Trace-element-rich brines in eclogitic veins: implications for fluid composition and transport during subduction

Primary and pseudosecondary fluid inclusions occur in oscillatory-and sector-zoned omphacite in eclogitic veins from the Monviso ophiolitic complex in the Western Alps. The inclusions contain aqueous brines and daughter crystals of halite, sylvite, calcite, dolomite, albite, anhydrite and/or gypsum, barite, baddeleyite, rutile, sphene, Fe oxides, pyrite and monazite. This daughter mineral suite indicates high solubilites of Na, K, Ca, Mg, Fe, Zr, Ti, P, Ba, Ce, La, Th, and S species and provides direct evidence for transport of high-fieldstrenght, large-ion-lithophile, and light-rare-earth elements as dissolved species during subduction. Fluid-inclusion heterogeneities preserved within and between adjacent grains in the veins, however, suggest that the scale of fluid equilibration was small. A crack-seal geometry in some of the veins implies that fluid release in pulses rather than steady flow controlled mineral deposition and growth in the veins. From these observations, we develop a model of fluid release and entrapment in which pulses of fluid are associated in time with increments of shear and tensile failure; the rate of fluid release and the reduction in porosity both depend on the rate of plastic flow. Vein fluids may initially be derived from decreptitation of early fluid inclusions in the host eclogites, Small-scale fluid heterogeneities implied by the fluid inclusions in the veins are best interpreted in terms of limited fluid flow, and hence limited metasomatism. We conclude that element recycling into the mantle wedge during subduction will depend at least as strongly on fluid transport mechanisms as on element solubilities in the fluid phase. At Monviso, despite evidence for high trace element solubilities in saline brines, the elements were not removed from the downgoing slab prior to teaching depths of 40 km.     

Measurement of natural stresses in a Provence mine (Southern France)

Stress measurements were carried out in the Arc syncline using drifs in a lignite mine. Eleven sites were investigated using the flat jack and hydraulic fracturing (or stimulating) methods. Two stress states were found to coexist, one isotropic, the other highly anisotropic. The orientations of the principal stresses are not homogeneous and an orientation ranging from E-W to NE-SW predominates locally. This does not accord with the regional stress field. The vertical stresses are systematically underestimated.     

应用各种示踪剂研究岩溶泉系统的补给边界

应用三种化学示踪剂,对桂林岩溶水文地质试验场“31号泉系统”的补给边界进行了研究。试验在雨期进行,示踪剂分别是降雨后投入落水洞随表层岩溶水带入地下;或在降雨前投入无水的落水洞中,待降雨后由地表产流带入地下。 试验表明,氯化锌、钼酸铵是较理想的示踪剂,地下水速度为4～250米/小时,速度差可能是由于包气带岩溶含水介质渗透性和水力坡度不同所致;泉口历时浓度曲线常呈多峰型,多是由于降雨脉冲影响所致;峰丛区高程不等的洼地多通道补给山边泉,峰丛区含水介质结构具有叠置性,即水平方向多通道,垂直方向多层次,故水均衡计算不可忽视;“31号泉系统”的补给边界,通过圈定有水力连系之洼地的地表分水岭来确定。      

Fluid composition and evolution in coesite-bearing rocks (Dora-Maira massif,Western Alps): implications for element recycling during subduction

