Development and deployment of a precision underwater positioning system for in situ laser Raman spectroscopy in the deep ocean

The field of ocean geochemistry has recently been expanded to include in situ laser Raman spectroscopic measurements in the deep ocean. While this technique has proved to be successful for transparent targets, such as fluids and gases, difficulty exists in using deep submergence vehicle manipulators to position and control the very small laser spot with respect to opaque samples of interest, such as many rocks, minerals, bacterial mats, and seafloor gas hydrates. We have developed, tested, and successfully deployed by remotely operated vehicle (ROV) a precision underwater positioner (PUP) which provides the stability and precision movement required to perform spectroscopic measurements using the Deep Ocean Raman In situ Spectrometer (DORISS) instrument on opaque targets in the deep ocean for geochemical research. The positioner is also adaptable to other sensors, such as electrodes, which require precise control and positioning on the seafloor. PUP is capable of translating the DORISS optical head with a precision of 0.1 mm in three dimensions over a range of at least 15 cm, at depths up to 4000 m, and under the normal range of oceanic conditions (T, P, current velocity). The positioner is controlled, and spectra are obtained, in real time via Ethernet by scientists aboard the surface vessel. This capability has allowed us to acquire high quality Raman spectra of targets such as rocks, shells, and gas hydrates on the seafloor, including the ability to scan the laser spot across a rock surface in sub-millimeter increments to identify the constituent mineral grains. These developments have greatly enhanced the ability to obtain in situ Raman spectra on the seafloor from an enormous range of specimens.     

Chemistry and distribution of accessory Ni, Co, Fe arsenic minerals in the Pechenga Ni-Cu deposits, Kola Peninsula, Russia

Summary Ni, Co, Fe arsenic minerals are common accessory phases associated with both the Ni-Cu mineralization and country rock sulphides of the Pechenga complex. The majority of the arsenic minerals fall in the cobaltite-gersdorffite series, with minor arsenopyrite, nickeline and maucherite. These minerals are regularly distributed between different types of mineralization. Nickeline, maucherite and gersdorffite occur mainly in hydrothermally altered Ni-Cu sulphide ores, in particular stringer zone sulphides and mineralized talc-carbonate rocks. Arsenopyrite occurs only in pentlandite-free assemblages of the host shales, mainly in remobilized iron sulphide mineralization. The concentrations of Ni and Co in arsenopyrite decrease with the distance from the Ni-Cu bearing intrusions. Cobaltite is an ubiquitous mineral, but Ni-rich cobaltite occurs mainly in the Ni-Cu ores. In general, the transition from Ni-Cu ores to country rocks is marked by the change from Ni-arsenides to Ni-Co sulpharsenides and, finally, to Fe sulpharsenides.Sedimentary pyrite in sulphidic shales contains up to 1.8 wt.% As and was initially enriched in arsenic during sedimentation and diagenesis. Metamorphic recrystallization of authigenic As-bearing pyrite to As-free pyrrhotite led to significant liberation of arsenic during metamorphism. The mobilized arsenic could have been carried by associated metamorphic fluids and then participated in the low-grade alteration of the ultramafic rocks and associated Ni-Cu sulphide ores.

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Zusammensetzung und Verteilung der akzessorischen Ni-, Co und Fe-Arsenminerale in den Nickel-Kupferlagerstätten von Pechenga, Kola-Halbinsel, Rußland

