was characterized.Sulfide and aluminosilicate minerals present in the waste dissolved, releasing sulfate and other solutes (mainly Fe, Zn, Cu, Al, Mg and Ca) to the pore-water. Evaporation caused a crust of efflorescent, water-soluble sulfates to develop over the complete top surface of the columns and into the pores of the underlying waste material. This crust, which has also been identified in the field, changed the hydraulic properties of the tailings and produced a decrease in the evaporation rate of the columns. Moreover, these water-soluble precipitates (mainly rozenite, szomolnokite, halotrichite, hexahydrite, mirabilite and gypsum) acted as temporary sinks for Cd, Pb, Co and Ni, which could be released to the surface run-off or the groundwaters during rainfall events under field conditions.Pore-water evolution was determined not only by geochemical processes (dissolution of sulfides and aluminosilicates, precipitation of secondary phases) but also by thermal and hydraulic processes. Progressive dilution was observed in the lower part of the columns. Dilution was caused by the thermally driven vapor flux from the top of the column to its colder bottom and subsequent condensation therein. This process, which may also occur in tailings under sub-arid climate, played a key role on the evolution of pore-water with increasing drying.     

The kinetics of iodide oxidation by the manganese oxide mineral birnessite

The kinetics of iodide (I⁻) and molecular iodine (I₂) oxidation by the manganese oxide mineral birnessite (δ-MnO₂) was investigated over the pH range 4.5-6.25. I⁻ oxidation to iodate proceeded as a two-step reaction through an I₂ intermediate. The rate of the reaction varied with both pH and birnessite concentration, with faster oxidation occurring at lower pH and higher birnessite concentration. The disappearance of I⁻ from solution was first order with respect to I⁻ concentration, pH, and birnessite concentration, such that −d[I⁻]/dt = k[I⁻][H⁺][MnO₂], where k, the third order rate constant, is equal to 1.08 ± 0.06 × 10⁷ M⁻² h⁻¹. The data are consistent with the formation of an inner sphere I⁻ surface complex as the first step of the reaction, and the adsorption of I⁻ exhibited significant pH dependence. Both I₂, and to a lesser extent, sorbed to birnessite. The results indicate that iodine transport in mildly acidic groundwater systems may not be conservative. Because of the higher adsorption of the oxidized I species I₂ and , as well as the biophilic nature of I₂, redox transformations of iodine must be taken into account when predicting I transport in aquifers and watersheds.     

Partition of radiotracers between suspended particles and seawater

Distinctive uptake mechanisms of different radiotracers by red clays in seawater are elucidated from the magnitude and change of distribution coefficients (K_d) for up to 17 γ-emitting radiotracers as functions of equilibration time, suspended particle concentration and compositions of solids and seawaters. The adsorption of ionic metals onto colloids and subsequent coagulation of colloids onto larger particles are the dominant removal processes of metals in the aquatic environments of low suspended particle concentration.     

Late glacial and holocene landscapes of central Beringia

New palynological and sedimentological data from St. Lawrence Island present a rare view into late-glacial and Holocene environments of the central Bering Land Bridge. The late glaciation was a time of dynamic landscape changes in south-central Beringia, with active thermokarst processes, including the formation and drainage of thaw lakes. The presence of such a wet, unstable substrate, if widespread, probably would have had an adverse impact on food sources and mobility for many of the large mammal populations. The establishment of Betula shrub tundra on the island suggests late-glacial summers that were warmer than present, consistent with regional paleoclimatic interpretations. However, the increasing proximity to the Bering Sea, as postglacial sea levels rose, modified the intensity of warming and prevented the establishment of deciduous forest as found in other areas of Beringia at this time. The mid- to late Holocene is marked by more stable land surfaces and development of Sphagnum and Cyperaceae peat deposits. The accumulation of organic deposits, decline of shrub Betula, and decrease in thermokarst disturbance suggest that conditions were cooler than the previous. A recent decline in peat accumulation at the study sites may relate to local geomorphology, but similar decreases have been noted for other arctic regions.     

The state of the environment in Mexico

The present work evaluates the state of the environment in Mexico based on indicators of the present status of the country’s natural resource management, social and economical conditions and anthropogenic modifications. The Mexican environment is interpreted as a spatially open system having a historical character that is essentially determined by the continual interaction between nature, society and economy. The landscape approach is followed, considering as units of territorial analysis each one of the 145 biophysical environmental units included in the national physiographic regionalization. The assessment of 16 indicators for each biophysical environmental unit was made considering their regional environmental integrity problems, the degree of disarticulation of their structure and function, and the alteration of their territorial structure, all of which determine whether or not they accomplish their environmental functions and achieve environmental stability. The classification of the state of the environment included 5 categories in 8 combinations represented in the map of the state of the environment in Mexico for the year 2008. The map shows that nearly 47.10% of the country’s surface has an environmental status ranging between unstable and critical, the problematic areas being mostly concentrated in the southeast and center of the national territory.     

