Uranium-series isotopes in river materials: Insights into the timescales of erosion and sediment transport

The uranium-series isotope signatures of the suspended and dissolved load of rivers have emerged as an important tool for understanding the processes of erosion and chemical weathering at the scale of a watershed. These signatures are a function of both time and weathering-induced fractionation between the different nuclides. Provided appropriate models can be developed, they can be used to constrain the residence time of river sediment. This chronometer is triggered as the bedrock starts weathering and the inferred timescale encompasses the residence time in the weathering profile, storage in temporary sediment deposits (e.g. floodplain) and transport in the river. This approach has been applied to various catchments over the past five years showing that river sediments can reside in a watershed for timescales ranging from a few hundreds of years (Iceland) to several hundreds of thousands of years (lowlands of the Amazon). Various factors control how long sediment resides in the watershed: the longest residence times are observed on stable cratons unaffected by glacial cycles (or more generally, climate variability) and human disturbance. Shorter residence times are observed in active orogens (Andes) or fast-eroding, recently glaciated catchments (Iceland). In several cases, the residence time of suspended sediments also corresponds to the time since the last major climate change. The U-series isotope composition of rivers can also be used to predict the river sediment yield assuming steady-state erosion is reached. By comparing this estimate with the modern sediment yield obtained by multi-year sediment gauging, it is clear that steady-state is seldom reached. This can be explained by climate variability and/or human disturbance. Steady-state is reached in those catchments where sediment transport is rapid (Iceland) or where the region has been unaffected by climate change and/or human disturbance. U-series are thus becoming an important tool to study the dynamics of erosion.     

Nature of sedimentary deposits in the western Makgadikgadi basin, Botswana

Quaternary sedimentation in the western Makgadikgadi basin of north central Botswana is evaluated on the basis of new evidence from satellite imagery and sedimentological analyses. Thematic Mapper imagery interpretation, combined with field evidence, has led to the identification of geomorphological features which are mainly composed of light grey calcareous sandstones (formerly calcretes) overlain by dark grey sands. The literature suggests that palaeolake Makgadikgadi I formed and developed intermittently after initial downwarping in the early–mid Pleistocene. The calcareous sandstones were formed when calcium carbonate precipitation took place in pre-existing Kalahari sands along the western shoreline of Makgadikgadi I. Field evidence, supported by X-ray diffraction and SEM analyses, indicates that CaCO₃precipitated mainly in marshy conditions around plant roots and stems and in association with bacteria in embayments along the lakeshore. The sandstones thickened and became partially indurated as a result of increasing palaeolake levels. Deposition was terminated by renewed tectonism which uplifted the shoreline zone relative to the lake basin, leading to falling palaeolake levels. Post-uplift reworking led to case hardening and pedogenic calcrete formation in the upper sections of the calcareous sandstones. Sedimentary conditions altered during the late Pleistocene. Extensive distributaries from the proto-Okavango system incised the shoreline ridge contributing to the filling of Makgadikgadi II. Satellite data suggest that the proto-Okavango rivers formed a series of fan deltas at this time along the western Makgadikgadi basin. Widespread dispersal of fluvial grey sands took place as a result of basin tilting which led to anastomosing channels flowing southward possibly around 18,000 B.P. These results, although preliminary in nature, augment previous geomorphological analyses by adding some detail in terms of depositional environments and by providing a tentative age and origin for the ubiquitous grey sands.     

Why Is the Climate Forcing of Sulfate Aerosols So Uncertain?

l. IntroductionAlthough the aerosol has been recognized as an important factor which has innuence onthe past, present and future climate for a long time, it still has much uncertainty in assessingits climate forcing. The direct radiative forcing of sulfate aerosols has been estimated rangingfrom --0.3 W/ m2 to --0.9 W/ m2 in recent publications (Charlson et al., l992, Kiehl andBriegleb l993; Taylor and Penner 1994, Boucher and Anderson l995, Kieh1 and Rodhe l995;Chuang et al., l997, Penne…     

Contribution of Secondary VOC to the Composition of Aqueous Atmospheric Particles: A Modeling Approach

