743离子交换快速分离—等离子体光谱法同时测定十五个稀土元素

本文研制了适用于地质样品中15个稀土元素分析的快速方法。样品经碱熔沉淀分离和743阳离子交换树脂分离富集将稀土元素制备成溶液用等离子体光谱法(ICP-AES)进行测量。方法检出限为0.002-0.3μg/g,当稀土元素含量为0.5-80,μg/g时,方法相对标准偏差为15％-2％。本方法经过多年的样品分析考验以及不断的改进和完善,证明方法简便快速,分析数据稳定可靠,能很好地满足地质样品中15个稀土分量测定的要求。     

INTERPRETATION OF THE GRAVITY ANOMALY OVER A CAUSATIVE BODY WITH CIRCULAR SYMMETRY*

The interpretation of the gravity anomaly on a horizontal plane over a causative body having circular symmetry about a vertical axis is considered from a rather unconventional approach. As the analytical expression for the gravity effect of a circular body assumes a closed form only on the axis of symmetry, the interpretation in this approach is carried out with the anomaly profile along the axis—which leads to simpler and faster computation. A numerical method is developed for computation of the anomaly profile along the vertical axis from the horizontal radial profile of the symmetric anomaly by upward continuation. Provision is also made for an end correction when the radial profile has only a limited extension. Some simple geometrical shapes are assumed for the causative body. Its parameters are then determined from least squares fitting of its gravity effects to the observed (upward continued) vertical profile (i) by the steepest descent method and (ii) by the Newton-Raphson method. Some applications of these methods are demonstrated.     

塔里木与扬子新元古代热-构造事件特征、序列和时代——扬子与塔里木连接(YZ-TAR)假设

淄博市大武水源地是中国北方罕见的特大型岩溶-裂隙地下水水源地,地下水开采量为52×10~4m~3/d。为了对岩溶地下水进行有效监测,需要建立最优的地下水监测网。文中在对岩溶地下水流系统分析的基础上,建立了地下水流系统确定性-随机性数学模型,运用有限元与卡尔曼滤波耦合的模拟递推算法,对大武水源地地下水监测网进行了优化设计,结果显示:现有地下水位动态监测网难以达到监测目标,最优地下水位监测网由14个监测井,每月监测一次的监测频率组成,比现有地下水位监测网减少了2个监测井。     

区域人地系统的优化调控与可持续发展

区域人地系统的优化调控始终是现代地理学的重要任务,也是市场经济条件下中国实施可持续发展战略的理论基石。文章认为,区域人地系统优化调控的对象结构应从PRED系统改进为P_DR_DE_DE_DE_DS_D系统,人地系统优化调控的切入点与重点应坚持“以人为本”,而调控的重中之重应是人的意识建设,优化调控的目标点是追求和谐发展至上的目标。人地系统优化调控的动态机理在于模拟“人圈”与“地圈”的最佳距离,优化调控的空间结构包括核心区、发生区、支持区和作用区,各功能区相互竞争的结果形成区域定位与空间共生。协调优化和调控区域人地系统,不仅包括人地系统各要素之间以及各要素内部发展的动态协调与优化,而且包括区域之间人地系统的空间协调和优化,只有同时实现了区域之间人地系统的产业组织协调和空间组织协调,消除了区域盲目竞争与区域冲突,才能实现人地系统经济社会行为对空间区位的合理占据,才能真正实现区域之间的协调发展和空间共生。     

GPS揭示的现今地壳运动与地震前兆特征

利用“中国地壳运动观测网络”产出的GPS观测资料,采用球坐标系下非连续变形算法对资源进行计算,以此为基础,对我国大陆地块及其边界带运动与形变进行了分析。对GPS基准站的连续观测序列采用小波变换进行分解变换,分析了部分震例,探讨了从GPS连续观测序列提取地震前兆的方法。初步取得两点认识：（1）7级以上的大地震主要发生在走滑运动量大的活动边界,且与高应变率地块有关,这可以作为地震中长期预测判据;（2）GPS基准站连续观测序列中的低频段,地震前6个月或稍长时段有一定的前兆异常出现,这可以作为地震中短期预测判据。     

