Ab initio calculations of the Fe(II) and Fe(III) isotopic effects in citrates,nicotianamine, and phytosiderophore,and new Fe isotopic measurements in higher plants

Iron is one of the most abundant transition metal in higher plants and variations in its isotopic compositions can be used to trace its utilization. In order to better understand the effect of plant-induced isotopic fractionation on the global Fe cycling, we have estimated by quantum chemical calculations the magnitude of the isotopic fractionation between different Fe species relevant to the transport and storage of Fe in higher plants: Fe(II)-citrate, Fe(III)-citrate, Fe(II)-nicotianamine, and Fe(III)-phytosiderophore. The ab initio calculations show firstly, that Fe(II)-nicotianamine is ～3‰ (⁵⁶Fe/⁵⁴Fe) isotopically lighter than Fe(III)-phytosiderophore; secondly, even in the absence of redox changes of Fe, change in the speciation alone can create up to ～1.5‰ isotopic fractionation. For example, Fe(III)-phytosiderophore is up to 1.5‰ heavier than Fe(III)-citrate₂ and Fe(II)-nicotianamine is up to 1‰ heavier than Fe(II)-citrate. In addition, in order to better understand the Fe isotopic fractionation between different plant components, we have analyzed the iron isotopic composition of different organs (roots, seeds, germinated seeds, leaves and stems) from six species of higher plants: the dicot lentil (Lens culinaris), and the graminaceous monocots Virginia wild rye (Elymus virginicus), Johnsongrass (Sorghum halepense), Kentucky bluegrass (Poa pratensis), river oat (Uniola latifolia), and Indian goosegrass (Eleusine indica). The calculations may explain that the roots of strategy-II plants (Fe(III)-phytosiderophore) are isotopically heavier (by about 1‰ for the δ⁵⁶Fe) than the upper parts of the plants (Fe transported as Fe(III)-citrate in the xylem or Fe(II)-nicotianamine in the phloem). In addition, we suggest that the isotopic variations observed between younger and older leaves could be explained by mixing of Fe received from the xylem and the phloem.     

Seismic sequence stratigraphy of Miocene deposits related to eustatic,tectonic and climatic events,Cap Bon Peninsula,northeastern Tunisia

The Cap Bon Peninsula, belonging to northeastern Tunisia, is located in the Maghrebian Alpine foreland and in the North of the Pelagian block. By its paleoposition, during the Cenozoic, in the edge of the southern Tethyan margin, this peninsula constitutes a geological entity that fossilized the eustatic, tectonic and climatic interactions. Surface and subsurface study carried out in the Cap Bon onshore area and surrounding offshore of Hammamet interests the Miocene deposits from the Langhian-to-Messinian interval time. Related to the basin and the platform positions, sequence and seismic stratigraphy studies have been conducted to identify seven third-order seismic sequences in subsurface (SM1-SM7), six depositional sequences on the Zinnia-1 petroleum well (SDM1-SDM6), and five depositional sequences on the El Oudiane section of the Jebel Abderrahmane (SDM1–SDM5). Each sequence shows a succession of high-frequency systems tract and parasequences. These sequences are separated by remarkable sequence boundaries and maximum flooding surfaces (SB and MFS) that have been correlated to the eustatic cycles and supercycles of the Global Sea Level Chart of Haq et al. (1987). The sequences have been also correlated with Sequence Chronostratigraphic Chart of Hardenbol et al. (1998), related to European basins, allows us to arise some major differences in number and in size. The major discontinuities, which limit the sequences resulted from the interplay between tectonic and climatic phenomena. It thus appears very judicious to bring back these chronological surfaces to eustatic and/or local tectonic activity and global eustatic and climatic controls.     