Measurements show that 20–60% of the carbon mass present in fine atmospheric particulate matter consists of water soluble organic compounds (WSOC). However, only 5–20% of this WSOC has been identified, mainly as dicarboxylic acids. Because of their high solubility in water, multifunctional secondary compounds derived from the gas-phase oxidation of volatile organic compounds (VOC) are suspected to be key contributors to the WSOC. To test this assumption, an estimate of aqueous uptake of secondary VOC was included in a highly detailed gas-phase mechanism which treats explicitly the formation of the secondary VOC from a set of representative primary species. Simulations were conducted for 2 scenarios, representing typical rural and urban areas. It was observed that the uptake of secondary VOC can lead to WSOC mass concentrations in the range of a few C m^–3, in fairly good agreement with typical WSOC mass concentrations measured. Speciation of WSOC was found to be mainly as tri- or higher multifunctional hydroxy-carbonyl species and hydroxy-hydroperoxide-carbonyl species, in urban and rural environments, respectively. However, it was also found that taking into account only the absorption of secondary VOC does not bring the carboxylic acids mass concentration in agreement with measurements. An attempt was made to explain this discrepancy by introducing chemistry occurring within deliquescent aerosols.     

Analytical Procedures for the Measurement of Boron Isotope Compositions by Ion Microprobe in Meteorites and Mantle Rocks

An analytical procedure has been developed to measure in situ the ¹¹ B/¹⁰ B ratio in terrestrial basaltic rocks and meteoritic chondrules having B concentration of less than 1 μg g^?1 using a small radius ims3f ion microprobe. The central difficulties for these measurements are (i) the removal of the trace amount of B contamination introduced in the sample during polishing, (ii) the precise calibration of instrumental mass fractionation of B isotopes and (iii) the low count rates of ¹⁰ B and ¹¹ B. Contamination experiments conducted with isotopically labelled B enriched in ¹⁰ B showed that ultrasonic cleaning in bi-distilled water (< 1 ng g^?1 B) and pre-sputtering of the analysed area decrease B contamination to the level of 0.01 μg g^?1. Analyses of isotope standards spanning a range of ¹¹ B/¹⁰ B between 3.93 and 4.20 showed that instrumental mass fractionation was constant within? during one session of analyses. Repeated analyses of a standard glass showed a reproducibility of instrumental mass fractionation between February 1991 and October 1996 of 1.3. Taking into account all sources of error, boron isotope measurements are accurate to within 5 for meteoritic samples having B contents in the range 0.1 to 1 μg g^?1. A slightly better accuracy of 1.5 can be achieved for basaltic glasses which can be sputtered with very intense primary beams.     

The amphibole effect: A possible mechanism for triggering explosive eruptions

The possible effect of pressure-induced breakdown of amphibole in triggering explosive eruptions is considered. Since amphibole is a hydrous mineral, when it breaks down to an anhydrous assemblage as pressure is reduced to less than 1.5–2 kbar, the water liberated might oversaturate the coexisting melt generating the necessary overpressure to trigger an explosive eruption. Resorbed amphiboles are commonly observed in evolved lavas and pyroclastic ejecta. The amount of a volatile component, such as water that will dissolve in a melt is a function of pressure, temperature and composition, and during crystallization it is also a function of the extent of crystallization and the nature of crystallizing minerals. The relation can be expressed by the simple equation: where X_r is the water content of the residual liquid, X_i is the initial water content, X_mOH, is the water content of hydrous minerals, f is the total extent of crystallization and f′ is the extent of crystallization of hydrous minerals such that 0 ≤ f′ ≤ f ≤ 1. We suggest that storage of water in hydrous minerals, such as amphibole and biotite, plays an important role in the eruptive behavior of certain types of magmas; the breakdown of these minerals liberates water to the melt at a rate governed by the kinetics of the resorption reaction. If the release of water causes the liquid fraction to exceed the solubility limit and the overpressure resulting from expansion of the gas exceeds the strength of the overlying magma and rocks in the conduit, the result can be an explosive eruption. The amphibole effect can occur at different structural levels depending on the nature of the magma and physical conditions leading to instability.     

