Time travel and chemical evolution: a look at the outer solar system

Many space scientists think that the chemical conditions today on planets and moons of the outer solar system are similar to conditions on Earth soon after it formed. If so, we can learn much about the chemistry that led to life on this planet. We can also speculate about exotic habitats that might have given rise to other types of life. And if we are able to discern the chemical reactions now occurring in the outer solar system, we may be able to extrapolate these rules to other solar systems, and so define the habitable zones around other stars where the potential for life is high.     

Age of Gimli beach of Lake Agassiz based on new OSL dating

Gimli beach in Manitoba is one of the lowest elevation beaches in the southern Lake Agassiz basin, and is a distinct ridge composed of bedded sand and gravel that rises above the lake plain and extends for more than 40 km. Ten new optically stimulated luminescence (OSL) ages from Gimli beach yield ages mostly ranging from 9.7 ± 0.7 to 10.5 ± 0.8 ka (average 10.3 ± 0.5 ka), which is older by 0.6 to >1.0 ka than age estimates of previous researchers. Two of our new OSL ages are notably older than the others, dating to ~11.3 ± 0.8 and 13.9 ± 1.0 ka, which we attribute to poorly bleached sands. We ascribe an age of about 10 ka to Gimli beach, which is several centuries before overflow from Lake Agassiz and its vast drainage basin shifted from the western Great Lakes to glacial Lake Ojibway and the St. Lawrence Valley.     

Quantitative elemental mapping of granulite-facies monazite: Textural insights and implications for petrochronology

Texturally complex monazite grains contained in two granulite-facies pelitic migmatites from southern Baffin Island, Arctic Canada, were mapped by laser ablation-inductively coupled plasma-mass spectrometry (using spot sizes ≤5 µm) to quantitatively determine the spatial variation in trace element chemistry (with up to 1,883 analyses per grain). The maps highlight the chemical complexity of monazite grains that have experienced multiple episodes of growth, resorption and chemical modification by dissolution–precipitation during high-grade metamorphism. Following detailed chemical characterization of monazite compositional zones, a related U–Pb data set is re-interpreted, allowing petrologically significant ages to be extracted from a continuum of concordant data. Synthesis of these data with pseudosection modelling of prograde and peak conditions allows for the temporal evolution of monazite trace element chemistry to be placed in the context of the evolving P–T conditions and major phase assemblage. This approach enables a critical evaluation of three commonly used petrochronological indicators: linking Y to garnet abundance, the Eu anomaly to feldspar content and Th/U to anatectic processes. Europium anomalies and Th/U behave in a relatively systematic fashion, suggesting that they are reliable petrochronological witnesses. However, Y systematics are variable, both within domains interpreted to have grown in a single event, between grains interpreted to be part of the same age population, and between samples that experienced similar metamorphic conditions and mineral assemblages. These observations caution against generalized petrological interpretations on the basis of Y content, as it suggests Y concentrations in monazite are controlled by domainal equilibria. The results reveal a c. 45 Myr interval between prograde metamorphism and retrograde melt crystallization in the study area, emphasizing the long-lived nature of heat flow in high-grade metamorphic terranes. Such long timescales of metamorphism would be assisted by the growth, retention and dominance of high-Th suprasolidus monazite, as observed in this study, contributing to the radiogenic heating budget of mid- to lower-crustal environments. Careful characterization of monazite grains suggests that continuum-style U–Pb data sets can be decoded to provide insights into the duration of metamorphic processes.     

The abundances of ammonia in the atmospheres of Jupiter,Saturn, and Titan

An investigation of low-resolution ratio spectra of Jupiter, Saturn, and Titan in the region 5400–6500 Å has permitted new evaluations of ammonia absorption bands. The distribution of ammonia over the disk of Jupiter is very inhomogeneous. The carbon-to-nitrogen ratio is distinctly different from the solar value, but this is probably a result of uneven mixing of methane and ammonia, as suggested previously by Kuiper, rather than a compositional anomaly. The abundance of ammonia on Saturn also shows spatial variations, but appears constant in time over a 3-yr period. Two weak, unidentified absorptions were discovered in the red region of Titan's spectrum, in the absence of any detectable ammonia. The new upper limit is ηN < 120 cm-am.     

