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71.
Occurrence of perfluorinated compounds in water, sediment and mussels from the Cantabrian Sea (North Spain) 总被引:1,自引:0,他引:1
Gómez C Vicente J Echavarri-Erasun B Porte C Lacorte S 《Marine pollution bulletin》2011,62(5):948-955
Perfluorinated compounds (PFCs) have emerged as significant global environmental pollutants with persistent, bioaccumulative and toxic properties. The aim of this study was to determine the occurrence of PFCs in water (wastewater, submarine emissaries and port-waters), sediment and transplanted mussels in estuarine areas of high urban and industrial impact from Northern Spain. Five PFCs of industrial use were studied: perfluorooctanesulfonate, perfluorohexanesulfonate, perfluorobutanesulfonate, perfluorooctanoate acid and perfluorononanoate acid. After selective extraction, samples were analyzed by Ultra Performance Liquid Chromatography coupled to tandem mass spectrometry. ΣPFCs ranged from 0.06 to 10.9 ng/L in water, with higher levels in wastewater treatment plants effluents and port waters than in submarine emissaries. Little accumulation was observed in sediments and mussels with ΣPFCs ranging from 0.01-0.13 ng/g dw and 0.01-0.06 ng/g ww, respectively. Most ubiquitous compounds were PFOS and PFOA. Mass fluxes of PFCs to the Cantabrian Sea are estimated and the impact to the coastal ecosystem is discussed. 相似文献
72.
Pedro Manuel Anastácio Emília Pereira Leite Margarida Ferreira Luís Vicente Alexandra Marçal Correia 《Limnologica》2011,41(3):228-234
The red swamp crayfish, Procambarus clarkii, and the eastern mosquitofish, Gambusia holbrooki have been introduced worldwide, but the interactions between these invasive species are not well known. The effects of crayfish presence, crayfish size and water depth on the consumption of G. holbrooki by P. clarkii were analyzed, as were the effects of mosquitofish presence and water depth on the consumption of recently hatched crayfish (RHC) by mosquitofish. To better understand this subject we conducted aquaria and open air mesocosm experiments simulating a rice field section. Aquarium experiments showed that P. clarkii consumes G. holbrooki and that G. holbrooki consumes RHC. Adult crayfish size did not significantly affect the consumption of mosquitofish and water depth had no effect on the consumption of G. holbrooki by P. clarkii and vice versa. In the outdoor mesocosm experiments P. clarkii caused no statistically significant effect on G. holbrooki numbers or biomass when compared with controls without crayfish. In spite of this, the analysis of crayfish stomach contents clearly demonstrated that several G. holbrooki individuals were consumed, indicating that crayfish can profit from the presence of G. holbrooki. Results from our study suggest that in shallow pools there are strong interactions between the two invasive species since adult crayfish predate mosquitofish and mosquitofish predate recently hatched crayfish. Therefore, there are bidirectional trophic interactions between these invasive species which change depending on their relative size. We believe that these interactions should become more relevant in confined areas such as small shallow pools formed during the late summer and autumn. 相似文献
73.
Geophysical flows of practical interest encompass turbulent boundary layer flows. The velocity profile in turbulent flows
is generally described by a log- or a power-law applicable to certain zones of the boundary layer, or by wall-wake law for
the entire zone of the boundary layer. In this study, a novel theory is proposed from which the power-law velocity profile
is obtained for the turbulent boundary layer flow. The new power-law profile is based on the conservation of mass and the
skin friction within the boundary layer. From the proposed theory, analytical expressions for the power-law velocity profile
are presented, and their Reynolds-number dependency is highlighted. The velocity profile, skin friction coefficient and boundary
layer thickness obtained from the proposed theory are validated by the reliable experimental data for zero-pressure gradient
turbulent boundary layers. The expressions for Reynolds shear stress and eddy viscosity distributions across the boundary
layer are also obtained and validated by the experimental data. 相似文献
74.
