Anorthosite formation by plagioclase flotation in ferrobasalt and implications for the lunar crust

The Sept Iles layered intrusion (Quebec, Canada) is dominated by a basal Layered Series made up of troctolites and gabbros, and by anorthosites occurring (1) at the roof of the magma chamber (100-500 m-thick) and (2) as cm- to m-size blocks in gabbros of the Layered Series. Anorthosite rocks are made up of plagioclase, with minor clinopyroxene, olivine and Fe-Ti oxide minerals. Plagioclase displays a very restricted range of compositions for major elements (An₆₈-An₆₀), trace elements (Sr: 1023-1071 ppm; Ba: 132-172 ppm) and Sr isotopic ratios (⁸⁷Sr/⁸⁶Sr_i: 0.70356-0.70379). This compositional range is identical to that observed in troctolites, the most primitive cumulates of the Layered Series, whereas plagioclase in layered gabbros is more evolved (An₆₀-An₃₈). The origin of Sept Iles anorthosites has been investigated by calculating the density of plagioclase and that of the evolving melts. The density of the FeO-rich tholeiitic basalt parent magma first increased from 2.70 to 2.75 g/cm³ during early fractionation of troctolites and then decreased continuously to 2.16 g/cm³ with fractionation of Fe-Ti oxide-bearing gabbros. Plagioclase (An₆₉-An₆₀) was initially positively buoyant and partly accumulated at the top of the magma chamber to form the roof anorthosite. With further differentiation, plagioclase (<An₆₀) became negatively buoyant and anorthosite stopped forming. Blocks of anorthosite (autoliths) even fell downward to the basal cumulate pile. The presence of positively buoyant plagioclase in basal troctolites is explained by the low efficiency of plagioclase flotation due to crystallization at the floor and/or minor plagioclase nucleation within the main magma body. Dense mafic minerals of the roof anorthosite are shown to have crystallized from the interstitial liquid.The processes related to floating and sinking of plagioclase in a large and shallow layered intrusion serve as a proxy to refine the crystallization model of the lunar magma ocean and explain the vertically stratified structure of the lunar crust, with (gabbro-)noritic rocks at the base and anorthositic rocks at the top. We propose that the lunar crust mainly crystallized bottom-up. This basal crystallization formed a mafic lower crust that might have a geochemical signature similar to the magnesian-suite without KREEP contamination, while flotation of some plagioclase grains produced ferroan anorthosites in the upper crust.     

Chloride and Boron behavior in fluids of Los Humeros geothermal field (Mexico): A model based on the existence of deep acid brine

Geothermal field Los Humeros, Mexico, is characterized by a high steam fraction in the well fluids, by extremely high B concentrations in separated water (grams per liter, with a magmatic B signature, δ¹¹B ± 2σ = −0.8 ± 1.6‰), by the absence of correlation between B and Cl concentrations and by positive correlation between B content in separated water and fluid enthalpy. Such behavior is consistent with the existence of moderately acid brine (pH 3–5) at depth with a high B concentration (500–600 mg/kg). In this case a 3-level model can be suggested for Los Humeros: (1) immature, moderately acid brine at depth which is boiling at a temperature ∼350 °C producing the HCl-bearing vapor with a high B content; (2) partial condensation of this vapor at the upper level accompanying water–rock interaction and neutralization; (3) formation of a shallow water-dominated aquifer above a lithologic low-permeability boundary as has been proposed by other authors. A thermochemical computer code has been used to model boiling of an aqueous fluid at 350 °C with 0.1 M of NaCl, 0.05 M of H₃BO₃ and variable amount of HCl (0.001–0.1 M), then a partial condensation of the produced vapor at 250 °C and then separation of the steam–water mixture at 150 °C. Results of simulation are in a qualitative agreement with the observed data.     

Les Montagnes Noires : cisaillement bordier méridional du bassin carbonifère de Châteaulin (Massif Armoricain,France). Caractéristiques structurales et métamorphiques

Résumé

L’évolution structurale et métamorphique de la zone des Montagnes Noires, qui borde vers le sud le bassin carbonifère de Châteaulin, est contrôlée par le fonctionnement d’un cisaillement trans-current dextre. Le caractère unique, mais progressif et inhomogène, de la déformation régionale d’âge carbonifère supérieur conduit à remettre en cause le concept d’une structuration hercynienne polyphasée et celui de « phase bretonne ».     

Bilan,fonctionnement et protection du système karstique de la Fontaine de Vaucluse (sud-est de la France)

Résumén

L’aquifère karstique de la célèbre Fontaine de Vaucluse a fait l’objet de nouvelles investigations hydrogéologiqurs dont les résultats portent sur la définition et le fonctionnement du système.