The structural,geometric and volumetric changes of a polythermal Arctic glacier during a surge cycle: Comfortlessbreen,Svalbard

Various parameters of the most recent surge of the polythermal glacier Comfortlessbreen in northwest Svalbard, have been assessed through a combination of remote sensing and ground observations. Analysis of a digital elevation model time‐series shows a marked change in the geometry of the glacier from quiescence (1990 and earlier) into the late surge phase (2009). The transfer of 0.74 km³ of ice caused up to 80 m of surface drawdown in the reservoir area, above the equilibrium line, whilst ice built up in a spatially concentrated manner in the receiving zone, below the equilibrium line. A ramp of ice, c. 100 m above quiescent level, developed in the lower reaches of the glacier late in the surge. Also in the lower reaches of the glacier, structures attributable to the passage of a kinematic wave are identified and the migration of a surge front on the glacier is thus inferred. In a conceptual model, we consider that a bend in the valley, in which the glacier resides, and convergence with tributary glaciers, to be significant factors in the style of surge evolution. Their flow‐restrictive interference results in slow initial mass‐transfer and the growth of a surge front within 3–4 km of the terminus. Copyright © 2015 John Wiley & Sons, Ltd.     

The quaternary glacial history of the Lahul Himalaya,northern India

This paper presents the first glacial chronology for the Lahul Himalaya, Northern India. The oldest glaciation, the Chandra Glacial Stage, is represented by glacially eroded benches at altitudes greater than 4300 m above sea-level. This glaciation was probably of a broad valley type. The second glaciation, the Batal Glacial Stage, is represented by highly weathered and dissected lateral moraines, which are present along the Chandra valley and some of its tributaries. This was an extensive valley glaciation. The third major glaciation, the Kulti Glacial Stage, is represented by well-preserved moraines in the main tributary valleys of the Chandra valley. This represents a less extensive valley glaciation. Two minor glacial advances, the Sonapani I and II, are represented by small sharp-crested moraines, which are within a few hundred metres or few kilometres of the present-day glaciers. The change in style and extent of glaciation is attributed to an increase in aridity throughout the Quaternary, due either to global climatic change or uplift of the Pir Panjal mountains to the south of Lahul, which restricted the northward penetration of the south Asian summer monsoon. © 1996 John Wiley & Sons, Ltd.     

Mineralogical and Geochemical Constraints on the Sediment Sources of Late Stone Age Pottery from the Birimi Site,Northern Ghana

The mineralogy and bulk chemical compositions of 15 Kintampo (Late Stone Age) potsherds from the Birimi site on the Gambaga Escarpment and eight samples of local sediment were determined with the intent of characterizing these wares and identifying the material used in their manufacture. Sediment from clay pits still used by potters north of the escarpment contains iron‐rich laterite clasts (100 × XFeO_t = 100 × FeO_t/[FeO_t + Al₂O₃ + SiO₂] ≥10). Sedimentary clasts in stream sediments are relatively siliceous and iron‐poor (100 × XFeO_t < 10). Bulk geochemical data together with the compositions of lithic clasts (laterite, siltstone/sandstone) link the pottery to sediment sources, including escarpment sediments not presently used by Ghanaian potters. Fresh granite clasts found in some of the sherds were not found in the analyzed sediment samples, although some of their distinctive mineralogical constituents (e.g., variably barian alkali feldspar) are present. The analytical data suggest that pots found at Birimi were made locally by mixing escarpment sediment with clay and stream sediment brought in from below the escarpment. This contrasts with present‐day practice, whereby the pots themselves are imported. The place where Birimi pottery was made and the outcrop source of aluminous sediment (mudstone with an “escarpment” trace element signature) used in these wares, however, remain unidentified. © 2013 Wiley Periodicals, Inc.     

Geomorphic response to an active transpressive regime: a case study along the Chaman strike‐slip fault,western Pakistan