Zusammenfassung Ni-, Co- und Fe-Arsenminerale sind verbreitete akzessorische Phasen, sowohl in den Nickel-Kupfer-Vererzungen, als auch in den Sulfiden der Nebengesteine des PechengaKomplexes. Der Großteil der Arsenminerale ist zur Cobaltit-Gersdorffit-Serie zu stellen. Arsenkies, Nickelin und Maucherit sind in geringeren Mengen vorhanden. Diese Minerale sind zwischen den verschiedenen Vererzungstypen gleichmäßig verteilt. Nickelin, Maucherit und Gersdorffit kommen hauptsächlich in hydrothermal veränderten Ni-Cu-Sulfiderzen vor, besonders in Sulfiden der Stringer-Zone und in mineralisierten Talk-Karbonat-Gesteinen. Arsenkies kommt nur in Pentlandit-freien Paragenesen in den schiefrigen Nebengesteinen, vor allem in einer remobilisierten Eisensulfidvererzung, vor. Die Konzentrationen von Ni, Fe und Co in Arsenkies nehmen mit zunehmender Entfernung von den Ni-Cu-führenden Intrusionen ab. Cobaltit ist ein verbreitetes Mineral, wobei nickelreicher Cobaltit jedoch hauptsächlich in den Nickel-Kupfererzen vorkommt. Im allgemeinen wird der übergang von NickelKupfererzen zu Nebengesteinen durch den übergang von Nickelarseniden zu NickelKobalt-Sulpharseniden und schließlich zu Eisensulpharseniden markiert.Sedimentärer Pyrit in den schiefrigen Nebengesteinen enthält bis zu 1,8 Gew% As, wobei die Arsenanreicherung während der Sedimentation und Diagenese erfolgten. Metamorphe Rekristallisation authigener As-führenden Pyrite zu As-freiem Magnetkies führte zu signifikanter Freisetzung von Arsen während der Metamorphose. Das mobilisierte Arsen dürfte durch metamorphe Fluide transportiert worden sein, die an der niedriggradigen Alteration der ultramafischen Gesteine und der assoziierten NickelKupfererze beteiligt waren.

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With 8 Figures     

1981—2022年藏东南4种界限温度时空变化

基于1981—2022年藏东南（林芝市）4个气象站点的日平均气温数据,采用线性倾向估计、Person系数、Mann-Kendall检验、优势主导分析等方法,分析了藏东南≥0 ℃、≥5 ℃、≥10 ℃和≥15 ℃共4种界限温度的时空变化特征。结果表明：(1)受海拔影响,藏东南4种积温总体呈自东南向西北递减的变化特征,各地≥0 ℃、≥5 ℃、≥10 ℃和≥15 ℃积温分别介于3161.4~4429.9 ℃·d、2869.2~4018.0 ℃·d、2273.3~3258.0 ℃·d和608.8~2133.2 ℃·d。(2)近42 a藏东南4种界限温度均呈初日提前、终日推迟、持续日数延长的趋势,≥10 ℃界限温度变幅最小,除初日外,≥15 ℃界限温度变幅最大。≥0 ℃和≥5 ℃持续日数的延长主要是初日提前引起的,≥10 ℃与≥15 ℃持续日数的增加主要是终日推迟导致的。4种积温均表现出极显著的增加趋势,增幅分别为123.81 ℃·d/10 a、136.71 ℃·d/10 a、76.22 ℃·d/10 a、166.43 ℃·d/10 a。(3)年代际变化上,4种积温具有明显的逐年代际增加态势。21世纪10年代是研究时段内最温暖的10 a,这一时期的4种积温比20世纪80年代增加了174.9~437.2 ℃·d,其中≥15 ℃积温增幅最大。除≥10 ℃外,20世纪80—90年代初日推迟、终日提早、持续日数缩短,而21世纪前20 a则截然相反。(4)M-K检验显示,≥10 ℃初日、终日未发生气候突变,其他界限温度指标发生突变时间多在2004年前后。     

Dissolution rates of pure methane hydrate and carbon-dioxide hydrate in undersaturated seawater at 1000-m depth

To help constrain models involving the chemical stability and lifetime of gas clathrate hydrates exposed at the seafloor, dissolution rates of pure methane and carbon-dioxide hydrates were measured directly on the seafloor within the nominal pressure-temperature (P/T) range of the gas hydrate stability zone. Other natural boundary conditions included variable flow velocity and undersaturation of seawater with respect to the hydrate-forming species. Four cylindrical test specimens of pure, polycrystalline CH₄ and CO₂ hydrate were grown and fully compacted in the laboratory, then transferred by pressure vessel to the seafloor (1028 m depth), exposed to the deep ocean environment, and monitored for 27 hours using time-lapse and HDTV cameras. Video analysis showed diameter reductions at rates between 0.94 and 1.20 μm/s and between 9.0 and 10.6 · 10⁻² μm/s for the CO₂ and CH₄ hydrates, respectively, corresponding to dissolution rates of 4.15 ± 0.5 mmol CO₂/m²s and 0.37 ± 0.03 mmol CH₄/m²s. The ratio of the dissolution rates fits a diffusive boundary layer model that incorporates relative gas solubilities appropriate to the field site, which implies that the kinetics of the dissolution of both hydrates is diffusion-controlled. The observed dissolution of several mm (CH₄) or tens of mm (CO₂) of hydrate from the sample surfaces per day has major implications for estimating the longevity of natural gas hydrate outcrops as well as for the possible roles of CO₂ hydrates in marine carbon sequestration strategies.     