Les données géologiques (lithologie, structure) nous ont permis la délimitation d’un impluvium de 1115 km² dont l’altitude moyenne. 870 m, est confirmée par les traceurs naturels physico-chimiques et isotopiques.

Le bilan hydrique, faute d’un réseau météorologique représentatif, a été calculé à partir d’un modèle climatique par tranches d’altitude, qui utilise les gradients pluviométriques et thermiques régionaux. On montre alors que les 3/4 des pluies efficaces proviennent des zones situées au-dessus de l’altitude moyenne de l’impluvium.

Les études hydrodynamiques et physico-chimiques nous ont permis de démontrer la faible inertie du système malgré sa taille, donc sa bonne karstification, ce qui confirme à l’échelle de l’ensemble les observations spéléologiques ponctuelles du plateau et de l’émergence.

Malgré leur faible apport au débit total, les précipitations estivales marquent la chimie de l’émergence et interrompent ainsi la phase de tarissement.

La contribution de l’eau des réserves au débit est prépondérante : respectivement les 3/4 et les 2/3 des volumes annuels écoulés en 1981 et 1982.

Compte tenu de l’absence de sols et de terrains poreux de couverture, ainsi que du développement de la karstification, la vulnérabilité du système est grande. Aussi une attention particulière doit-elle être portée à l’aménagement de la zone montagnarde de l’impluvium dont le rôle est prépondérant dans l’alimentation du système.     

Floor-age constraining of a tectonic paroxysm of the Pyrenean orogen. Late Middle Eocene mammal age of a faulted karstic filling of the Quercy phosphorites,south-western France

Abstract

Breaking effects of a Pyrenean compressive tectonic phase are recognised in northern Pyrenean foreland, such as in the Quercy Jurassic limestone platform. The age of this phase still remains poorly constrained. In the so-called Quercy phosphorites area, within the Prajoux—Mémerlin paleokarst system near the city of Cajarc, a clay filling shows a strike slip fault effect, close to N-S direction. According to an analysis of the mammal fauna and inferred chronology of the polyphased paleokarst infilling, the age of the faulted clay is late Middle Eocene, with a mammal age estimate of 41.5 Ma. This provides reliable precise floor-age constraining for the involved sismo-tectonic paroxysm, seemingly related to the Pyrenean tectonic compressive phase. © 2000 Editions scientifiques et médicales Elsevier SAS     

Geostatistical Assessment of Ice Content Distribution Within the Glacier Bonnard

The Glacier Bonnard is a rock glacier located in the State of Valais, Switzerland. It overhangs a settlement and its slow downward constant creep constitutes an environmental hazard. It is therefore important to understand the glacier’s internal structure, particularly in terms of ice content, in order to evaluate its current global dynamic and future evolution. Following preliminary geophysical investigations, several boreholes have been drilled to measure the thickness of the glaciated mass and the vertical distribution of lithology and ice content. These new data are helpful in assessing the amount of ice within the Glacier Bonnard. Two geostatistical modeling approaches are considered: a direct modeling of ice content and an indirect approach linking together lithology and ice content by the use of the plurigaussian algorithm. Comparisons between these approaches are made in terms of ice content prediction and of global ice mass within the sampled area; they underline the benefit of the geostatistical modeling and particularly the advantages of the indirect approach.     

Characterizing atmospheric circulation signals in Greenland ice cores: insights from a weather regime approach

Greenland ice cores offer seasonal to annual records of δ¹⁸O, a proxy for precipitation-weighted temperature, over the last few centuries to millennia. Here, we investigate the regional footprints of the North Atlantic weather regimes on Greenland isotope and climate variability, using a compilation of 22 different shallow ice-cores and the atmospheric pressure conditions from the twentieth century reanalysis (20CR). As a first step we have verified that the leading modes of winter and annual δ¹⁸O are well correlated with oceanic (Atlantic multidecadal oscillation) and atmospheric [North Atlantic oscillation (NAO)] indices respectively, and also marginally with external forcings, thus confirming earlier studies. The link between weather regimes and Greenland precipitation, precipitation-weighted temperature and δ¹⁸O is further explored by using an isotope simulation from the LMDZ-iso model, where the 3-dimensional wind fields are nudged to those of 20CR. In winter, the NAO+ and NAO? regimes in LMDZ-iso produce the largest isotopic changes over the entire Greenland region, with maximum anomalies in the South. Likewise, the Scandinavian blocking and the Atlantic ridge also show remarkable imprints on isotopic composition over the region. To assess the robustness and model dependency of our findings, a second isotope simulation from the isotopic model is also explored. The percentage of Greenland δ¹⁸O variance explained by the ensemble of weather regimes is increased by a factor near two in both LMDZ-iso and IsoGSM when compared to the contribution of the NAO index only. Similarly, weather regimes provide a net gain in the δ¹⁸O variance explained of similar magnitude for the whole set of ice core records. Greenland δ¹⁸O also appears to be locally affected by the low-frequency variations in the centres of action of the weather regimes, with clearer imprints in the LMDZ-iso simulation. This study opens the possibility for reconstructing past changes in the frequencies of occurrence of the weather regimes, which would rely on the sensitive regions identified here, and the use of additional proxies over the North Atlantic region.     

