面向问题的空间应用表达与实现

讨论空间应用的一种面向问题的表达方法与实现机制。为解决空间应用的描述问题,在建立时空一体化空间数据模型基础上,定义了对SQL进行扩展的时空复合查询语言,实现了对空间应用问题的非过程化描述;研究复杂空间应用的表达问题,讨论时空复合查询语言的限制,并在语言中引入流机制,通过空间应用问题的组合实现更为复杂的空间应用,并支持空间数据分布式计算;最后给出若干空间应用实例及其面向问题的表达。     

香港西贡滨珊瑚REE的地球化学特征及其与海平面变化的关系

用ICP-MS技术测定了位于珠江口西岸香港西贡滨珊瑚在1991～2002年(分辨率达到0.5a)的稀土元素(REE)含量。实验结果显示香港滨珊瑚REE具有Ce负异常、重稀土富集这种典型的海水相分布模式。香港滨珊瑚中REE含量处于目前已见报道中的高值范围,与巴布亚新几内亚珊瑚的REE含量相当。通过与不同地区的比较,香港珊瑚高REE含量很可能就是毗邻的珠江水体高REE的直接反映,而且同南海北缘半封闭边缘海的性质有关。香港珊瑚REE的来源主要为珠江口及其相邻的陆缘沉积物。此外,1991～2002年香港珊瑚REE含量年际下降趋势十分明显,Ce负异常和重稀土富集的程度也呈加剧的趋势,分布模式向海水相转化。REE含量与海平面的年际变化之间有显著的负相关关系(r=-0.7～-0.9),而且重稀土与海平面的相关系数优于轻稀土。上述结果揭示了热带滨珊瑚对近期全球变暖、极冰融化和海水膨胀所引起的海平面快速上升的响应。     

全球水储量变化的GRACE卫星检测

利用GRACE月尺度变化的地球重力场反演了全球水储量变化,并与陆地水文资料、卫星测高资料及海洋模式得到的结果进行了比对.通过对SOURE台站重力变化的陆地水储量变化计算结果和GRACE重力场系数截断为15阶得到的结果比较,发现两者比较接近,且年周期变化特征明显.对于亚马逊流域,当重力场系数截断为15阶且平滑半径使用106 m时,GRACE反演的区域平均水储量厚度的周年变化振幅为15.6×10-2m,小于使用平滑半径为4×105m的23.7×10-2m.在研究长江流域时,本文对水文资料做球谐系数展开,并与GRACE数据做同样的截断和平滑处理,结果发现GRACE反演的水厚度变化与水文资料结果基本上符合.对于纬度±66°之间的海洋区域,GRACE反演的海水质量变化接近于结合卫星测高和海洋模式得到的结果,但对于2°×2°网格,则在一些区域差异明显,最大超过了0.2 m,中误差为3.8×10-2m.可见,当前GRACE卫星时变重力场只能确定出上千公里及以上尺度区域的水储量变化.     

Adsorption of Pentachlorophenol onto Oxide and Clay Minerals： Surface Reaction Model and Environmental Implications

The adsorption of pentachlorophenol （PCP） onto quartz, kaolinite, illite, montmorillonite and iron oxides has been investigated by batch equilibrium techniques. The pH-dependent isotherms are curves with peak values, the position of which is at about pH = 5-6 depending on the mineral species. Based on distribution of both speciation of surface hydroxyls on minerals and PCP in solution a surface reaction model involving surface complexation and surface electrostatic attraction is presented to fit the pH-dependent isotherms, and both reaction constants are calculated. The results show that on quartz and phyllosilicate minerals the predominant adsorption reaction is surface complexation, meanwhile both of surface electrostatic attraction and surface complexation are involved on the iron oxide minerals. The reaction constants of surface electrostatic adsorption are usually one to three orders in magnitude, larger than that of surface complexation. The concentration-dependent isotherms can be well fitted by Langmnir equation with the correlation coefficient R〉0.93 for kaolinite and iron oxides. The maximum adsorption is found in the order： hematite 〉 lepidocrocite 〉 goethite 〉 kaolinite 〉 quartz 〉 montmorillonite ≈ illite, which can be interpreted by consideration of both reaction mechanism and surface hydroxyl density. The significant adsorption of PCP onto mineral surfaces suggests that clay and iron oxide minerals will play an important role as HIOCs are adsorbed in laterite or latertoid soil, which is widespread in South China.     

