A Laboratory Experimental Study of the Hydromechanical Behavior of Boom Clay

This paper reports some results of a large experimental program on Boom Clay conducted in Grenoble in the framework of the European project SELFRAC. The program included isotropic compression up to relatively high stress, drained triaxial compression tests at different cell pressures, as well as permeability measurements under isotropic and deviatoric stress. Local measurement of axial and radial displacements allowed the detection of strain localization during deviatoric loading. The permeability of Boom Clay is found to depend on the mean effective stress. The response of Boom Clay during deviatoric loading appears to be strongly affected by the swelling experienced during the isotropic stage preceding triaxial compression. The rate of swelling decreases with isotropic stress. The longer the swelling before shear, more the response under shear becomes ductile and the lower the initial stiffness. Permeability depends on the mean effective stress and it is found to decrease of about two orders of magnitude when the mean stress increases from 1 to 32 MPa. Permeability during shear loading is essentially constant and does not seem to be affected by strain localization. These results are complemented by a few observations obtained using X-ray microtomography in the framework of the more recent European project TIMODAZ. These findings illustrate the impact of pre-existing inclusions and fissures on specimen deformation upon deviatoric loading in the laboratory.     

Review of the El Soplao Amber Outcrop,Early Cretaceous of Cantabria,Spain

<正>El Soplao outcrop,an Early Cretaceous amber deposit recently discovered in northern Spain (Cantabria),has been shown to be the largest site of amber with arthropod inclusions that has been found in Spain so far.Relevant data provided herein for biogeochemistry of the amber,palynology,taphonomy and arthropod bioinclusions complement those previously published.This set of data suggests at least two botanical sources for the amber of El Soplao deposit.The first(type A amber)strongly supports a source related to Cheirolepidiaceae,and the second(type B amber)shows non-specific conifer biomarkers.Comparison of molecular composition of type A amber with Frenelopsis leaves(Cheirolepidiaceae)strongly suggests a biochemical affinity and a common botanical origin.A preliminary palynological study indicates a regional high taxonomical diversity,mainly of pteridophyte spores and gymnosperm pollen grains.According to the preliminary palynological data,the region was inhabited by conifer forests adapted to a dry season under a subtropical climate.The abundant charcoalified wood associated with the amber in the same beds is evidence of paleofires that most likely promoted both the resin production and an intensive erosion of the litter,and subsequent great accumulation of amber plus plant cuticles.In addition,for the first time in the fossil record, charcoalified plant fibers as bioinclusions in amber are reported.Other relevant taphonomic data are the exceptional presence of serpulids and bryozoans on the surfaces of some amber pieces indicating both a long exposure on marine or brackish-water and a mixed assemblage of amber.Lastly,new findings of insect bioinclusions,some of them uncommon in the fossil record or showing remarkable adaptations,are reported.In conclusion,a documented scenario for the origin of the El Soplao amber outcrop is provided.     

Tectonic and eustatic control on a mixed siliciclastic–carbonate platform during the Late Oxfordian–Kimmeridgian (La Rochelle platform,western France)

