Tidal variability in benthic silicic acid fluxes and microphytobenthos uptake in intertidal sediment

Silicic acid (DSi) benthic fluxes play a major role in the benthic–pelagic coupling of coastal ecosystems. They can sustain microphytobenthos (MPB) development at the water–sediment interface and support pelagic diatoms when river DSi inputs decrease. DSi benthic fluxes have been studied at the seasonal scale but little is known about their dial variations. This study measured the amplitude of such variations in an intertidal area over an entire tidal cycle by following the alteration of DSi pore water concentrations at regular intervals over the flood/ebb period. Furthermore we independently estimated the potential DSi uptake by benthic diatoms and compared it to the variations of DSi pore water concentrations and fluxes. The microphytobenthos DSi demand was estimated from primary production measurements on cells extracted from the sediment. There were large changes in DSi pore water concentration and a prominent effect of tidal pumping: the DSi flushed out from the sediment at rising tide, occurs in a very short period of time, but plays a far more important role in fueling the ecosystem (800 μmol-Si m⁻² d⁻¹), than diffusive fluxes occurring throughout the rest of the tidal cycle (2 μmol-Si m⁻² d⁻¹). This process is not, to our knowledge, currently considered when describing the DSi cycling of intertidal sediments. Moreover, there was a large potential MPB requirement for DSi (812 μmol-Si m⁻² d⁻¹), similar to the advective flow periodically pumped by the incoming tide, and largely exceeded benthic diffusive fluxes. However, this DSi uptake by benthic diatoms is almost undetectable given the variation of DSi concentration profiles within the sediment.     

Environmental and Cultural Implications of Visitor Access in the Kimberley Region,Australia

The Kimberley coast in Australia's far north-west is the traditional country and home of a number of Indigenous groups and hosts some of the country's richest cultural heritage, most spectacular rock art, scenery and wildlife, making it an attractive tourism destination. A growing expedition cruise industry provides the main means of visitor access to remote coastal sites and offers excursions to shore-based attractions in what are mostly Aboriginal Reserve lands. In light of concerns about environmental and cultural site impacts resulting from increasing visitor numbers, this study examined biophysical site impacts along access trails to shore-based attractions and used qualitative methods to ascertain cultural impacts. The synthesis of the findings highlights that cultural concerns arising from visitor access without having sought traditional owner consent for such access, combined with a lack of traditional owner involvement in the planning, management or running of visitor activities, overshadow currently low environmental impacts of onshore expedition cruise activities. To overcome the continuing impasse regarding the issue of unsanctioned visitor access, the Kimberley urgently needs a coordinated approach by key stakeholders and the traditional owners which recognises and acknowledges the historical context. Such a process would facilitate tourism activities to become culturally sustainable.     

Growth mechanism of snowball garnets from the Lukmanier Pass area (Central Alps,Switzerland): a combined μCT/EPMA/EBSD study

For two decades, considerable efforts have been made to explain the formation of snowball garnets by either the rotational or non‐rotational models. On the basis of morphological, chemical and crystallographic evidence, this paper presents new data on snowball garnets showing that the formation of these microstructures can be explained by the combination of the two previously proposed mechanisms operating consecutively during garnet growth. The crystallization sequence of garnet revealed by Mn contouring and the distribution of crystallographic orientations within the spiral indicate that the final stages of garnet growth are controlled by post‐kinematic crystallization. However, some microstructural arguments plead for a rotational contribution during the first stages of growth. In this view, the overall spiral geometry is thought to overestimate the true amount of rotation experienced by the garnets. Results also reveal the existence of complex snowball garnets consisting of several grains formed from distinct nucleation sites.     

5. Prebiotic Chemistry – Biochemistry – Emergence of Life (4.4–2 Ga)

This chapter is devoted to a discussion about the difficulties and even the impossibility to date the events that occurred during the transition from non-living matter to the first living cells. Nevertheless, the attempts to devise plausible scenarios accounting for the emergence of the main molecular devices and processes found in biology are presented including the role of nucleotides at early stages (RNA world). On the other hand, hypotheses on the development of early metabolisms, compartments and genetic encoding are also discussed in relation with their role in extant living organisms. The nature of the Last Common Ancestor is also presented as well as hypotheses on the evolution of viruses. The following sections constitute a collection of independent articles providing a general overview of these aspects.     