Impact of subsurface rock fragments on runoff and interrill soil loss from cultivated soils 总被引:1,自引:0,他引:1
Field and laboratory studies have indicated that rock fragments in the topsoil may have a large impact on soil properties, soil quality, hydraulic, hydrological and erosion processes. In most studies, the rock fragments investigated still remain visible at the soil surface and only properties of these visible rock fragments are used for predicting runoff and soil loss. However, there are indications that rock fragments completely incorporated in the topsoil could also significantly influence the percolation and water distribution in stony soils and therefore, also infiltration, runoff and soil loss rates. Therefore, in this study interrill laboratory experiments with simulated rainfall for 60 min were conducted to assess the influence of subsurface rock fragments incorporated in a disturbed silt loam soil at different depths below the soil surface (i.e. 0.001, 0.01, 0.05 and 0.10 m), on infiltration, surface runoff and interrill erosion processes for small and large rock fragment sizes (i.e. mean diameter 0.04 and 0.20 m, respectively). Although only small differences in infiltration rate and runoff volume are observed between the soil without rock fragments (control) and the one with subsurface rock fragments, considerable differences in total interrill soil loss are observed between the control treatment and both contrasting rock fragments sizes. This is explained by a rapid increase in soil moisture in the areas above the rock fragments and therefore a decrease in topsoil cohesion compared with the control soil profile. The observed differences in runoff volume and interrill soil loss between the control plots and those with subsurface rock fragments is largest after a cumulative rainfall (Pcum) of 11 mm and progressively decreases with increasing Pcum. The results highlight the impacts and complexity of subsurface rock fragments on the production of runoff volume and soil loss and requires their inclusion in process‐based runoff and erosion models. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
75.
On November 4th 2007, along the Grijalva River in the state of Chiapas, Mexico, has occurred one of the largest landslides
ever known. This landslide, known as Juan del Grijalva, destroyed the town of the same name, killing 20 people, and moved 55 million cubic meters of rock and debris down slope
to completely block the Grijalva River. In order to understand the characteristics and factors that triggered the Juan del
Grijalva landslide, geologic studies were conducted at the site. The results indicate that the landslide was composed of a
lithologic sequence of thin-bedded shales and thin to medium-thick-bedded sandstones. This was faulted into several blocks
dipping in the same sense as the mass movement. The main triggering factor was the increment of the pore pressure into the
lithologic unit due to water saturation after 5 days of heavy rain before the incident. According to records from the last
century, the Juan del Grijalva mass movement represents one of the largest mass movements recorded all over the world. The
risk conditions of the area after the landslide lead to the rapid construction of an artificial channel to drain the accumulating
mass of water upstream and therefore prevent a future catastrophic inundation down stream. 相似文献
76.
Florencia Botto Esteban Gaitán Hermes Mianzan Marcelo Acha Diego Giberto Agustín Schiariti Oscar Iribarne 《Estuarine, Coastal and Shelf Science》2011
The Río de la Plata (34° 36′ S, 55° 58′ W; Argentina and Uruguay) estuary, one of the most important South American estuarine environments, is characterized by weak seasonal freshwater discharge, low tidal amplitude (<1 m), a wide and permanent connection to the sea, and a salt-wedge regime. Using stable isotope analysis, we explored the relative importance of the different sources of primary production in the food web. Our results show that phytoplankton and macrodetritus from terrestrial salt and freshwater marshes both contribute to the food web of the Río de la Plata estuary. On the basis of the sampled species, we identified four trophic levels. The clam Mactra isabelleana, the calanoid copepod Acartia tonsa, and the opossum shrimp Neomysis americana are the primary consumers. The rays Atlantoraja castelnaui and Squatina guggenheim and the shark Galeorhinus galeus are the top predators. The Río de la Plata food web shows an important input of nutrients derived from phytoplankton. Rays, sharks, and predatory gastropods reveal an important contribution of C4 plants (likely Spartina spp.). However, production derived from C3 plants is also important for some species. The fishes Brazilian menhaden, Brevoortia aurea; the stripped weakfish Cynoscion guatucupa; and the whitemouth croaker, Micropogonias furnieri, showed differences in their isotopic signatures as juveniles and adults, indicating different food sources, and they were therefore treated as different components of the food web. Our data suggest that detritus from salt and freshwater marshes is reaching the Río de la Plata estuary and can be an important allocthonous source of energy to this environment. 相似文献
77.
