Predicting size effect on diffusion-limited current density of oxygen reduction by copper wire

The size effect of copper wire radius (0.04–0.82 mm) on the diffusion-limited current density of an oxygen reduction reaction in stagnant simulated seawater (naturally aerated 0.5 mol/L NaCl) is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) and compared with the results obtained in 0.5 mol/L H2SO4. In the oxygen diffusion-limited range, size effect is found to occur independent of electrolytes, which is attributed to non-linear diffusion. Additionally, to sati...     

山区遥感图像自动分类研究——以西南地区为例(英文)

In mountainous areas, it is the undulant terrain, various types of geomorphic and land use that make the remote sensing images great metamorphism. Moreover, due to the elevation, there are many areas covered with shadow, clouds and snow that make the images more inaccurate. As a result, it would be very difficult to carry out auto-classification of RS images in these areas. The study took Southwest China as the case study area and the TM images, SPOT images as the basic information sources assisted by the a...     

野生二粒小麦 Triticum dicoccoides抗杀锈病基因 YrH52分子定位的初步研究(英文)

主要对以色列野生二粒小麦赫尔蒙种群中分离获得的一个抗条锈病基因进行了分子定位研究 ,将源于赫尔蒙山具抗杀锈病的种系 T.dicoccides H52与普通的栽培种 Langdon进行杂交并创建了 F2 代遗传图。研究发现 H52种系抗条锈病的能力由一种显性基因控制 ,将其暂定名为 Yr H52。从 1 2 0个微卫星标记中 ,已经检测到来自亲本 91 %的多态性 ,而且从其中 56个微卫星分子标记中产生了 79个分离的位点 ,有 9个位点显示出了与 Yr H 52基因连锁 ,其重组率 0 .0 2～ 0 .3 5,遗传距离 2 .0 0～ 4 3 .3 7cm之间 ,L OD值 3 .56～ 54.2 2。由 1 0个微卫星位点和 Yr H52构建的染色体 1 B遗传图 ,其图距全长为 1 0 1 .5cm。Yr H52基因位于 Xgwm2 64 a和 Xgwm2 64 c之间 ,且与 Xgwm2 64 a、Xgwm1 8紧密连锁 ,两侧依次分别与 Xgwm1 3 1 a、Xgwm63 6b、Xgwm2 64 c、Xgwm4 0 3 a、Xgwm1 53、Xgwm550 a和 Xgwm1 2 4连锁。同时 ,Yr H52也与 REL P标记物 N or1紧密连锁 ,图距 1 .4 cm,L OD2 9.62。这显然与野生二粒小麦另一个抗条锈病基因 Yr1 5不同 ,研究证明 Yr1 5与 N or1图距是 1 1 .0 cm。     

河流相沉积中准层序与短期基准面旋回对比研究——以四川中部须家河组为例

通过详细分析曲流河沉积动力学特点,在四川中部须家河组建立了河流相沉积的准层序模式。曲流河沉积中可发育粒级向上变细准层序,也可以发育粒级向上变粗的准层序。辫状河准层序表现为粒级向上变细、河道水体向上变浅的准层序,而粒级向上变粗的准层序不发育。河流相准层序界面是河道砂体底部的冲刷侵蚀面,在粒级向上变粗的泛滥平原-决口扇或决口河道沉积中,准层序界面为暴露过泥岩与上部洪水期的暗色泥岩间的界面。将河流相准层序与短期基准面旋回进行精细的分析与对比认为,二者在层序地层学级次划分中时限相当,发育时间为0.01~0.05Ma;二者的界面是相同的,均为河道砂体底部的冲刷侵蚀面或者是暴露过泛滥平原泥岩、根土岩等。河流相中准层序与短期基准面旋回其实是相同时间内沉积的一套相同的沉积体,二者的不同只是分析的角度不同,其实质内容是一致的,即在曲流河短期基准面升降变化过程中,所保留下来的沉积物总是相对河水位是向上变浅的,由位于河水面以下的河道或边滩砂体向上变浅至河水面之上的天然堤、泛滥平原泥岩,此相序特征也正与准层序向上变浅的定义相同。     

