The toxicological interaction between ocean acidity and metals in coastal meiobenthic copepods

Increased atmospheric CO₂ concentrations are causing greater dissolution of CO₂ into seawater, and are ultimately responsible for today’s ongoing ocean acidification. We manipulated seawater acidity by addition of HCl and by increasing CO₂ concentration and observed that two coastal harpacticoid copepods, Amphiascoides atopus and Schizopera knabeni were both more sensitive to increased acidity when generated by CO₂. The present study indicates that copepods living in environments more prone to hypercapnia, such as mudflats where S. knabeni lives, may be less sensitive to future acidification. Ocean acidification is also expected to alter the toxicity of waterborne metals by influencing their speciation in seawater. CO₂ enrichment did not affect the free-ion concentration of Cd but did increase the free-ion concentration of Cu. Antagonistic toxicities were observed between CO₂ with Cd, Cu and Cu free-ion in A. atopus. This interaction could be due to a competition for H⁺ and metals for binding sites.     

On the pair-instability supernovae and gamma-ray burst phenomenon

We present a model of a gamma-ray burst (GRB) related to “very massive” stars. In the framework of our model, the GRB phenomenon is a result of helium burning in degenerate conditions in a massive star (≳130 M _⊙), in which the thermal nuclear burning occurs in the deflagration regime and has a pulsating temporal pattern. The shock runs away from the burning (reaction) zone, which leads to the development of a coronal outflow (jet-like) structure. In our scenario the GRB observable prompt fast rise and decay part can be a result of photon propagation through the hot corona (Comptonization photosphere) of the star. On the other hand, the GRB afterglow is a cooling phase of the expanding and outflowing envelope. Presumably, the X-ray part of the GRB emergent spectrum is formed due to upscattering of soft photons of outer layers of the star off hot coronal electrons, and thus it should have a specific shape of the Comptonization spectrum.     

Soil erosion and sediment transport in Tanzania: Part II – sedimentological evidence of phased land degradation

Soil resources in parts of Tanzania are rapidly being depleted by increased rates of soil erosion and downstream sediment transport, threatening ecosystem health, water and livelihood security in the region. However, incomplete understanding to what effect the dynamics of soil erosion and sediment transport are responding to land-use changes and climatic variability are hindering the actions needed to future-proof Tanzanian land-use practices. Complementary environmental diagnostic tools were applied to reconstruct the rates and sources of sedimentation over time in three Tanzanian river systems that have experienced changing land use and climatic conditions. Detailed historical analysis of sediment deposits revealed drastic changes in sediment yield and source contributions. Quantitative sedimentation reconstruction using radionuclide dating showed a 20-fold increase in sediment yield over the past 120 years. The observed dramatic increase in sediment yield is most likely driven by increasing land-use pressures. Deforestation, cropland expansion and increasing grazing pressures resulted into accelerating rates of sheet erosion. A regime shift after years of progressive soil degradation and convergence of surface flows resulted into a highly incised landscape, where high amounts of eroded soil from throughout the catchment are rapidly transported downstream by strongly connected ephemeral drainage networks. By integrating complementary spatial and temporal evidence bases, this study demonstrated links between land-use change, increased soil erosion and downstream sedimentation. Such evidence can guide stakeholders and policy makers in the design of targeted management interventions to safeguard future soil health and water quality.     

An Alternative Protocol for Single Zircon Dissolution with Application to (U‐Th‐Sm)/He Thermochronometry

Zircon (U‐Th‐Sm)/He (ZHe) thermochronometry is a powerful tool that has been widely used in geology to constrain the exhumation histories of orogens. In this study, we present an alternative protocol for dissolving zircon grains for determination of parent nuclides. This new alkali fusion procedure developed at the SARM (Service d'Analyse des Roches et des Minéraux) in Nancy, France, is fast (requiring only 2 d, including cleaning steps) and offers several advantages over conventional methods by avoiding: (i) use of HF pressure dissolution and (ii) complete removing of grains from the metal microvials. After dissolution, U, Th and Sm were measured using an ICP‐MS. We tested the new procedure on two different ZHe reference materials, the Fish Canyon Tuff and Buluk Tuff; these provided precision values for ZHe‐age estimations of 9 and 6% (1s), respectively. In addition, using this method, zircons from the Buluk Tuff are shown to be chemically more homogenous and more suitable for assessing the uncertainty of the entire integrated procedure.     

