Speciation of naturally-accumulated uranium in an organic-rich soil of an alpine region (Switzerland)

Very high concentrations of uranium (up to 4000 ppm) were found in a natural soil in the Dischma valley, an alpine region in the Grisons canton in Switzerland. The goal of this study was to examine the redox state and the nature of uranium binding in the soil matrix in order to understand the accumulation mechanism. Pore water profiles collected from Dischma soil revealed the establishment of anoxic conditions with increasing soil depth. A combination of chemical extraction methods and spectroscopy was applied to characterize the redox state and binding environment of uranium in the soil. Bicarbonate extraction under anoxic conditions released most of the uranium indicating that uranium occurs predominantly in the hexavalent form. Surprisingly, the uranium redox state did not vary greatly as a function of depth. X-ray absorption near edge spectroscopy (XANES), confirmed that uranium was present as a mixture of U(VI) and U(IV) with U(VI) dominating. Sequential extractions of soil samples showed that the dissolution of solid organic matter resulted in the simultaneous release of the majority of the soil uranium content (>95%). Extended X-ray absorption fine structure (EXAFS) spectroscopy also revealed that soil-associated uranium in the soil matrix was mainly octahedrally coordinated, with an average of 1.7 axial (at about 1.76 Å) and 4.6 to 5.3 equatorial oxygen atoms (at about 2.36 Å) indicating the dominance of a uranyl-like (UO₂²⁺) structure presumably mixed with some U(IV). An additional EXAFS signal (at about 3.2 Å) identified in some spectra suggested that uranium was also bound (via an oxygen atom) to a light element such as carbon, phosphorus or silicon. Gamma spectrometric measurements of soil profiles failed to identify uranium long-life daughter products in the soil which is an indication that uranium originates elsewhere and was transported to its current location by water. Finally, it was found that the release of uranium from the soil was significantly promoted at very low pH values (pH 2) and increased with increasing pH values (between pH 5 and 9).     

Consolidation with threshold gradients

Evidence for threshold gradients is reviewed. The consolidation problem, with threshold gradient, is properly formulated and solved numerically. An approximate analytical solution is also developed. The influence of a threshold gradient on the time rate of settlement is examined, and it is shown that by modifying the definition of the degree of consolidation a good approximation to the threshold gradient problem can be obtained directly from the Terzaghi solution. It is also shown that threshold gradients will have no influence on odometer testing and their effect is, therefore, to reduce the primary compression below that predicted from standard tests.     

Diet of Haplognathia ruberrima (Gnathostomulida) in a Caribbean marine mangrove

Haplognathia ruberrima is a cosmopolitan gnathostomulid species found in sulfur bacterial mats in mangroves in Guadeloupe (French West Indies). Haplognathia ruberrima presents a δ¹³C value lower than all measured meiofaunal grazers and lower than the available measured food sources of this environment. This low δ¹³C value can not be due to specific ingestion of ¹³C‐depleted methanogenic bacteria because abundances of those bacteria are reduced in surficial and deep sediments as revealed by δ¹³C of bacterial fatty acid. According to scanning electron microscope observations, no bacterial ectosymbionts were observed at the surface of the gnathostomulids, and transmission electron microscope views revealed the absence of bacterial endosymbionts. Energy‐dispersive X‐ray spectroscopy analysis detected low levels of sulfur (0.32%±0.8) in biological tissues of H. ruberrima, confirming the absence of thioautotrophic bacterial symbionts in these animals. Consequently, the low δ¹³C value of H. ruberrima can not be due to the presence of sulfur‐oxidizing symbionts but more probably to the selective and exclusive consumption of free‐living, sulfur‐oxidizing bacteria.     

Hydrodynamic time parameters response to meteorological and physical forcings: toward a stagnation risk assessment device in coastal areas

Ocean Dynamics - Identifying zones of stagnation and deposition of terrigenous matter or contaminants induced by human activity is a key issue in coastal areas. In this paper, circulation processes...     

A Comprehensive Framework for Intrinsic OpenStreetMap Quality Analysis

OpenStreetMap (OSM) is one of the most popular examples of a Volunteered Geographic Information (VGI) project. In the past years it has become a serious alternative source for geodata. Since the quality of OSM data can vary strongly, different aspects have been investigated in several scientific studies. In most cases the data is compared with commercial or administrative datasets which, however, are not always accessible due to the lack of availability, contradictory licensing restrictions or high procurement costs. In this investigation a framework containing more than 25 methods and indicators is presented, allowing OSM quality assessments based solely on the data's history. Without the usage of a reference data set, approximate statements on OSM data quality are possible. For this purpose existing methods are taken up, developed further, and integrated into an extensible open source framework. This enables arbitrarily repeatable intrinsic OSM quality analyses for any part of the world.