Comparative discharges of fresh and waste water along the California coast

As the population of California grows, the discharge of domestic and industrial waste water and power-plant cooling water into coastal waters continuously increases. About 0.75 × 10⁶ m³ of industrial waste water, 3.75 × 10⁶ m³ of domestic waste water, and 26.5 × 10⁶ m³ of thermal effluent are discharged daily into California's nearshore waters. These waters do not have an infinite capacity to break down and disperse the pollutants. Waste water discharged near shore may remain there for considerable time and have a significant effect on water quality and marine life. The low population and wet climate of the northern coastal region have led to small discharges of waste water but very large inputs of fresh water to the ocean. Southward along the Pacific Coast the climate becomes more arid, and population increases. This combination leads to a large excess of waste-water over fresh-water discharge. Many individual waste-water discharges exceed the average daily discharge of most of the rivers which enter the coastal waters.     

Multiphase inclusions in plagioclase from anorthosites in the Stillwater Complex,Montana: implications for the origin of the anorthosites

Multiphase inclusions, consisting of clinopyroxene+ilmenite+apatite, occur within cumulus plagioclase grains from anorthosites in the Stillwater Complex, Montana, and in other rocks from the Middle Banded series of the intrusion. The textures and constant modal mineralogy of the inclusions indicate that they were incorporated in the plagioclase as liquid droplets that later crystallized rather than as solid aggregates. Their unusual assemblage, including a distinctive manganiferous ilmenite and the presence of baddeleyite (ZrO₂), indicates formation from an unusual liquid. A process involving silicater liquid immiscibility is proposed, whereby small globules of a liquid enriched in Mg, Fe, Ca, Ti, P, REE, Zr and Mn exsolved from the main liquid that gave rise to the anorthosites, became trapped in the plagioclase, and later crystallized to form the inclusions. The immiscibility could have occurred locally within compositional boundaries around crystallizing plagioclase grains or it could have occurred pervasively throughout the liquid. It is proposed that the two immiscible liquids were analogous, n terms of their melt structures, to immiscible liquid pairs reported in the literature both in experiments and in natural basalts. For the previously reported pairs, immiscibility is between a highly polymerized liquid, typically granitic in composition, and a depolymerized liquid, typically ferrobasaltic in composition. In the case of the anorthosites, the depolymerized liquid is represented by the inclusions, and the other liquid was a highly polymerized aluminosilicate melt with a high normative plagioclase content from which the bulk of the anorthosites crystallized. Crystallization of the anorthosites from this highly polymerized liquid accounts for various distinctive textural and chemical features of the anorthosites compared to other rocks in the Stillwater Complex. A lack of correlation between P contents and chondrite-normalized rare earth element (REE) ratios of plagioclase separates indicates that the amount of apatite in the inclusions is too low to affect the REE signature of the plagioclase separates. Nevertheless, workers should use caution when attempting REE modelling studies of cumulates having low REE contents, because apatite-bearing inclusions can potentially cause problems.     

Late Quaternary Vegetation and Climate of the Wind River Range, Wyoming

Sediments from Rapid Lake document glacial and vegetation history in the Temple Lake valley of the Wind River Range, Wyoming over the past 11,000 to 12,000 yr. Radiocarbon age determinations on basal detrital organic matter from Rapid Lake (11,770 ± 710 yr B.P.) and Temple Lake (11,400 ± 630 yr B.P.) bracket the age of the Temple Lake moraine, suggesting that the moraine formed in the late Pleistocene. This terminal Pleistocene readvance may be represented at lower elevations by the expansion of forest into intermontane basins 12,000 to 10,000 yr B.P. Vegetation in the Wind River Range responded to changing environmental conditions at the end of the Pleistocene. Following deglaciation, alpine tundra in the Temple Lake valley was replaced by a Pinus albicaulis parkland by about 11,300 ¹⁴C yr B.P. Picea and Abies, established by 10,600 14C yr B.P., grew with Pinus albicaulis in a mixed conifer forest at and up to 100 m above Rapid Lake for most of the Holocene. Middle Holocene summer temperatures were about 1.5°C warmer than today. By about 5400 ¹⁴C yr B.P. Pinus albicaulis and Abies became less prominent at upper treeline because of decreased winter snowpack and higher maximum summer temperatures. The position of the modern treeline was established by 3000 ¹⁴ C yr B.P. when Picea retreated downslope in response to Neoglacial cooling.     

Vegetation Dynamics in a Tidal Freshwater Wetland: A Long-Term Study at Differing Scales

Tidal freshwater wetlands are complex, species-rich ecosystems located at the interface between tidal estuaries and nontidal rivers. This study conducted on the Patuxent River estuary in Maryland was designed to assess vegetation dynamics over several decades to determine if there were directional changes in the dominant communities. Aerial photographs (1970, 1989, and 2007) documented broad-scale spatial changes in major plant communities. The coverage of areas dominated by Nuphar lutea and Phragmites australis expanded; mixed vegetation and scrub–shrub habitats were essentially unchanged; and Typha and Zizania aquatica communities fluctuated in coverage. Data collected between 1988 and 2010 from permanent plots and transects were used to examine fine-scale changes. Shifts in the importance of some species through time were observed, but there were no directional changes in community species composition. The lack of directional change as measured at a fine scale is characteristic of tidal freshwater wetlands in which variations in the abundance of individual species, especially annuals, are responsible for most short-term change in species composition. Changes in the composition of plant communities are interpreted as responses to variations in vertical accretion, stability of habitat types, invasive plant species, and herbivores. In the future, vegetation changes are likely to occur as a result of the intrusion of brackish water and increased flooding associated with global climate change and sea level rise. This long-term study establishes a baseline from which potential future changes to tidal freshwater wetlands can be better understood.