东海超高压榴辉岩中绿帘石、褐帘石、磷灰石和钍石集合体的电子探针成分和化学定年研究

中国大陆超深钻(CCSD)主孔从100米到3000米切穿含柯石英榴辉岩,为系统研究大陆深俯冲过程中含稀土元素副矿物提供了机会。本文报道了该钻孔榴辉岩存在发现的绿帘石、褐帘石、磷灰石和钍石复合颗粒。它们以同心环带结构为特征,从边部向中心依次为绿帘石、褐帘石和磷灰石;钍石既可包裹再磷灰石中,也可见于褐帘石中。电子探针分析显示,褐帘石不仅含有较高的轻稀土元素(LREE2O3=23．36wt％),而且可含有2．6wt％ThO2。根据绿帘石和褐帘石的电子探针高分辨U、Th、Pb成分计算得到绿帘石边部的形成年龄为738±88Ma,该年龄与大别-苏鲁地体榴辉岩的元古代源岩的年龄相当,因此,绿帘石可能为残留相。相反,褐帘石的年龄为220±41Ma,与大别-苏鲁超高压变质年龄相近。因此,褐帘石与磷灰石和钍石一起应该为超高压变质事件的产物。根据绿帘石、褐帘石及其共生的磷灰石和钍石的结构、成分特征和化学定年结果,我们推测绿帘石与可能已完全消耗的独居石很可能为变质副矿物组合的先驱矿物。独居石-绿帘石复合颗粒在榴辉岩相高压／超高压变质过程中反应形成磷灰石+钍石+褐帘石组合。     

Interannual Thermocline Signals and El Nio-La Nia Turnabout in the Tropical Pacific Ocean

One of the fundamental questions concerning the nature and prediction of the oceanic states in the equatorial eastern Pacific is how the turnabout from a cold water state (La Nina) to a warm water state (El Nino) takes place, and vice versa. Recent studies show that this turnabout is directly linked to the interannual thermocline variations in the tropical Pacific Ocean basin. An index, as an indicator and precursor to describe interannual thermocline variations and the turnabout of oceanic states in our previous paper (Qian and Hu, 2005), is also used in this study. The index, which shows the maximum subsurface temperature anomaly (MSTA), is derived from the monthly 21-year (1980-2000) expendable XBT dataset in the present study. Results show that the MSTA can be used as a precursor for the occurrences of El Nino (or La Nina) events. The subsequent analyses of the MSTA propagations in the tropical Pacific suggest a one-year potential predictability for El Nino and La Nina events by identifying ocean temperature anomalies in the thermocline of the western Pacific Ocean. It also suggests that a closed route cycle with the strongest signal propagation is identified only in the tropical North Pacific Ocean. A positive (or negative) MSTA signal may travel from the western equatorial Pacific to the eastern equatorial Pacific with the strongest signal along the equator. This signal turns northward along the tropical eastern boundary of the basin and then moves westward along the north side of off-equator around 16°N. Finally, the signal returns toward the equator along the western boundary of the basin. The turnabout time from an El Nino event to a La Nina event in the eastern equatorial Pacific depends critically on the speed of the signal traveling along the closed route, and it usually needs about 4 years. This finding may help to predict the occurrence of the El Nino or La Nina event at least one year in advance.     

海南乐东地区抱伦金矿矿石特征及其成因矿物学意义

抱伦金矿为大型中温热液石英脉型矿床,矿石以含金石英脉型为主,次为含金蚀变岩型。主要金属矿物为黄铁矿和磁黄铁矿,次要金属矿物20多种;脉石矿物有石英、方解石、绢云母和绿泥石等。金矿物主要为自然金,次为金、铋和银的固溶体,含Au8.20%～99.30%,Ag≤52.71%,Bi≤91.20%。铋、碲矿物有自然金属、硫化物、铋化物、硫盐和碲化物等类型。金矿石含Bi0.18×10-6～16×10-6,平均4.11×10-6,富矿石中达419×10-6。该矿床属较特殊的富铋类型,与琼西戈枕剪切带的金矿有相似之处,在琼西-粤东金矿带大陆一侧存在类似矿床,它们在成因上均应与岩浆和韧—脆性断裂活动有关。     

新疆西天山达巴特铜矿床地质特征和成矿时代研究

本文通过对西天山地区比较典型的达巴特斑岩铜钼矿床矿石中辉钼矿Re-Os的直接定年研究,结合区域地质演化和其他年代学资料,探讨了西天山赛里木和博罗科努地区斑岩铜多金属成矿带的成矿地球动力学背景和成矿机制。结果显示达巴特矿床中辉钼矿Re-Os年龄为301±20Ma,表明成矿作用发生于晚石炭世。矿床形成于别珍套—科古琴石炭纪岛弧带,成岩成矿与石炭纪巴音沟洋壳向南的俯冲作用密切相关,可能的成矿机制是由于洋壳向南对赛里木隆起带陆壳基底的俯冲,岛弧基底断裂系向北逆冲,导致一系列与斑岩矿床有关的中酸性岩浆活动,区域深大断裂为岩浆的上侵提供了条件。