Post‐Palaeozoic uplift history of southeastern Australia revisited: Results from a process‐based model of landscape evolution

Digital elevation models (DEMs) are widely relied upon as representations of the Earth's topographic morphology. The most widely used global DEMs available are ETOPO5, TerrainBase and JGP95E at a 5‐arc‐minute spatial resolution, and the GTOPO30 and GLOBE (version 1) global DEMs at a 30‐arc‐second spatial resolution. This paper presents the results of intercomparisons of these global DEMs over Australia, and with the GEODATA 9‐arc‐second DEM (version 1) of Australia. These DEMs were also compared to an independently produced, altimeter‐derived orthometric height database. This allows not only a totally independent assessment of the quality of these different DEMs over Australia, but also an insight into the ERS‐1 radar altimeter's ability to measure orthometric heights on land. The results of all these comparisons reveal large differences among the DEMs, with the greatest difference between JGP95E and ETOPO5 (mean 49 m, standard deviation ±274 m). The comparison with the altimeter‐derived database shows good agreement with the version 1 GEODATA DEM (mean 2 m, standard deviation ±27 m), thus demonstrating that the altimeter is a viable method for quality assessment of DEMs in lowland regions. A further conclusion is that the representation of the Australian land surface in both the JGP95E and TerrainBase global DEMs is more accurate than the higher resolution GLOBE (version 1) global DEM, even though JGP95E displays a disparity along the 140°E meridian because of the different data sources used in its construction.     

Storm‐dominated sedimentation in a protected basin fringed by coral reefs,Nara Inlet,Whitsunday Islands,Great Barrier Reef,Australia

Hydrodynamic data and samples of bed sediment were collected from Nara Inlet, a small incised embayment in the Whitsunday Islands, central Great Barrier Reef. Measured tidal currents in the inlet do not exceed 0.2 ms^–1 even at spring tides. Swell waves dominate much of the inner shelf of the Great Barrier Reef but are absent from in the inlet due to the presence of a fringing reef at the inlet mouth. On the silty sand floor of the inlet, particle size decreases towards the inlet head. Most of the bed is too coarse to be remobilised by fair‐weather wave and tides, and we predict that bedload sediment transport thresholds are only exceeded in the inlet during cyclones. The observed distribution of bed sediments is consistent with landward dispersal of sediment under storm conditions. Over 20 m of (presumably Holocene) sediments occurs in the inlet and the seismic character of the infill is consistent with the observed textural variation of the modern sediments. We infer that sediment accumulation on the floor of the inlet has been storm dominated throughout much of the Holocene.     

Deformation history of the Naraku Batholith,Mt Isa Inlier,Australia: Implications for pluton ages and geometries from structural study of the Dipvale Granodiorite and Levian Granite

Plutons of the Naraku Batholith were emplaced into Proterozoic metasediments of the northern portion of the Eastern Fold Belt of the Mt Isa Inlier during two intrusive episodes approximately 200 million years apart. Structural relationships and geochronological data suggest that the older plutons (ca 1750 Ma) are contemporaneous with granites of the Wonga Batholith to the west. The Dipvale Granodiorite and the Levian Granite represent these older intrusive phases of the Naraku Batholith, and both contain an intense tectonic foliation, S₁, which is interpreted to have formed during the north‐south shortening associated with D₁ of the Isan Orogeny. The geometry of S₁ form surfaces at the southern end of the Dipvale Granodiorite, and of the previously unrecognised sheeted contact, defines a macroscopic, steeply south‐southwest‐plunging antiform, which was produced by the regional D₂ of the Isan Orogeny. S₁ form surfaces in the Levian Granite define open F₂ folds with wavelengths of several hundred metres. The structural age of emplacement of the Dipvale Granodiorite and the Levian Granite is interpreted to be pre‐ or syn‐ the regional D₁. An intense foliation present in some of the younger (ca 1505 Ma) granites that comprise the bulk of the Naraku Batholith is interpreted to represent S₃ of the Isan Orogeny. Foliations commonly have similar styles and orientations in both the pre‐D₁ and younger plutons. This emphasises the simplicity with which regional fabrics can be, and probably have been, miscorrelated in the Eastern Fold Belt, and that the classification of granites in general on the basis of structural and geometric criteria alone is fraught with danger.     