Fluid inclusions and F, Cl concentration of hydrous minerals were analysed in the coesite-pyrope quartzite, the interlayered jadeite quartzite and their country-rock gneiss from the Dora-Maira massif using a combination of microthermometry, Raman spectrometry, synchrotron X-ray microfiuorescence and electron microprobe analysis. Three populations of fluid inclusions were recognized texturally and can be related to distinct metamorphic stages. A low-salinity aqueous fluid occurs in the retrogressed country gneiss and as late secondary inclusions in jadeite quartzite and chloritized pyrope. An earlier secondary population is found in matrix quartz of the jadeite- and pyro-pe-quartzites. This population can be related to the early decompression and so to incipient breakdown of garnet into phlogopite-bearing assemblages. The inclusion fluid is highly saline (up to 84 wt% equivalent NaCl) and contains Na, Ca, Fe, Cu and Zn as major cations. In pyrope quartzite, additional K was found in these brines, which locally coexist with CO₂-rich inclusions. The oldest fluid inclusions are preserved in kyanite grains included in fresh pyrope and in pyrope itself. In pyrope, all inclusions have decrepitated and contain magnesite, an Mg-phosphate, sheet-silicate(s), a chloride and an opaque phase, with no fluid preser ved. In contrast, the kyanite inclusions in pyrope preserve primary H₂O-CO₂ low-salinity fluid inclusions, probably owing to the low compressibility of the kyanite inclusions and host garnet. In spite of in-situ re-equilibration, these inclusions can be interpreted as relics of the dehydration fluid that attended pyrope growth. These correlations between textural and chemical fluid inclusion data and metamorphic stages are consistent with the fluid composition calculated from the halogen content of different generations of phlogopite and biotite. The preservation of different fluid compositions, both in time and space, is evidence for local control and possibly origin of the fluids, in agreement with isotopic data. These results, in particular the absence of CO₂ in the jadeite quartzite, are best interpreted in terms of a fluid-melt system evolution. With increasing metamorphism, partitioning of H₂O, Na, Ca, Fe and heavy metals into melt (jadeite quartzite) and Mg, Na/K, F, CO₂ and P(?) into a residual aqueous fluid can account for depletion in Na, Ca and Fe of the pyrope quartzite. During the retrograde path, a _{H 2 O} rose as melt crystallized, generating the two populations of hypersaline and water-rich fluids that were highly reactive to pyrope. The process of fluid-melt interaction envisioned here coupled with models of melt extraction in subduction zones provides an attractive opportunity for the instantaneous ( < 1 Ma) and selective transport of elements between a downgoing slab and the overlying mantle wedge.     

Speciation of naturally-accumulated uranium in an organic-rich soil of an alpine region (Switzerland)

Very high concentrations of uranium (up to 4000 ppm) were found in a natural soil in the Dischma valley, an alpine region in the Grisons canton in Switzerland. The goal of this study was to examine the redox state and the nature of uranium binding in the soil matrix in order to understand the accumulation mechanism. Pore water profiles collected from Dischma soil revealed the establishment of anoxic conditions with increasing soil depth. A combination of chemical extraction methods and spectroscopy was applied to characterize the redox state and binding environment of uranium in the soil. Bicarbonate extraction under anoxic conditions released most of the uranium indicating that uranium occurs predominantly in the hexavalent form. Surprisingly, the uranium redox state did not vary greatly as a function of depth. X-ray absorption near edge spectroscopy (XANES), confirmed that uranium was present as a mixture of U(VI) and U(IV) with U(VI) dominating. Sequential extractions of soil samples showed that the dissolution of solid organic matter resulted in the simultaneous release of the majority of the soil uranium content (>95%). Extended X-ray absorption fine structure (EXAFS) spectroscopy also revealed that soil-associated uranium in the soil matrix was mainly octahedrally coordinated, with an average of 1.7 axial (at about 1.76 Å) and 4.6 to 5.3 equatorial oxygen atoms (at about 2.36 Å) indicating the dominance of a uranyl-like (UO₂²⁺) structure presumably mixed with some U(IV). An additional EXAFS signal (at about 3.2 Å) identified in some spectra suggested that uranium was also bound (via an oxygen atom) to a light element such as carbon, phosphorus or silicon. Gamma spectrometric measurements of soil profiles failed to identify uranium long-life daughter products in the soil which is an indication that uranium originates elsewhere and was transported to its current location by water. Finally, it was found that the release of uranium from the soil was significantly promoted at very low pH values (pH 2) and increased with increasing pH values (between pH 5 and 9).     