Titan's 3-micron spectral region from ISO high-resolution spectroscopy

The near-infrared spectrum of Titan, Saturn's largest moon and one of the Cassini/Huygens' space mission primary targets, covers the 0.8 to 5 micron region in which it shows several weak CH₄ absorption regions, and in particular one centered near 2.75 micron. Due to the interference of telluric absorption, only part of this window region (2.9-3.1 μm) has previously been observed from the ground [Noll, K.S., Geballe, T.R., Knacke, R., Pendleton, F., Yvonne, J., 1996. Icarus 124, 625-631; Griffith, C.A., Owen, T., Miller, G.A., Geballe, T., 1998. Nature 395, 575-578; Griffith, C.A., Owen, T., Geballe, T.R., Rayner, J., Rannou, P., 2003. Science 300, 628-630; Geballe, T.R., Kim, S.J., Noll, K.S., Griffith, C.A., 2003. Astrophys. J. 583, L39-L42]. We report here on the first spectroscopic observations of Titan covering the whole 2.4-4.9 μm region by two instruments on board the Infrared Space Observatory (ISO) in 1997. These observations show the 2.75-μm window in its complete extent for the first time. In this study we have also used a high-resolution Titan spectrum in the 2.9-3.6 μm region taken with the Keck [Geballe, T.R., Kim, S.J., Noll, K.S., Griffith, C.A., 2003. Astrophys. J. 583, L39-L42; Kim, S.J., Geballe, T.R., Noll, K.S., Courtin, R., 2005. Icarus 173, 522-532] to infer information on the atmospheric parameters (haze extinction, single scattering albedo, methane abundance, etc.) by fitting the methane bands with a detailed microphysical model of Titan's atmosphere (updated from Rannou, P., McKay, C.P., Lorenz, R.D., 2003. Planet. Space Sci. 51, 963-976). We have included in this study an updated version of a database for the CH₄ absorption coefficients [STDS, Wenger, Ch., Champion, J.-P., 1998. J. Quant. Spectrosc. Radiat. Transfer 59, 471-480. See also http://www.u-bourgogne.fr/LPUB/TSM/sTDS.html for latest updates; Boudon, V., Champion, J.-P., Gabard, T., Loëte, M., Michelot, F., Pierre, G., Rotger, M., Wenger, Ch., Rey, M., 2004. J. Mol. Spectrosc. 228, 620-634]. For the atmosphere we find that (a) the haze extinction profile that best matches the data is one with higher (by 40%) extinction in the atmosphere with respect to Rannou et al. (2003) down to about 30 km where a complete cut-off occurs; (b) the methane mixing ratio at Titan's surface cannot exceed 3% on a disk-average basis, yielding a maximum CH₄ column abundance of 2.27 km-am in Titan's atmosphere. From the derived surface albedo spectrum in the 2.7-3.08 micron region, we bring some constraints on Titan's surface composition. The albedo in the center of the methane window varies from 0.01 to 0.08. These values, compared to others reported in the other methane windows, show a strong compatibility with the water ice spectrum in the near-infrared. Without confirming its existence from this work alone, our data then appear to be compatible with water ice. A variety of other ices, such as CO₂, NH₃, tholin material or hydrocarbon liquid cannot be excluded from our data, but an additional unidentified component with a signature around 2.74 micron is required to satisfy the data.     

Hydrologic prediction for urban watersheds with the Distributed Hydrology–Soil–Vegetation Model

Some relatively straightforward modifications to the Distributed Hydrology–Soil–Vegetation Model (DHSVM) are described that allow it to represent urban hydrological processes. In the modified model, precipitation that falls on impervious surfaces becomes surface runoff, and a spatially varying (depending on land cover) fraction of surface runoff is connected directly to the stream channel, with the remainder stored and slowly released to represent the effects of stormwater detention. The model was evaluated through application to Springbrook Creek watershed in a partially urbanized area of King County, Washington. With calibration, the modified DHSVM simulates hourly streamflow from these urbanized catchments quite well. It is also shown how the revised model can be used to study the effects of continuing urbanization in the much larger Puget Sound basin. Model simulations confirm many previous studies in showing that urbanization increases peak flows and their frequency, and decreases peak flow lag times. The results show that the urbanization parameterizations for DHSVM facilitate use of the model for prediction and/or reconstruction of a range of historic and future changes in land cover that will accompany urbanization as well as other forms of vegetation change. Copyright © 2008 John Wiley & Sons, Ltd.     