Impact of Fertilization on a Salt Marsh Food Web in Georgia

We examined the response of a salt marsh food web to increases in nutrients at 19 coastal sites in Georgia. Fertilization increased the nitrogen content of the two dominant plants, Spartina alterniflora and Juncus roemerianus, indicating that added nutrients were available to and taken up by both species. Fertilization increased Spartina cover, height, and biomass and Juncus height, but led to decreases in Juncus cover and biomass. Fertilization increased abundances of herbivores (grasshoppers) and herbivore damage, but had little effect on decomposers (fungi), and no effect on detritivores (snails). In the laboratory, herbivores and detritivores did not show a feeding preference for fertilized versus control plants of either species, nor did detritivores grow more rapidly on fertilized versus control plants, suggesting that changes in herbivore abundance in the field were driven more by plant size or appearance than by plant nutritional quality. Community patterns in control plots varied predictably among sites (i.e., 17 of 20 regression models examining variation in biological variables across sites were significant), but variation in the effects of fertilization across sites could not be easily predicted (i.e., only 6 of 20 models were significant). Natural variation among sites was typically similar or greater than impacts of fertilization when both were assessed using the coefficient of variation. Overall, these results suggest that eutrophication of salt marshes is likely to have stronger impacts on plants and herbivores than on decomposers and detritivores, and that impacts at any particular site might be hard to distinguish from natural variation among sites.     

Quantitative reconstruction of the last interglacial vegetation and climate based on the pollen record from Lake Baikal, Russia

Changes in mean temperature of the coldest (T _c) and warmest month (T _w), annual precipitation (P _ann) and moisture index (α) were reconstructed from a continuous pollen record from Lake Baikal, Russia. The pollen sequence CON01-603-2 (53°57′N, 108°54′E) was recovered from a 386 m water depth in the Continent Ridge and dated to ca. 130–114.8 ky BP. This time interval covers the complete last interglacial (LI), corresponding to MIS 5e. Results of pollen analysis and pollen-based quantitative biome reconstruction show pronounced changes in the regional vegetation throughout the record. Shrubby tundra covered the area at the beginning of MIS 5e (ca. 130–128 ky), consistent with the end of the Middle Pleistocene glaciation. The late glacial climate was characterised by low winter and summer temperatures (T _c ~ −38 to −35°C and T _w~11–13°C) and low annual precipitation (P _ann~300 mm). However, the wide spread of tundra vegetation suggests rather moist environments associated with low temperatures and evaporation (reconstructed α~1). Tundra was replaced by boreal conifer forest (taiga) by ca. 128 ky BP, suggesting a transition to the interglacial. Taiga-dominant phase lasted until ca. 117.4 ky BP, e.g. about 10 ky. The most favourable climate conditions occurred during the first half of the LI. P _ann reached 500 mm soon after 128 ky BP. However, temperature changed more gradually. Maximum values of T _c ~ −20°C and T _w~16–17°C are reconstructed from about 126 ky BP. Conditions became gradually colder after ca. 121 ky BP. T _c dropped to ~ −27°C and T _w to ~15°C by 119.5 ky BP. The reconstructed increase in continentality was accompanied by a decrease in P _ann to ~400–420 mm. However, the climate was still humid enough (α~0.9) to support growth of boreal evergreen conifers. A sharp turn towards a dry climate is reconstructed after ca. 118 ky BP, causing retreat of forest and spread of cool grass-shrub communities. Cool steppe dominated the vegetation in the area between ca. 117.5 ky and 114.8 ky BP, suggesting the end of the interglacial and transition to the last glacial (MIS 5d). Shift to the new glaciation was characterised by cool and very dry conditions with T _c ~ −28 to −30°C, T _w~14–15°C, P _ann~250 mm and α~0.5.     