赣南天门山-红桃岭钨锡矿田成岩成矿时代精细测定及其地质意义

素有“世界钨都”美誉的赣南产有密集的与花岗岩类侵入体密切相关的钨锡多金属矿床,然而,目前对钨锡成矿和花岗岩成岩年龄还缺乏很好的约束。本文以天门山-红桃岭钨锡矿田为对象,在详细的矿田地质调查和典型矿床解剖基础之上,采用高精度测年技术开展了成岩成矿年代学研究。利用锆石SHRIMPU-Pb法,分别获得天门山似斑状黑云母二长花岗岩体和红桃岭黑云母花岗岩体成岩年龄分别为151.8±2.9Ma(n=14,MSWD=1.3)和151.4±3.1Ma(n=11,MSWD=0.34);利用辉钼矿Re-Os等时线法,分别获得牛岭内带石英脉型和樟斗外带石英脉型钨矿成矿年龄分别为154.9±4.1~154.6±9.7Ma和149.1±7.1Ma(n=6,MSWD=1.3)。可见,本区钨矿床成矿和与之有密切成因关系的花岗岩成岩年龄限定在晚侏罗世,对应于区域华南中生代第二次大规模成矿作用,钨成矿与花岗岩成岩基本不存在时差。     

Coastal permafrost landscape development since the Late Pleistocene in the western Laptev Sea,Siberia

Winterfeld, M., Schirrmeister, L., Grigoriev, M. N., Kunitsky, V. V., Andreev, A., Murray, A. & Overduin, P. P. 2011: Coastal permafrost landscape development since the Late Pleistocene in the western Laptev Sea, Siberia. Boreas, 10.1111/j.1502‐3885.2011.00203.x. ISSN 0300‐9483. The palaeoenvironmental development of the western Laptev Sea is understood primarily from investigations of exposed cliffs and surface sediment cores from the shelf. In 2005, a core transect was drilled between the Taymyr Peninsula and the Lena Delta, an area that was part of the westernmost region of the non‐glaciated Beringian landmass during the late Quaternary. The transect of five cores, one terrestrial and four marine, taken near Cape Mamontov Klyk reached 12 km offshore and 77 m below sea level. A multiproxy approach combined cryolithological, sedimentological, geochronological (¹⁴C‐AMS, OSL on quartz, IR‐OSL on feldspars) and palaeoecological (pollen, diatoms) methods. Our interpretation of the proxies focuses on landscape history and the transition of terrestrial into subsea permafrost. Marine interglacial deposits overlain by relict terrestrial permafrost within the same offshore core were encountered in the western Laptev Sea. Moreover, the marine interglacial deposits lay unexpectedly deep at 64 m below modern sea level 12 km from the current coastline, while no marine deposits were encountered onshore. This implies that the position of the Eemian coastline presumably was similar to today's. The landscape reconstruction suggests Eemian coastal lagoons and thermokarst lakes, followed by Early to Middle Weichselian fluvially dominated terrestrial deposition. During the Late Weichselian, this fluvial landscape was transformed into a poorly drained accumulation plain, characterized by widespread and broad ice‐wedge polygons. Finally, the shelf plain was flooded by the sea during the Holocene, resulting in the inundation and degradation of terrestrial permafrost and its transformation into subsea permafrost.     

Study on Flow Field Around Vertical Breakwater Under Different Overtopping Conditions Based on Numerical Simulation

A numerical wave flume is constructed based on the Reynolds Averaged Navier-Stokes (RANS) equations with turbulence closure by a modified k-ε model to study the viscous interactions of waves with vertical breakwaters for different overtopping cases. The governing equations,the turbulence model,boundary conditions,and solution method for the numerical wave flume are introduced briefly. The reliability of the numerical wave flume is examined by comparing the numerical results with the experimental measurement...     