Boreal and Tethyan realms of Western Europe present significant sedimentological, paleontological, and stratigraphic differences. The purpose of this study is to constrain regional versus global controls on the dynamics of a sedimentary system located at the interface of these two realms in order to better understand the origin of their differences. Detailed sedimentological, palynofacies and calcareous nannofossil analyses were performed on two sections from the La Rochelle platform (western France). The Pas section includes part of the Late Oxfordian and Early Kimmeridgian, and the Rocher d'Yves section is assigned to the Late Kimmeridgian. They correspond to monotonous marl–argillaceous limestone alternations. Limestones are essentially mudstones with echinoderms, bivalves and foraminifera that suggest low-energy, open-marine conditions. Highly bioclastic and/or peloidal deposits occur commonly, and show wackestones to wacke-pack-grainstones textures. These deposits indicate frequent high-energy events, and are interpreted as storm deposits. Marls dominate in the most proximal depositional environments, while calcareous deposits are more important in more distal environments. The Rocher d'Yves section is globally more marly than the Pas section, suggesting a more proximal setting. Palynofacies are dominated by woody particles, suggesting shallow-water, proximal depositional environments. Calcareous nannofossils are ascidian spicules, coccoliths, and schizospheres. Watznaueria britannica dominate calcareous nannofossil assemblages in the Pas section. The Rocher d'Yves assemblages are quasi-exclusively composed of Cyclagelosphaera margerelii, and indicate more proximal paleoenvironments than those of the Pas section. Different orders of depositional sequences are defined, with sequence boundaries corresponding to the most rapid relative sea-level falls. They are hierarchically stacked, and correlate, on the basis of ammonite zones, with the sequences of contemporaneous sections from Tethyan and boreal realms. The stacking pattern of these sequences suggests an orbital control on sedimentation. Small-, medium- and large-scale sequences correspond to precession (20 ky) cycles and to 100 ky and 400 ky eccentricity cycles, respectively. The elementary sequences have durations shorter than 20 ky. The Kimmeridgian was a period of global sea-level rise that ended in the Late Kimmeridgian. More proximal depositional environments in the Rocher d'Yves section (Late Kimmeridgian) than in the Pas section (Early Kimmeridgian) imply a progradation of the La Rochelle platform during the Kimmeridgian. This progradation resulted from a slowdown of the subsidence in the Aquitaine Basin during the Kimmeridgian, corresponding to the first steps of Atlantic Ocean opening. High-frequency cycles on the La Rochelle platform formed in sync with Milankovitch orbital cycles, while tectonics controlled the formation of the low-frequency cycles.     

Non-chondritic Sm/Nd ratio in the terrestrial planets: Consequences for the geochemical evolution of the mantle-crust system

Super-chondritic ¹⁴²Nd signatures are ubiquitous in terrestrial, Martian and lunar samples, and indicate that the terrestrial planets may have accreted from material with Sm/Nd ratio higher than chondritic. This contradicts the long-held view that chondrites represent a reference composition for the ¹⁴⁷Sm-¹⁴³Nd system. Using coupled ¹⁴⁶Sm-¹⁴²Nd and ¹⁴⁷Sm-¹⁴³Nd systematics in planetary samples, we have proposed a new set of values for the ¹⁴⁷Sm/¹⁴⁴Nd and ¹⁴³Nd/¹⁴⁴Nd ratios of the bulk silicate Earth (Caro et al., 2008). Here, we revise the Bulk Silicate Earth estimates for the ⁸⁷Rb-⁸⁷Sr and ¹⁷⁶Lu-¹⁷⁶Hf systems using coupled Sr-Nd-Hf systematics in terrestrial rocks. These estimates are consistent with Hf-Nd systematics in lunar samples. The implications of a slightly non-chondritic silicate Earth with respect to the geochemical evolution of the mantle-crust system are then examined. We show that the Archean mantle has evolved with a composition indistinguishable from that of the primitive mantle until about 2 Gyr. Positive ε¹⁴³Nd and ε¹⁷⁶Hf values ubiquitous in the Archean mantle are thus accounted for by the non-chondritic Sm/Nd and Lu/Hf composition of the primitive mantle rather than by massive early crustal formation, which solves the paradox that early Archean domains only have a limited extension in the present-day continents. The Sm-Nd and Lu-Hf evolution of the depleted mantle for the past 3.5 Gyr can be entirely explained by continuous extraction of the continents from a well-mixed mantle. Thus, in contrast to the chondritic Earth model, Sm-Nd mass balance relationships can be satisfied without the need to call upon hidden reservoirs or layered mantle convection. This new Sm-Nd mass balance yields a scenario of mantle evolution consistent with trace element and noble gas systematics. The high ³He/⁴He mantle component is associated with ¹⁴³Nd/¹⁴⁴Nd compositions indistinguishable from the bulk silicate Earth, suggesting that the less degassed mantle sources did not experience significant fractionation for moderately incompatible elements.     