An empirical approach to estimating population parameters from censored fracture-length distributions

Most fracture data sets are length-censored because of incomplete exposure at the surface, so estimating values of parameters of the sampled populations is difficult. Unless the form of the distribution function of the population is known, or one which is analytically tractable is assumed, length-censoring presents formidable problems in determining population parameters. Tests conducted on experimental fracture patterns developed in clay samples subjected to simple shear loading are the basis of a distribution-free way to estimate population parameters. Comparison of random samples of censored and uncensored fracture lengths shows that a useful, homogeneous data set consists of those cracks which lie entirely within the sampling area (two-ended cracks). The properties of this data set can be used to estimate the mean and variance of uncensored data. Estimates of the maximum fracture length of uncensored data, using the variance and maximum length of these two-ended cracks, show good agreement with measured values. Knowledge of the mean, variance, and maximum value of fracture-length populations are of interest in engineering and hydraulic studies, as well as in remote sensing studies of the Earth and other planets. Application of these results to data on rock masses are subject to the caveat that different crack-growth mechanisms in clay and rock may affect the accuracy of the calculations.     

The role of the intra-daily SST variability in the Indian monsoon variability and monsoon-ENSO–IOD relationships in a global coupled model

The impact of diurnal SST coupling and vertical oceanic resolution on the simulation of the Indian Summer Monsoon (ISM) and its relationships with El Ni?o-Southern Oscillation (ENSO) and Indian Ocean Dipole (IOD) events are studied through the analysis of four integrations of a high resolution Coupled General Circulation Model (CGCM), but with different configurations. The only differences between the four integrations are the frequency of coupling between the ocean and atmosphere for the Sea Surface Temperature (SST) parameter (2 vs. 24?h coupling) and/or the vertical oceanic resolution (31 vs. 301 levels) in the CGCM. Although the summer mean tropical climate is reasonably well captured with all the configurations of the CGCM and is not significantly modified by changing the frequency of SST coupling from once to twelve per day, the ISM–ENSO teleconnections are rather poorly simulated in the two simulations in which SST is exchanged only once per day, independently of the vertical oceanic resolution used in the CGCM. Surprisingly, when 2?h SST coupling is implemented in the CGCM, the ISM–ENSO teleconnection is better simulated, particularly, the complex lead-lag relationships between the two phenomena, in which a weak ISM occurs during the developing phase of an El Ni?o event in the Pacific, are closely resembling the observed ones. Evidence is presented to show that these improvements are related to changes in the characteristics of the model’s El Ni?o which has a more realistic evolution in its developing and decaying phases, a stronger amplitude and a shift to lower frequencies when a 2-hourly SST coupling strategy is implemented without any significant changes in the basic state of the CGCM. As a consequence of these improvements in ENSO variability, the lead relationships between Indo-Pacific SSTs and ISM rainfall resemble the observed patterns more closely, the ISM–ENSO teleconnection is strengthened during boreal summer and ISM rainfall power spectrum is in better agreement with observations. On the other hand, the ISM–IOD teleconnection is sensitive to both SST coupling frequency and the vertical oceanic resolution, but increasing the vertical oceanic resolution is degrading the ISM–IOD teleconnection in the CGCM. These results highlight the need of a proper assessment of both temporal scale interactions and coupling strategies in order to improve current CGCMs. These results, which must be confirmed with other CGCMs, have also important implications for dynamical seasonal prediction systems or climate change projections of the monsoon.     