Evolution of pore space in the Poza Rica trend (Mid-Cretaceous), Mexico

ABSTRACT The Poza Rica trend of the Tampico embayment, Mexico, will ultimately produce more than 2.3 × 10⁹ barrels of oil from Mid-Cretaceous (Albian-Cenomanian) basin-margin deposits. Bioclastic grainstone, packstone, and wackestone are interbedded with polymictic lime breccia and dolomitized debris; all were deposited by sediment gravity flow. Indigenous sediment was pelagic lime mud. Typical reservoir porosities are about 10%; permeabilities average 2 md and rarely exceed 100 md. Porosity is largely the result of selective dissolution of rudist fragments, which were originally aragonite. Detailed petrographic study, with emphasis on the diagenetic products, allows quantitative assessment of porosity at various diagenetic stages from original sediment to reservoir rock. A relatively simple diagenetic history is reflected by about 90% of the samples studied: primary porosity was reduced through lithification of matrix mud and initial cementation by clear, equant to bladed, non-ferroan calcite. Later dissolution produced extensive skelmoldic and minor vuggy porosity. Subsequently, non-ferroan calcite cement reduced porosity before the emplacement of hydrocarbons. Reconstructed sediment porosities are comparable to, but lower than, modern counterparts. The initial phase of cementation and presumed lithification of mud greatly reduced porosity in all lithologies, but appreciably more porosity persisted in grainstone and packstone than in wackestone or mudstone. Dissolution produced a porosity resurrection, which exceeded that of the initial sediment in some grainstones. Calcite cementation and local multiphase quartz cementation and dolomitization reduced porosity to present average values of 8–12% in grain-supported rocks and 3% in mud-supported rocks. The greater persistence of primary porosity and, therefore, permeability in grain-supported rocks probably accounts for their greater secondary porosity development and ultimate reservoir quality. Geometrically averaged permeabilities range from only 0.17 md in wackestone to 3.85 md in dolomite, but differ significantly with rock type and grain size. Permeability increases with porosity in all lithologies; the rate of increase is greater at higher porosities and with coarser grain sizes. The agent for both early cementation and development of secondary porosity appears to have been meteoric water. Subaerial exposure appears to be ruled out, however, by a basin-margin depositional environment and continued burial beneath Upper Cretaceous pelagic sediments. Early exposure to meteoric water can be explained by a hydrologic head developed during penecontemporaenous exposure that produced cavernous porosity in the adjacent Golden Lane trend. Descending meteoric water likely emerged as submarine springs along the Tamabra trend. Deposition of pelagic limestone during the Turonian blanketed part of the Golden Lane escarpment to enhance development of a large freshwater lens; gaps in the blanket localized springs and influenced flow patterns within the Poza Rica field. Analogous freshwater circulation exists today in northern Florida.     

胶东西北部地区金矿床铅同位素特征及其地质意义

胶东地区不同类型金银、铅锌矿床及交代—深熔花岗岩三者的铅同位素特征相似,皆为来自铀针亏损型源区的多阶段铅。在Pb~(207)/Pb~(204)-Pb~(206)/Pb~(204)图解上,它们的投影点可拟合成一条直线。据此,并根据大量的K-Ar、U-Pb、Rb-Sr和Ar~(30)-Ar~(40)年龄数据,得t_1=3.2Ga,t_2=0.15Ga,μ_1=7.07～8.17,W_1=29.16～35.80,Th/U=3.97～4.52。矿石铅与胶东群变质岩岩石铅同位素统计对比表明,金银、铅锌和交代—深熔花岗岩中的铅皆来自再活化的下地壳源铅。     

关于我国1957年旧重力基本网的精度与系统转换

简述了原国家重力基本网(57网)的历史和技术要点,详细地分析了57网的各类误差和产生原因,提出了新、旧系统转换的方法。本文研究表明,57网基本点相对观测的实际精度约为±0.06mgal,仪器平均值误差为1.6×10~(-4)。基本点重力值含-13.56mgal的基准误差和1.9×10~(-4)的尺度差,并含有±0.1～0.2mgal的非线性系统误差。对基本点实行新、旧系统转换误差为±0.05mgal,基本不损失其观测精度。