The self-organizing map,a new approach to apprehend the Madden–Julian Oscillation influence on the intraseasonal variability of rainfall in the southern African region

The Madden–Julian Oscillation (MJO) is the major mode of intraseasonal variability (30–60 days) in the tropics, having large rainfall impacts globally, and possibly on southern Africa. However, the latter impact is not well understood and needs to be further explored. The life cycle of the MJO, known to be asymmetric, has been nevertheless analyzed usually through methods constrained by both linearity and orthogonality, such as empirical orthogonal function analysis. Here we explore a non-linear classification method, the self-organizing map (SOM), a type of artificial neural network used to produce a low-dimensional representation of high-dimensional datasets, to capture more accurately the life cycle of the MJO and its global impacts. The classification is applied on intraseasonal anomalies of outgoing longwave radiation within the tropical region over the 1980–2009 period. Using the SOM to describe the MJO is a new approach, complimentary to the usual real-time multivariate MJO index. It efficiently captures this propagative phenomenon and its seasonality, and is shown to provide additional temporal and spatial information on MJO activity. For each node, the subtropical convection is analyzed, with a particular focus on the southern Africa region. Results show that the convection activity over the central tropical Indian Ocean is a key factor influencing the intraseasonal convective activity over the southern African region. Enhanced (suppressed) convection over the central Indian Ocean tends to suppress (enhance) convection over the southern African region with a 10-day lag by modulating the moisture transport.     

Mean meridional currents in the central and eastern equatorial Atlantic

Ship-based acoustic Doppler current profiler (ADCP) velocity measurements collected by several major field programs in the tropical Atlantic are averaged and combined with estimates of the mean near-surface velocity derived from drifters and Argo float surface drifts (ADCP+D) to describe the mean cross-equatorial and vertical structure of the meridional currents along 23°W and 10°W. Data from moored ADCPs and fixed-depth current meters, a satellite-derived velocity product, and a global ocean reanalysis were additionally used to evaluate the mean ADCP+D meridional velocity. The dominant circulation features in the long-term mean ADCP+D meridional velocity in the upper 100 m are the tropical cells (TCs) located approximately between 5°S and 5°N, with near-surface poleward flow and subsurface equatorward flow that is stronger and shallower in the northern cell compared to the southern cell. The thickness of the surface limb of the TCs decreases and the northern cell is found to shift further south of the equator from the central to eastern tropical Atlantic. Analysis of two-season means estimated from the ship-based ADCP, near-surface drift, and moored velocity data, as well as the simulated fields, indicates that the maximum poleward velocity in the surface limb of the TCs intensifies during December–May along 23°W largely due to seasonal compensation between the geostrophic and ageostrophic (or wind-driven) components of the meridional velocity, whereas the maximum equatorward flow in the subsurface limb of the northern cell intensifies during June–November along both 23°W and 10°W due to the seasonality of the geostrophic meridional velocity.     

Field experiment in Soultz-sous-Forêts, 1993: Changes of the pattern of induced seismicity

The data of the known field experiment on water injection in the borehole were analyzed. Parameters of self-similarity of seismicity were estimated in comparison with the changes of water pressure. Changes of seismicity parameters that indicate the redistribution of the failure from lower scales to upper are revealed. The total number of earthquakes per series of the water initiation found to be depended exponentially on the water pressure and seismic activity maximum is delayed gradually relative to beginning of initiation. The growth of induced seismicity zone in time differs from diffusion model for water flow in the porous medium. Analysis carried out from laboratory data indicates that diffusion growth of the failure area may be realized in the dry specimen, without fluid. It could be assumed that both kinetic processes — water and the failure diffusion — can be significant for the development of seismicity induced by the water injection.