Textural evolution of polyhedral olivine experiencing rapid cooling rates

Dynamic crystallization experiments in the CaO–MgO–Al₂O₃–SiO₂ (CMAS) system have been used to investigate the change in crystal shape when pre-existing polyhedral olivine crystals are cooled rapidly (1,639–2,182°C/h). Polyhedral olivines are crystallized initially in a first step using a slow cooling rate (2°C/h), then skeletal and dendritic overgrowths develop on the polyhedral crystals during a subsequent fast cooling event. During this second episode small dendritic olivines also nucleate within the liquid phase. Observation of the experimental sample by optical microscopy shows that the polyhedral olivine shape progressively changes to a skeletal and then to a dendritic morphology in the following sequence: polyhedral ⇒ hopper polyhedral ⇒ dendritic polyhedral. This evolutional sequence is discussed in terms of changes in the crystal growth conditions during cooling and a general relation between these olivine dynamic crystallization experiments and the integrated model of crystal growth by Sunagawa (Bull Minér 104:81–87, 1981, Morphology of crystals, Terra Scientific Publishing Company, 1987) is proposed.     

Estimating species diversity: Comparison of two algorithms

Two approaches to estimating the number of species in a lithologic unit are compared. An empirical model of the sampling process, which involves fitting the equation of a rectangular hyperbola to the data from a collector's curve, is compared with a logarithmic model derived from a statistical theory of sampling. The two approaches give equally accurate estimates of species richness when organisms are randomly dispersed but the logarithmic model generally requires more sampling than the hyperbolic model.     

A wave‐dominated,tide‐modulated model for the Lower Ordovician of the Anti‐Atlas,Morocco

Hybrid depositional systems are created by the interaction of two or more hydrodynamic processes that control facies distribution and their characteristics in terms of sedimentary structures and depositional geometry. The interaction of wave and tide both in the geological sedimentary record and modern environments has been rarely described in the literature. Mixed coastal environments are identified by the evidence of wave and tidal structures and are well identified in nearshore environments, while their recognition in lower shoreface–offshore environments lacks direct information from modern settings. Detailed field analyses of 10 stratigraphic sections of the Lower Ordovician succession (Fezouata and Zini formations; Anti‐Atlas, Morocco) have allowed the definition of 14 facies, all grouped in four facies zones belonging to a storm‐dominated, wave‐dominated sedimentary siliciclastic system characterized by symmetrical ripples of various scales. Peculiar sedimentary organization and sedimentary structures are observed: (i) cyclical changes in size of sedimentary structures under fair‐weather or storm‐weather conditions; (ii) decimetre‐deep erosional surfaces in swaley cross‐stratifications; (iii) deep internal erosion within storm deposits; (iv) discontinuous sandstone layers in most depositional environments, and common deposition of sandstones with a limited lateral extension, interpreted to indicate that deposition at all scales (metric to kilometric) is discontinuous; (v) combined flow–oscillation ripples showing aggrading–prograding internal structures alternating with purely aggrading wave ripples; and (vi) foreshore environments characterized by alternating phases of deposition of parallel stratifications, small‐scale and large‐scale ripples and tens of metres‐wide reactivation surfaces. These characteristics of deposition suggest that wave intensity during storm‐weather or fair‐weather conditions was continuously modulated by another controlling factor of the sedimentation: the tide. However, tidal structures are not recognized, because they were probably not preserved due to dominant action of storms and waves. A model of deposition is provided for this wave‐dominated, tide‐modulated sedimentary system recording proximal offshore to intertidal–foreshore environments, but lacking diagnostic tidal structures.     

Late Panafrican evolution of the main Hoggar fault zones: Implications of magnetic fabric study in the In Telloukh pluton (Tin Serririne basin, Algeria)

The Late Panafrican evolution of the Hoggar shield is characterized by emplacement of magmatic intrusions and by occurrence of major shear zones separating different terranes. In Telloukh granite is close to the In Guezzam faults (western border of the Tin Serririne basin). Analysis of its visible and magnetic fabrics suggests an emplacement mode and deformation that are not related to the In Guezzam faults, but most likely to a N–S compression, an event not yet identified. Dioritic dykes crosscutting the granite have a very different magnetic fabric, which is related on the contrary to dextral strike-slip movements along the In Guezzam faults. In both cases, no visible fabric can be correlated with the magnetic fabric, which has been likely acquired during late magmatic stages. This magnetic fabric was not significantly affected by the tectonic events that took place after entire crystallization of the magma. The In Guezzam faults and the major 7°30 and 4°50 shear zones are close to intrusions such as In Telloukh dykes and the Alous En Tides and Tesnou plutons where quite similar magnetic fabrics are observed, all related with dextral strike-slip movements along these structures.