Mössbauer study of Meridiani Planum,the first iron‐nickel meteorite found on the surface of Mars by the MER Opportunity

Abstract— –Meridiani Planum is the first iron meteorite found on Mars. It was discovered in 2005 by the Mars Exploration Rover Opportunity (MER‐B). Mössbauer spectra (MS) of the unbrushed and brushed meteorite species were acquired in 10 degrees temperature windows in the range of 210–260 K. Earlier examinations of these MS have led to the conclusion that the meteorite, which contains ～～7 wt% Ni, belongs to the IAB meteorite group. Here, making use of a recently developed calibration/folding procedure for MER MS, we report the results of the MS analyses for the single temperature windows m5 (210–220 K), m6 (220–230 K), m7 (230–240 K), and m89 (240–260 K). All spectra consist of a sextet and a ferric doublet. The hyperfine field of the sextet, extrapolated to room temperature, is ～～34.5 T, which is, based on Mössbauer studies of meteorites found on Earth, indeed consistent with the presence of kamacite. The fractional spectral area of the sextet is ～～0.96 of the total spectrum. The ferric doublet has an average quadrupole splitting of 0.70 mm/s and is not diagnostic of any specific Fe mineral.     

A mountain icefield of Loch Lomond Stadial age, western Grampians, Scotland

The extent of a large mountain icefield that existed in the western Grampians during the Loch Lomond stade has been mapped. The main types of evidence used in establishing the limits comprise moraines, thick drift, fluvioglacial landforms, erratics, ice-smoothed bedrock, striae, friction cracks and relict periglacial forms. Trimlines on 198 spurs, and various forms of glacial and periglacial evidence on 73 cols and in c . 200 cirques, enable the upper limits and morphology of the icefield to be reconstructed. Abundant striae and friction cracks in many areas enable ice-flow directions and the surface form of the icefield to be inferred in some detail. The icefield had ice-shed altitudes of c . 750 m, a maximum width of 80 km and an area over 2,000 km². At least 60 nunataks stood above the icefield, and on its western side outlet glaciers reached the sea and flowed for as much as 28 km along major tidal water lochs.     

Controlling factors of volumetrically important marine carbonate cementation in deep slope settings

The controlling parameters of early marine carbonate cementation in shoal water and hemipelagic to pelagic domains are well‐studied. In contrast, the mechanisms driving the precipitation of early marine carbonate cements at deeper slope settings have received less attention, despite the fact that considerable volumes of early marine cement are present at recent and fossil carbonate slopes in water depths of several hundreds of metres. In order to better understand the controlling factors of pervasive early marine cementation at greater water depths, marine carbonate cements observed along time‐parallel platform to basin transects of two intact Pennsylvanian carbonate slopes are compared with those present in the slope deposits of the Permian Capitan Reef and Neogene Mururoa Atoll. In all four settings, significant amounts of marine cements occlude primary pore spaces downslope into thermoclinal water depths, i.e. in a bathymetric range between some tens and several hundreds of metres. Radial, radiaxial and fascicular optic fibrous calcites, and radiaxial prismatic calcites are associated with re‐deposited facies, boundstones and rudstones. Botryoidal (formerly) aragonitic precipitates are common in microbially induced limestones. From these case studies, it is tentatively concluded that sea water circulation in an extensive, near‐sea floor pore system is a first‐order control on carbonate ion supply and marine cementation. Coastal upwelling and internal or tidal currents are the most probable mechanisms driving pore water circulation at these depths. Carbonate cements precipitated under conditions of normal to elevated alkalinity, locally elevated nutrient levels and variable sea water temperatures. The implications of these findings and suggestions for future work are discussed.     

Modelling tidal current‐induced bed shear stress and palaeocirculation in an epicontinental seaway: the Bohemian Cretaceous Basin,Central Europe

Lower to Middle Turonian deposits within the Bohemian Cretaceous Basin (Central Europe) consist of coarse‐grained deltaic sandstones passing distally into fine‐grained offshore sediments. Dune‐scale cross‐beds superimposed on delta‐front clinoforms indicate a vigorous basinal palaeocirculation capable of transporting coarse‐grained sand across the entire depth range of the clinoforms (ca 35 m). Bi‐directional, alongshore‐oriented, trough cross‐set axes, silt drapes and reactivation surfaces indicate tidal activity. However, the Bohemian Cretaceous Basin at this time was over a thousand kilometres from the shelf break and separated from the open ocean by a series of small islands. The presence of tidally‐influenced deposits in a setting where co‐oscillating tides are likely to have been damped down by seabed friction and blocked by emergent land masses is problematic. The Imperial College Ocean Model, a fully hydrodynamic, unstructured mesh finite element model, is used to test the hypothesis that tidal circulation in this isolated region was capable of generating the observed grain‐size distributions, bedform types and palaeocurrent orientations. The model is first validated for the prediction of bed shear stress magnitudes and sediment transport pathways against the present‐day North European shelf seas that surround the British Isles. The model predicts a microtidal to mesotidal regime for the Bohemian Cretaceous Basin across a range of sensitivity tests with elevated tidal ranges in local embayments. Funnelling associated with straits increases tidal current velocities, generating bed shear stresses that were capable of forming the sedimentary structures observed in the field. The model also predicts instantaneous bi‐directional currents with orientations comparable with those measured in the field. Overall, the Imperial College Ocean Model predicts a vigorous tide‐driven palaeocirculation within the Bohemian Cretaceous Basin that would indisputably have influenced sediment dispersal and facies distributions. Palaeocurrent vectors and sediment transport pathways however vary markedly in the different sensitivity tests. Accurate modelling of these parameters, in this instance, requires greater palaeogeographic certainty than can be extracted from the available rock record.