Impact of intra-daily SST variability on ENSO characteristics in a coupled model

This paper explores the impact of intra-daily Sea Surface Temperature (SST) variability on the tropical large-scale climate variability and differentiates it from the response of the system to the forcing of the solar diurnal cycle. Our methodology is based on a set of numerical experiments based on a fully global coupled ocean–atmosphere general circulation in which we alter (1) the frequency at which the atmosphere sees the SST variations and (2) the amplitude of the SST diurnal cycle. Our results highlight the complexity of the scale interactions existing between the intra-daily and inter-annual variability of the tropical climate system. Neglecting the SST intra-daily variability results, in our CGCM, to a systematic decrease of 15% of El Ni?o—Southern Oscillation (ENSO) amplitude. Furthermore, ENSO frequency and skewness are also significantly modified and are in better agreement with observations when SST intra-daily variability is directly taken into account in the coupling interface of our CGCM. These significant modifications of the SST interannual variability are not associated with any remarkable changes in the mean state or the seasonal variability. They can therefore not be explained by a rectification of the mean state as usually advocated in recent studies focusing on the diurnal cycle and its impact. Furthermore, we demonstrate that SST high frequency coupling is systematically associated with a strengthening of the air-sea feedbacks involved in ENSO physics: SST/sea level pressure (or Bjerknes) feedback, zonal wind/heat content (or Wyrtki) feedback, but also negative surface heat flux feedbacks. In our model, nearly all these results (excepted for SST skewness) are independent of the amplitude of the SST diurnal cycle suggesting that the systematic deterioration of the air-sea coupling by a daily exchange of SST information is cascading toward the major mode of tropical variability, i.e. ENSO.     

Impact of climate change on the hydrogeology of two basins in northern France

This study presents an analysis of climate-change impacts on the water resources of two basins located in northern France, by integrating four sources of uncertainty: climate modelling, hydrological modelling, downscaling methods, and emission scenarios. The analysis focused on the evolution of the water budget, the river discharges and piezometric heads. Seven hydrological models were used, from lumped rainfall-discharge to distributed hydrogeological models, and led to quite different estimates of the water-balance components. One of the hydrological models, CLSM, was found to be unable to simulate the increased water stress and was, thus, considered as an outlier even though it gave fair results for the present day compared to observations. Although there were large differences in the results between the models, there was a marked tendency towards a decrease of the water resource in the rivers and aquifers (on average in 2050 about ?14 % and ?2.5 m, respectively), associated with global warming and a reduction in annual precipitation (on average in 2050 +2.1 K and ?3 %, respectively). The uncertainty associated to climate models was shown to clearly dominate, while the three others were about the same order of magnitude and 3–4 times lower. In terms of impact, the results found in this work are rather different from those obtained in a previous study, even though two of the hydrological models and one of the climate models were used in both studies. This emphasizes the need for a survey of the climatic-change impact on the water resource.     

Intraseasonal SST-precipitation relationship and its spatial variability over the tropical summer monsoon region

The SST-precipitation relationship in the intraseasonal variability (ISV) over the Asian monsoon region is examined using recent high quality satellite data and simulations from a state of the art coupled model, the climate forecast system version 2 (CFSv2). CFSv2 demonstrates high skill in reproducing the spatial distribution of the observed climatological mean summer monsoon precipitation along with its interannual variability, a task which has been a conundrum for many recent climate coupled models. The model also exhibits reasonable skill in simulating coherent northward propagating monsoon intraseasonal anomalies including SST and precipitation, which are generally consistent with observed ISV characteristics. Results from the observations and the model establish the existence of spatial variability in the atmospheric convective response to SST anomalies, over the Asian monsoon domain on intraseasonal timescales. The response is fast over the Arabian Sea, where precipitation lags SST by ~5 days; whereas it is slow over the Bay of Bengal and South China Sea, with a lag of ~12 days. The intraseasonal SST anomalies result in a similar atmospheric response across the basins, which consists of a destabilization of the bottom of the atmospheric column, as observed from the equivalent potential temperature anomalies near the surface. However, the presence of a relatively strong surface convergence over the Arabian Sea, due to the presence of a strong zonal gradient in SST, which accelerates the upward motion of the moist air, results in a relatively faster response in terms of the local precipitation anomalies over the Arabian Sea than over the Bay of Bengal and South China Sea. With respect to the observations, the ocean–atmosphere coupling is well simulated in the model, though with an overestimation of the intraseasonal SST anomalies, leading to an exaggerated SST-precipitation relationship. A detailed examination points to a systematic bias in the thickness of the mixed layer of the ocean model, which needs to be rectified. A too shallow (deep) mixed layer enhances (suppress) the amplitude of the intraseasonal SST anomalies, thereby amplifying (lessening) the ISV and the active-break phases of the monsoon in the model.