Andrés García García Carolina Perpiñá Carlos de Alfonso Vicente Hernández 《Earth Science Informatics》2013,6(4):199-207
This paper presents the integration of desktop grid infrastructure with GIS technologies, by proposing a parallel resolution method in a generic distributed environment. A case study focused on a discrete facility location problem, in the biomass area, exemplifies the high amount of computing resources (CPU, memory, HDD) required to solve the spatial problem. A comprehensive analysis is undertaken in order to analyse the behaviour of the grid-enabled GIS system. This analysis, consisting of a set of the experiments on the case study, concludes that the desktop grid infrastructure is able to use a commercial GIS system to solve the spatial problem achieving high speedup and computational resource utilization. Particularly, the results of the experiments showed an increase in speedup of fourteen times using sixteen computers and a computational efficiency greater than 87 % compared with the sequential procedure. 相似文献
78.
79.
Maria Teresa Gómez-Pugnaire Peter Ulmer Vicente López-Sánchez-Vizcaíno 《Contributions to Mineralogy and Petrology》2000,139(4):436-457
Mafic igneous rocks are widespread in the Nevado-Filábride Complex, the lowermost metamorphic unit of the internal zones
of the Betic Cordilleras. They form intrusive, small, discontinuous bodies, predominantly dikes with subordinate small lava
flows. The entire complex underwent alpine compressional metamorphism during the Paleogene continental collision, resulting
in eclogites and blueschists in the mafic bodies and high-pressure assemblages in the intruded metasediments. Locally, weakly
metamorphosed or completely unmetamorphosed igneous rocks with the same textural features occur as patches surrounded by eclogitized
igneous rocks. The bulk rock chemistry of unmetamorphosed and completely metamorphosed mafic igneous rocks is consistent with
an alkaline to transitional tholeiitic magmatism with typical within-plate geochemical characteristics. All but a few samples
are nepheline normative and display REE and trace element characteristics typical of continental, rift-related magmatism.
This conclusion is strongly supported by the mineral chemistry of the major constituents, in particular the calcic Ti-rich
character of clinopyroxene, the lack of orthopyroxene, and the occurrence of kaersutitic amphibole. Incompatible trace element
abundances and Sr and Nd isotopes support the provenance of these magmas from a variably metasomatized previously depleted
sub-continental lithospheric mantle source.
Received: 5 July 1999 / Accepted: 28 February 2000 相似文献
80.
Ali Mohammadi Mohssen Moazzen Anna Lechmann Oscar Laurent 《International Geology Review》2020,62(15):1931-1948
ABSTRACT We present zircon U-Pb crystallization ages combined with bulk rock major and trace element geochemistry and Sr-Nd-Pb and zircon in-situ Hf isotopic compositions of the Amand and Moro granitoid intrusions in northwest Iran. The Amand and Moro plutons include granite and syeno-diorite with LA-ICP-MS U-Pb zircon ages of 367 ± 6.8 Ma and 351 ± 1.3 Ma, respectively, representative of Late Devonian-Early Carboniferous magmatic activity in NW Iran. Geochemical characteristics such as typical enrichments in alkalis, Nb, Zr, Ga and Y, depletion in P and Sr and fractionated REE patterns with high Ga/Al ratios and Eu negative anomalies are consistent with A-type magmatic signatures. The granitoids are classified as A2-type and within-plate granitoids. The bulk rock geochemistry (enrichments in Th, Nb and, high Th/Yb, Zr/Y ratios) along with low variation of 143Nd/144Nd(i) and 87Sr/86Sr(i) ratios and positive zircon εHf(t) support the role of a mantle plume component for the evolution of the Amand and Moro A-type granitoids in an extensional tectonic environment. In fitting with wider regional knowledge, this magmatism occurred during Paleo-Tethys opening in northern Gondwana. 相似文献