Chemical Composition of Ancient Celadon Material （1127-1279 A.D.） from Zhejiang, China and Its Implication

The microprobe EDXRF equipment was used for analysis of the major and trace elements in glaze layer-transitive layer-body layer of the celadon from the Altar Yao （Kiln） and Laohudong Yao in the Southern Song Dynasty （1127-1279 A.D.）, Zhejiang, China. The K values of the discriminant factor for the celadon wares are larger than 8, which means the celadon of the Altar Yao and Laohudong Yao are different from that of the Longquan Yao. The former two belong to the Guan Yao system （the Chinese imperial kilns）, but the latter to the Min Yao system （the Chinese popular kilns）. The principle component analysis shows their relationship between the Altar and Laohudong wares with provenance postulation. The thickness of the transitive layer in the Altar and Laohudong wares is obviously different, which reveals the microstructure characteristics of the celadon even though both kinds of wares belong to the imperial kiln system.     

Extensive Cold-Precipitation-Freezing Events in Southern China and Their Circulation Characteristics

Concurrence of low temperature,precipitation and freezing weather in an extensive area would cause devastating impacts on local economy and society.We call such a combination of concurrent disastrous weather“extensive coldprecipitation-freezing”events(ECPFEs).In this study,the ECPFEs in southern China(15°?35°N,102°?123°E)are objectively defined by using daily surface observational data for the period 1951?2013.An ECPFE in southern China is defined if the low temperature area,precipitation area and freezing area concurrently exceed their respective thresholds for at least three consecutive days.The identified ECPFEs are shown to be reasonable and reliable,compared with those in previous studies.The circulation anomalies in ECPFEs are characterized by a large-scale tilted ridge and trough pairing over mid-and high-latitude Eurasia,and the intensified subtropical westerlies along the southern foot of the Tibetan Plateau and the anomalous anticyclonic circulation over the subtropical western Pacific.Comparative analysis reveals that the stable cold air from the north and the warm and moist air from the south converge,facilitating a favorable environment for the concurrence of extensive low-temperature,precipitation and freezing weather.     

石煤钒矿成分分析标准物质的研制

石煤钒矿资源的开发和合理利用需要对其成分进行准确的分析测试和质量控制.目前,国内外尚未有石煤钒矿成分分析的标准物质,现有钒成分分析标准物质无论是其五氧化二钒含量,还是定值成分都无法满足我国对石煤钒矿勘查、开发和研究需要.本文对采自湖北省崇阳县小源冲钒矿、湖南省芷江县牛牯坪钒矿、湖南省古丈县岩头寨钒矿和湖南省凤凰县黑冲钒...     

共转换点道集的抽取与转换波时变静校正

纵横波速度比固定时,同一地震道中各时间采样点对应不同的转换点位置,因此,常规的整体抽道方法只能抽取特定深度或特定层位条件下的共转换点道集,它不能保证所有P-SV转换波的反射点位置都在同一水平位置处。提出了一种精确抽取共转换点道集的新方法,运用这种方法抽取的共转换点道集中所有数据对应的转换点在地面的投影都对应于同一位置,因此,该道集是一种真正意义上的共转换点道集,在此基础上提出了一种解决短波长问题的转换波时变静校正方法,实际资料处理取得了好的效果。     

几种常用消毒剂对杂色鲍幼鲍的急性毒性试验

在常温静水的条件下,分别用高锰酸钾、菌毒净、聚维酮碘对杂色鲍(Haliotis diversi-color Reeve)幼鲍进行急性毒性试验。试验结果表明,毒性大小依次为高锰酸钾>菌毒净>聚维酮碘。高锰酸钾对幼鲍24,48 h的LC50分别为17.1,5.18 mg/L。菌毒净对幼鲍24,48h的LC50分别为105,46.5 mg/L。聚维酮碘对幼鲍24,48 h的LC50分别为530,218 mg/L。菌毒净、聚维酮碘是较为理想的消毒药物。     

新时期新疆水库大坝建设的主要问题与对策建议

截止 2018 年,全疆（含兵团）已建、在建及拟建水库 722 座（包括电站水库）,总库容 295.0 × 10⁸ m³。有力地改善了水资源调控和利用效率,在灌溉、供水、防洪、发电、旅游等方面发挥了极其 重要的作用。新时期按照水利部“水利工程补短板、水利行业强监管”的工作总基调,针对南北疆 水资源配置不平衡问题、水资源利用不充分问题,谋划提出了兴建数十座大中型山区水库,以及提 升已建水库大坝信息化管理水平、加强水库调度运行管理,在满足生态需水的前提下统筹生活、生 产供水,最大程度发挥水库效益、确保水库安全运行。针对新时期气候变化条件下水库洪水风险 分析、大坝建设需要重点关注的几项关键技术、山区水库替代平原水库、河流健康与生态调度、水库 清淤与能力提升、水库信息化与智能调度以及延长服役期等问题进行了探讨,提出若干对策建议。