Qualitative Methods for Research on Mapmaking and Map Use

Contemporary cartographic research on mapmaking and map use has a broad mandate and, as a consequence, researchers need a broad suite of methods. Consistent with research developments in other geographic subdisciplines, cartographic researchers now use qualitative methods. They offer the advantage of bringing research closer to the problem‐solving realms of mapmakers and map users. Our purpose here is to discuss an array of qualitative methods for mapmaking and map use. Questionnaires, interviews, and protocol methods are used to gather verbal data about mapmaking and map use. Ethnographies produce data from direct observation of mapmakers and users. Maps also are sources for document analysis. We use examples of published cartographic research to elaborate on each of these methods.     

阿拉斯加北极地区的工程设计和施工经验及教训

阿拉斯加北极地区位于布鲁克斯山以北, 白令海峡以东的北坡地区, 属北极海洋性气候区. 区内寒冷( -10 ～ -6 ℃)、连续多年冻土厚度多在200～300 m, 局部达700 m. 地表湖塘和冰楔多边形广泛分布. 阿拉斯加北极地区的工程建筑活动主要为海军部和商业石油勘探、开发和运输服务. 从20世纪40年代以来, 尽管有不少的曲折和教训, 但成功和可以借鉴的经验很多. 最成功的例子当数普如道湾油气田开发、阿里亚斯卡输油管道工程及其相应的环境保护措施. 工程师为了成功和经济地在北极地区修筑和运行工程设施, 必须从"冷"处着想, 并付诸计划和行动. 设计和施工的工程师必须保持实事求是、不断创新精神, 而不拘泥于中纬度地区的教育、培训, 或行业传统. 从工程勘察、设计到施工阶段, 工程师和从事环境研究的科学家必须密切合作. 工程师需要知道环境参数, 制约因素和可利用的机会; 环境科学家需要知道工程师的施工设计和问题, 理解工程限制条件、设备工作能力, 以及备选方案的经济学问题. 这些相互理解只能在密切合作中形成, 并能创造工程经济效益和奇迹.     

Highway Roadway Stability Influenced by Warm Permafrost and Seasonal Frost Action: A Case Study from Glennallen, Alaska, USA

Ground temperatures from four of the seven extensively studied highway cross-sections near Gulkana/Glennallen,Alaska during 1954~1962,were chosen to better understand the impacts of highway construction on warm permafrost.Both the thawing of permafrost and seasonal frost action impacted on road surface stability for about 6 years until the maximum summer thaw reached about 3 m in depth.Seasonal frost action caused most of the ensuing stability problems.Unusually warm summers and the lengths of time required to re-freeze the active layer were far more important than the average annual air temperatures in determining the temperatures of the underlying shallow permafrost,or the development of taliks.The hypothesized climate warming would slightly and gradually deepen the active layer and the developed under-lying talik,but its effect would be obscured by unusually warm summers,by warmer than usual winters,and by the vari-able lengths of time of the zero curtains.At least one period of climate mini-cooling in the deeper permafrost during the early 20th century was noted.     

A natural hydrate dissolution experiment on complex multi-component hydrates on the sea floor

Dissolution of natural hydrate cores was measured using time-lapse photography on the seafloor at Barkley Canyon (850 m depth and 4.17 °C). Two types of hydrate fabrics in close contact with one another were studied: a “yellow” hydrate stained with condensate oil and a “white” hydrate. From thermogenic origins, both fabrics contained methane as well as heavier hydrocarbons. These multi-component hydrates were calculated to be well within p-T stability conditions (<200 m water depth needed at 4.17 °C). While stable in pressure and temperature, the hydrates were bathed in under-saturated seawater, which promoted dissolution. The flux of gas from the shrinking yellow hydrate core was 0.15 ± 0.01 mmol gas/m² s, while the white hydrate dissolved faster at 0.25 ± 0.02 mmol gas/m² s. To determine the controlling mechanism for the observed changes in the hydrate cores, experimental results were compared with an engineering correlation for convective mass transfer. Using water velocity as a fitting parameter, the correlation agreed well with results from a previous dissolution experiment on well-characterized synthetic hydrates. Even with a number of other unknowns, when applied to the natural hydrate, the mass transfer correlation predicted the dissolution rate within 20%. This seafloor-based experiment, along with visual observations of seafloor hydrate dissolution over a 3-day period, were used to further understand the fate of natural seafloor hydrates exposed on the seafloor. By showing that mass transfer is the rate-controlling mechanism for dissolution of these natural hydrate outcrops, proper hydrodynamic calculations can be employed to give a refined estimate on hydrate dissolution rates.