Iron isotope fractionation during proton- and ligand-promoted dissolution of primary phyllosilicates

We studied stable iron isotope fractionation during dissolution of a biotite and chlorite enriched mineral fraction from granite by HCl and 5 mM oxalic acid in a pH range of 4-5.9. Batch experiments covered a time period from 2 h to 100 days and were performed at initial potassium concentrations of 0, 0.5, and 5 mM to induce different levels of biotite exfoliation. All experiments were kept anoxic to investigate solely the dissolution step without the influence of oxidation and precipitation of secondary Fe oxyhydroxides. Oxalic acid increased the release of Fe by a factor of ∼15 compared with the HCl experiments. Addition of 0.5 mM K to initial solutions in proton-promoted dissolution decreased the release of Fe by 30-65% depending on the dissolution stage. In ligand-controlled dissolution, K reduced the Fe release only to a minor extent. All solutions of the early dissolution stages were enriched in light Fe isotopes by up to −1.4‰ in δ⁵⁶Fe compared with the isotopic composition of biotite and chlorite mineral separates, which we explained by a kinetic isotope effect. In proton-promoted dissolution, early released fractions of K-enriched experiments were significantly lighter (−0.7‰ to −0.9‰) than in the initially K-free experiments. The evolution of Fe isotope ratios in solution was modeled by a linear combination of kinetic isotope effects during two independent dissolution processes attacking different crystallographic sites. In ligand-controlled dissolution, K did not influence the kinetic isotope effect and the Fe isotope composition in solution in the late dissolution stages remained slightly lighter than the bulk composition of the biotite/chlorite enriched mineral fraction. This study demonstrates that the initial Fe weathering flux should be enriched in light Fe isotopes and that Fe isotope data in combination with dissolution kinetics and stoichiometry provide new insights into dissolution mechanisms.     

Analytical theory of a lunar artificial satellite with third body perturbations

We present here the first numerical results of our analytical theory of an artificial satellite of the Moon. The perturbation method used is the Lie Transform for averaging the Hamiltonian of the problem, in canonical variables: short-period terms (linked to l, the mean anomaly) are eliminated first. We achieved a quite complete averaged model with the main four perturbations, which are: the synchronous rotation of the Moon (rate ), the oblateness J ₂ of the Moon, the triaxiality C ₂₂ of the Moon ( ) and the major third body effect of the Earth (ELP2000). The solution is developed in powers of small factors linked to these perturbations up to second-order; the initial perturbations being sorted ( is first-order while the others are second-order). The results are obtained in a closed form, without any series developments in eccentricity nor inclination, so the solution apply for a wide range of values. Numerical integrations are performed in order to validate our analytical theory. The effect of each perturbation is presented progressively and separately as far as possible, in order to achieve a better understanding of the underlying mechanisms. We also highlight the important fact that it is necessary to adapt the initial conditions from averaged to osculating values in order to validate our averaged model dedicated to mission analysis purposes.     

On the use and error of approximation in the Domenico (1987) solution

A mathematical solution for solute transport in a three-dimensional porous medium with a patch source under steady-state, uniform ground water flow conditions was developed by Domenico (1987). The solution derivation strategy used an approximate approach to solve the boundary value problem, resulting in a nonexact solution. Variations of the Domenico (1987) solution are incorporated into the software programs BIOSCREEN and BIOCHLOR, which are frequently used to evaluate subsurface contaminant transport problems. This article mathematically elucidates the error in the approximation and presents simulations that compare different versions of the Domenico (1987) solution to an exact analytical solution to demonstrate the potential error inherent in the approximate expressions. Results suggest that the accuracy of the approximate solutions is highly variable and dependent on the selection of input parameters. For solute transport in a medium-grained sand aquifer, the Domenico (1987) solution underpredicts solute concentrations along the centerline of the plume by as much as 80% depending on the case of interest. Increasing the dispersivity, time, or dimensionality of the system leads to increased error. Because more accurate exact analytical solutions exist, we suggest that the Domenico (1987) solution, and its predecessor and successor approximate solutions, need not be employed as the basis for screening tools at contaminated sites.     