Late Eocene foraminifers and palaeoenvironment,Cascade Seamount,southwest Pacific Ocean: implications for seamount subsidence and Australia Antarctica Eocene correlation

A Late Eocene foraminiferal fauna of free specimens is recorded from Cascade Seamount, a feature of volcanic origin, whose age and fauna were previously studied only in thin section. The fauna is of Late Eocene (P15) age because of the presence of Globigerapsis index, Globigerapsis rubriformis, Subbotina linaperta, Subbotina angiporoides and Chiloguembelina cubensis. Many typical Eocene indicators, such as Hantkenina, Pseudohastigerina and key globorotaliids, are absent. The age is a little older than that estimated for previous samples from the seamount. The fauna is dominated (78%) by benthic species, especially species of Cibicides that have greater affinities with New Zealand faunas than with coeval southern Australian faunas. The sediment and its fauna accumulated near the lower limits of wave activity, off the coast of a volcano that probably stood at least 400 m above sea level. The location has subsided nearly 1000 m over the past 40 million years to its present water depth of 1000 m, suggesting that the entire East Tasman Plateau was approximately 1000 m above its current depth at the time. Conditions were cool temperate and the fauna lacks any warm water indices, consistent with a palaeolatitude of 55–60°S, but also with cool waters at a time of oscillating conditions in southern Australia and also in Antarctica. There is essentially no infauna and the waters were highly oxygenated in the turbulent zone.     

The lower boundary of the Adelaide system and older basement relationships in south Australia∗

The stratigraphical problem of defining the lower boundary of the Adelaide System is discussed in relation to the geology of several critical areas in the Adelaide Geosyncline and adjacent shelf‐platform.

The Precambrian stratigraphical succession and geological history is outlined with the aid of Rb/Sr age‐determinations made by Dr W. Compston of the Australian National University.

It is concluded that the lower boundary of the Adelaide System is related to the collapse of older basement positive areas on which a regional erosional surface had developed. This surface is defined by the Callanna Beds, the oldest deposits of Willouran age. Willouran sedimentation began some time between 1,340 m.y. and 1,490 m.y. ago. Erosion of the basement rocks probably occupied a major early part of this time interval.     

Tsunamis as geological agents

When a tsunami wave series approaches and interacts with a coast, the consequent passage shorewards of great volumes of water and their invasion of the land, especially within bays and up river valleys, results in the disturbance of existing sediment and the removal seawards of land debris and coastal and shallow‐water marine sediments. Tsunami action builds up sequences of peculiar sediments in shallow water; it at least assists in the formation and maintenance of submarine canyons and, through them, produces turbidity currents of a particularly powerful kind. Tsunami action may explain many puzzling sedimentary phenomena, for example, sudden and drastic changes in near‐shore bathymetry; the formation of chaotic sediments such as some paraconglomerates and edgewise conglomerates. It offers solutions to problems arising from the study of turbiditic sequences, both modern and ancient.     

Correlation of the middle devonian formations of Australia

In the Precambrian rocks west and southwest of the Mount Isa Fault three significant fold generations are recognized. Within individual successions, units containing an early phase of deformation are juxtaposed by a late fault against a sequence that does not share these earlier events.

Many of the large‐scale structures in the Judenan Beds are first‐generation folds, whereas west of the Judenan Beds the area is dominated by second‐generation folds. These two sets of folds are tentatively correlated and are referred to as the Judenan Folds. An earlier set of pre‐Judenan folding is only found in the units west of the Judenan Beds. One phase of the Sybella Granite is also associated with the Judenan folding. Later small‐scale folds associated with a crenulation cleavage are, however, of little regional importance and are commonly found only in zones of highly deformed rocks.     

The geology and palaeohydrology of the Kow Swamp fossil hominid site,Victoria, Australia

During a lake‐full phase at the end of the Pleistocene Period, lacustrine silts and aeolian sands were deposited around the eastern margins of Kow Swamp. These sediments have yielded the remains of a large population of early Australian man, retaining certain archaic Homo erectus characteristics.

The lake‐lunette system in which the burials were made provides a geographically isolated situation for the examination of late Pleistocene and Holocene hydrological changes which have left their imprint on the sediments, soils and vegetation.