Lichenometry in the Cordillera Blanca, Peru: “Little Ice Age” moraine chronology

This paper is a comparison and compilation of lichenometric and geomorphic studies performed by two independent teams in the Cordillera Blanca, Peru, in 1996 and 2002 on 66 “Little Ice Age” moraines of 14 glaciers. Using eleven new control points, we recalibrated the initial rapid growth phase of the previously established Rhizocarpon subgenus Rhizocarpon growth curve. This curve was then used to estimate the age of “Little Ice Age” moraines. The time of deposition of the most prominent and numerous terminal and lateral moraines on the Pacific-facing side of the Cordillera Blanca (between AD 1590 and AD 1720) corresponds to the coldest and wettest phase in the tropical Andes as revealed by ice-core data. Less prominent advances occurred between AD 1780 and 1880.     

Corotational Tomography of Heliospheric Features Using Global Thomson Scattering Data

The Air Force/NASA Solar Mass Ejection Imager (SMEI) will provide two-dimensional images of the sky in visible light with high (0.1%) photometric precision, and unprecedented sky coverage and cadence. To optimize the information available from these images they must be interpreted in three dimensions. We have developed a Computer Assisted Tomography (CAT) technique that fits a three-dimensional kinematic heliospheric model to remotely-sensed Thomson scattering observations. This technique is designed specifically to determine the corotating background solar wind component from data provided by instruments like SMEI. Here, we present results from this technique applied to the Helios spacecraft photometer observations. The tomography program iterates to a least-squares solution of observed brightnesses using solar rotation, spacecraft motion and solar wind outflow to provide perspective views of each point in space covered by the observations. The corotational tomography described here is essentially the same as used by Jackson et al. (1998) for the analysis of interplanetary scintillation (IPS) observations. While IPS observations are related indirectly to the solar wind density through an assumed (and uncertain) relationship between small-scale density fluctuations and density, Thomson scattering physics is more straightforward, i.e., the observed brightness depends linearly on the solar wind density everywhere in the heliosphere. Consequently, Thomson scattering tomography can use a more direct density-convergence criterion to match observed Helios photometer brightness to brightness calculated from the model density. The general similarities between results based on IPS and Thomson scattering tomography validate both techniques and confirm that both observe the same type of solar wind structures. We show results for Carrington rotation 1653 near solar minimum. We find that longitudinally segmented dense structures corotate with the Sun and emanate from near the solar equator. We discuss the locations of these dense structures with respect to the heliospheric current sheet and regions of activity on the solar surface.     

Noble gas measurements in the L/LL5 chondrite Knyahinya

Abstract— The L/LL5 chondrite Knyahinya had an approximately spherical shape, and as it experienced a single stage exposure history, it represents a very interesting object to study depth profiles of cosmic-ray-produced nuclide concentrations. Such data are required to improve and to validate model calculations of production rates. We report Ne, Ar, Kr and Xe isotopic abundances in five bulk samples. The adopted procedure of noble gas extraction included two pyrolysis steps at 450 °C and 650 °C, respectively, followed by a combustion step in pure O₂ at 650 °C before melting the sample. This procedure allows for the separation of a significant fraction of the trapped Kr and Xe, leading to an enrichment of the cosmic-ray produced component, which is released in the melting step. The isotopic composition of the trapped Xe component measured in the combustion step is found to be identical with the OC-Xe composition (Lavielle and Marti, 1992) and supports the suggestion that ordinary chondrites formed in a homogeneous trapped noble gas reservoir. Cosmic-ray produced Kr and Xe components and depth profiles were measured, including for the first time a ⁸¹Kr profile. The calculated exposure age of 39.5 ± 1.0 Ma, based on the ⁸¹Kr-Kr method, is found to be in excellent agreement with previous determinations. The concentrations of trapped and fissiogenic noble gas components are clearly lower than those generally observed in type 5 ordinary chondrites and may suggest diffusion losses before a meter-sized object was exposed to the cosmic radiation.