Intra‐crater sedimentary deposits at the Haughton impact structure,Devon Island,Canadian High Arctic

Abstract— Detailed field mapping has revealed the presence of a series of intra‐crater sedimentary deposits within the interior of the Haughton impact structure, Devon Island, Canadian High Arctic. Coarse‐grained, well‐sorted, pale gray lithic sandstones (reworked impact melt breccias) unconformably overlie pristine impact melt breccias and attest to an episode of erosion, during which time significant quantities of impact melt breccias were removed. The reworked impact melt breccias are, in turn, unconformably overlain by paleolacustrine sediments of the Miocene Haughton Formation. Sediments of the Haughton Formation were clearly derived from pre‐impact lower Paleozoic target rocks of the Allen Bay Formation, which form the crater rim in the northern, western, and southern regions of the Haughton structure. Collectively, these field relationships indicate that the Haughton Formation was deposited up to several million years after the formation of the Haughton crater and that they do not, therefore, represent an immediate, post‐impact crater lake deposit. This is consistent with new isotopic dating of impactites from Haughton that indicate an Eocene age for the impact event (Sherlock et al. 2005). In addition, isolated deposits of post‐Miocene intra‐crater glacigenic and fluvioglacial sediments were found lying unconformably over remnants of the Haughton Formation, impact melt breccias, and other pre‐impact target rock formations. These deposits provide clear evidence for glaciation at the Haughton crater. The wealth and complexity of geological and climatological information preserved as intra‐crater deposits at Haughton suggests that craters on Mars with intra‐crater sedimentary records might present us with similar opportunities, but also possibly significant challenges.     

Crowdsourcing a cyclist perspective on suggested recreational paths in real-world networks

ABSTRACT

Routing and navigation services for leisure activities are conditioned by special needs and trade-offs. The advent of online communities and large crowdsourced datasets offers opportunities to improve the adoption of a user’s perspective in these suggested paths. This paper focuses on achieving two goals. First, the presented methodology analyses a dataset of 190,610 historical GPS traces to gain insights into the appreciation or attractiveness of each edge in a real-world network for a specific leisure activity (i.e. road cycling). Second, as literature on these leisure activities is still sparse, we want to create a thorough understanding of the activities at hand for future work. An appreciation model is proposed and the spread of this score is analyzed in shortest-path alternatives of popular routing engines for this activity. This analysis successfully discriminates these shortest paths based on the scoring value and three morphological parameters of the path. However, the robustness of the model should be improved to ensure the viability of the proposed approach in future work. More specifically, further research on the local optimality of the route choices will be imperative.     

Coastal response to the Holocene transgression in the Bahamas: episodic sedimentation versus continuous sea-level rise

Sedimentological and petrographic study of Holocene deposits in the Eastern Bahamas shows that sedimentation occurred episodically during this period of continually rising sea-level.

The Holocene stratigraphic record exposed on the islands of San Salvador, Lee Stocking and Cat consists of two distinctive units separated by a paleosol: (1) 5000 year-old oolitic eolianites deposited when sea-level was lower than today, and (2) 3000 to 500 year-old bioclastic paleo-beaches and dunes that are congruent with the present stand of sea-level.

A five-stage model that reconciles intermittent sedimentation pattern with continuous sea-level rise is presented. Pre-Holocene topography and changes in the rate of the transgression seem to regulate local⁴ hydrodynamic conditions, which in turn control onset and offset of sedimentary processes.

This Holocene example of episodic sedimentation during an uninterrupted transgression should be considered when studying ancient discontinuities that are systematically interpreted in terms of relative sea-level fall.     

Anharmonicity and high-temperature heat capacity of crystals: the examples of Ca2GeO4, Mg2GeO4 and CaMgGeO4 olivines

Drop-calorimetry determinations of the isobaric heat capacity (C_P) of Mg₂GeO₄, Ca₂GeO₄ and CaMgGeO₄ have been made up to 1700 K. The thermal expansion coefficient (α) of these olivine germanates has been determined from high-temperature X-ray measurements up to 1500 K. From these measurements and available compressibility data, one calculates that the isochoric heat capacity (C_V) exceeds the harmonic limit of Dulong and Petit above 1000–1200 K. Such an intrinsic anharmonic behaviour can be accounted for by introducing anharmonic parameters a_i=(? ln v _i/?T)_V in vibrational modelling of C_V. These parameters are calculated from pressure and temperature shifts of the vibrational frequencies as measured by Raman spectroscopy up to 10 GPa at room temperature and up to 1300 K at 1 bar. A comparison of the Raman spectra of the three germanates with those of natural olivines justifies once again the use of germanates as silicate analogues. Extensive Ca,Mg disordering likely takes place in CaMgGeO₄, beginning at about 1100 K and leading to unusually high increases of the heat capacity and thermal expansion coefficient.