Analyses of precipitation,temperature and evapotranspiration in a French Mediterranean region in the context of climate change

This study is focused on the western part of the French Mediterranean area, namely the Pyrénées-Orientales and Aude administrative departments. The water resources (surface and groundwater) in the region are sensitive to climate change. The study addresses the question of whether any trend in the annual and monthly series of temperature, rainfall and potential evapotranspiration (PET) already appears at the scale of this region. Two data sources have been used: (a) direct local measurements using the meteorological network; and (b) spatially interpolated data from the French weather service model SAFRAN for the period 1970–2006. The non-parametric Mann–Kendall test was applied to identify significant trends at the local scale and, because of the natural spatial variability of the Mediterranean climate, regional interpretation was also performed. The trends observed in the 13 catchments of interest are consistent with those observed at a larger scale. An increase in annual mean temperature and annual PET was observed throughout the study area, whereas annual precipitation has not exhibited any trend. The monthly scale has revealed strong seasonal variability in trend. The trend for an increase in monthly PET has been observed mainly in the spring, and has not been seen in the coastal areas. A trend for an increase in monthly temperature has been observed in June and in the spring throughout the entire area. Monthly rainfall has been found to decrease in June and increase in November throughout the area. The significant trends observed in rainfall and temperature seem to be consistent between the different data sources.     

辽宁义县组禽龙类恐龙一新属种——义县薄氏龙Bolong yixianensis gen. et sp. nov.

在辽西义县组新发现了一具近完整的禽龙类化石骨架.据头骨和牙齿特征建立了一新属、新种--义县薄氏龙(Bolong yixianensis gen.et sp.nov.).它的自近裔性状包括:上颌骨与泪骨之间有一凹坑;在眼眶之上,前额骨后部发育有一前后延长的凹陷;前额骨后侧边缘发育一厚嵴,在厚嵴之上有一前后延长的凹陷;前齿骨腹突向后延伸并与前齿骨腹缘平行;齿骨背侧的前齿骨关节面高度不足齿骨高度的2/3,齿骨前尖位于齿骨自下向上1/3高处;上颌骨牙齿主脊位于牙齿颊面后1/3处,并向后弯曲.与同样在辽西义县组发现的锦州龙Jinzhousaurus的头骨和牙齿相比较,薄氏龙至少有14处不同.包括上颌骨前端不下弯、前齿骨腹突分叉和上颌骨齿齿冠有多条副脊等.它也是迄今在亚洲发现的几种最原始的禽龙类之一.     

Complete Zonal Problem of the Artificial Satellite: Generic Compact Analytic First Order in Closed Form

This paper is a contribution to the Theory of the Artificial Satellite, within the frame of the Lie Transform as canonical perturbation technique (elimination of the short period terms). We consider the perturbation by any zonal harmonic J _n (n ≥ 2) of the primary on the satellite, what we call here the complete zonal problem of the artificial satellite. This is quite useful for primaries with symmetry of revolution. We give an analytical formula to compute directly the first order averaged Hamiltonian. The computation is carried out in closed form for all terms, avoiding therefore tedious expansions in the eccentricity or in any anomaly; this feature makes the averaging process, not only valid for all kind of elliptic trajectories but at the same time it yields the averaged Hamiltonian in a very short and compact way. The formula allows us to now skip the averaging process, which means an asymptotic gain of a factor 3n/2 regarding the computational cost of the n ^th zonal. Our analytical formulae have been widely checked, by comparison on one hand with published works (Brouwer, 1959) (which contained results for particular zonal harmonics, let’s say typically from J ₂ to J ₈), and on the other hand with the results of 3 symbolic manipulation software, among which the MM (standing for ‘Moon’s series Manipulator’), which has already been used and described in (De Saedeleer B., 2004). Additionally, the first order generator associated with this transformation is given into the same closed form, and has also been validated.