The Chaman left‐lateral strike‐slip fault bounds the rigid Indian plate boundary at the western end of the Himalayan‐Tibetan orogen and is marked by contrasting topographic relief. Deformed landforms along the fault provide an excellent record for understanding this actively evolving intra‐continental strike‐slip fault. The geomorphic response of an active transpessional stretch of the Chaman fault was studied using digital elevation model (DEM) data integrated with Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) Visible and Near Infrared/Short Wave Infrared (VNIR/SWIR) and images from GeoEye‐1. Geologic and geomorphic mapping helped in reconstructing the Late Quaternary landscape history of this transpessional strand of the Chaman strike‐slip fault and the associated Spinatizha thrust fault in western Pakistan. Topographic analysis of a part of the transpression (the thrust bounded Roghani ridge) revealed northward growth of the Spinatizha fault with the presence of three water gaps and two corresponding wind gaps. Geomorphic indices including stream length‐gradient index, mountain front sinuosity, valley floor width to valley height ratios, and entrenchment of recent alluvial fan deposits were used to define the lateral growth and direction of propagation of the Spinatizha fault. Left‐lateral displacement along Chaman fault and uplift along the Spinatizha fault was defined using topographic analysis of the Roghani ridge and geomorphic mapping of an impressive alluvial fan, the Bostankaul fan. The landforms and structures record slip partitioning along the Indian plate boundary, and account for the convergence resulting from the difference in the Chaman fault azimuth and orientation of the velocity vector of the Indian plate. Copyright © 2012 John Wiley & Sons, Ltd.     

Geological interpretation of a deep seismic‐reflection transect across the boundary between the Delamerian and Lachlan Orogens,in the vicinity of the Grampians,western Victoria

A deep seismic‐reflection transect in western Victoria was designed to provide insights into the structural relationship between the Lachlan and the Delamerian Orogens. Three seismic lines were acquired to provide images of the subsurface from west of the Grampians Range to east of the Stawell‐Ararat Fault Zone. The boundary between the Delamerian and Lachlan Orogens is now generally considered to be the Moyston Fault. In the vicinity of the seismic survey, this fault is intruded by a near‐surface granite, but at depth the fault dips to the east, confirming recent field mapping. East of the Moyston Fault, the uppermost crust is very weakly reflective, consisting of short, non‐continuous, west‐dipping reflections. These weak reflections represent rocks of the Lachlan Orogen and are typical of the reflective character seen on other seismic images from elsewhere in the Lachlan Orogen. Within the Lachlan Orogen, the Pleasant Creek Fault is also east dipping and approximately parallel to the Moyston Fault in the plane of the seismic section. Rocks of the Delamerian Orogen in the vicinity of the seismic line occur below surficial cover to the west of the Moyston Fault. Generally, the upper crust is only weakly reflective, but subhorizontal reflections at shallow depths (up to 3 km) represent the Grampians Group. The Escondida Fault appears to stop below the Grampians Group, and has an apparent gentle dip to the east. Farther east, the Golton and Mehuse Faults are also east dipping. The middle to lower crust below the Delamerian Orogen is strongly reflective, with several major antiformal structures in the middle crust. The Moho is a slightly undulating horizon at the base of the highly reflective middle to lower crust at 11–12 s TWT (approximately 35 km depth). Tectonically, the western margin of the Lachlan Orogen has been thrust over the Delamerian Orogen for a distance of at least 25 km, and possibly over 40 km.     

From London to Liverpool: Evidence for a Limehouse–Reid porcelain connection based on the analysis of sherds from the Brownlow Hill (ca. 1755–1767) factory site

The diversity of Brownlow Hill porcelains of the W^m Reid & Co. era is due to the remarkably wide range in the composition of their pastes and glazes and inferred firing conditions relative to the initial vitrification temperature. Sixteen of 21 analyzed sherds from the factory site are bone‐ash wares that display large variations in their bulk chemical composition. The remaining samples have silicious‐aluminous (akin to “stone china” sensu Richard Pococke in 1750) and silicious‐aluminous‐calcic (“S‐A‐C”) compositions that resemble Limehouse (London) and Pomona (Staffordshire) porcelains produced during the 1740s. The mineralogy of the Brownlow Hill S‐A‐C sherds suggests firing at a relatively high temperature (T_max approaching 1400°C, based on relations on the SiO₂‐Al₂O₃‐CaO phase diagram), thereby obscuring the identity of some of the ingredients (e.g., the source of CaO) used in their manufacture. Limehouse and Brownlow Hill may have been linked through the activities of William Ball, who is mentioned in connection with both factories, or indirectly via former Limehouse staff later employed at the Pomona factory, located not far from a W^m Reid & Co. branch factory in Shelton, Stoke‐on‐Trent. In terms of a time line, knowledge of these pastes appears to have spread first from London to Staffordshire, and then to Liverpool. © 2003 Wiley Periodicals, Inc.