Thermochemistry of sulfide liquids IV: density measurements and the thermodynamics of O–S–Fe–Ni–Cu liquids at low to moderate pressures

We present the results of a series of density experiments in the system O–S–Fe–Ni–Cu. These experiments were designed to extend our understanding of the physical properties of sulfide liquids, and to extend one-bar thermochemical models for sulfide liquids to apply to low to moderate pressures. Density measurements indicate both positive and negative deviations from linear mixing of partial molar volumes across this five-dimensional composition space. In terms of the homogeneous speciation model of Kress (in Contrib Mineral Petrol 154:191–204, 2007), the best fit to experimental data can be achieved by starting with a model where the volume of formation reaction for associated species initially is set to zero. Further refinement of this first-order fit yields a volume mixing model which reproduces experimental data to within nearly the estimated experimental uncertainty. Experimental ultrasonic and X-ray absorption data from the literature, along with the bulk modulus–volume relation of Anderson and Nafe (J Geophys Res 16:3951–3963, 1965), allow the estimation of the pressure dependence of partial molar volumes for sulfide liquid species. The resulting combined thermochemical model should be valid to about 2,000 K and 3 GPa. Application of this thermochemical model in a simple adiabatic magma ascent scenario confirms earlier work suggesting that the pressure dependence of sulfur solubility in sulfide-saturated magma will decrease with increasing pressure along geologically reasonable paths in P–T–– space.     

Shallow landslide susceptibility mapping using high-resolution topography for areas devastated by super typhoon Haiyan

Super typhoon Haiyan, considered as one of the most powerful storms recorded in 2013, devastated the central Philippines region on 8 November 2013 with damage amounting to more than USD 2 billion. Hardest hit is the province of Leyte which is located in central Philippines. Rehabilitation of the areas that were devastated requires detailed hazard maps as a basis for well-planned reconstruction. Along with severe wind, storm surge, and flood hazard maps, detailed landslide susceptibility maps for the cities and municipalities of Leyte (7246.7 km²) province are necessary. In order to rapidly assess and delineate areas susceptible to rainfall-induced shallow landslides, Stability INdex MAPping (SINMAP) software was used over a 5-m Interferometric Synthetic Aperture Radar (InSAR)-derived digital terrain model (DTM) grid. Topographic, soil strength, and hydrologic parameters were used for each pixel of a given DTM grid to compute for the corresponding factor of safety. The landslide maps generated using SINMAP are highly consistent with the landslide inventory derived from high-resolution satellite imagery from 2002 to 2014 with a detection percentage of 97.5 % and missing factor of 0.025. These demonstrate that SINMAP performs well despite the lack of an extensive geotechnical and hydrological database in the study area. The detailed landslide susceptibility classification is useful to identify safe and unsafe areas for reconstruction and rehabilitation efforts. These maps complement the debris flow and structurally controlled landslide hazard maps that are also being prepared for rebuilding Haiyan’s devastated areas.     

Automatic GIS-based system for volcanic hazard assessment

This paper presents an automatic system for the elaboration of volcanic hazard maps and scenarios. The methodology used for the generation of both maps is based on the use of numerical simulation of eruptive processes. The system has been developed in a Geographical Information System (GIS) framework, where models for the numerical simulation of different volcanic hazards have been integrated. The user can select in a toolbar one hazard and then decide whether to generate a scenario map (usually with a unique vent) or a hazard map (generally with a broader source area). Once the input parameters are selected, the system automatically generates the corresponding map. The system also incorporates a module to determine the spatial probability of vent opening, as this could be an important parameter for the computation of hazard maps. The tool has been designed in such a way that the inclusion of new numerical models and functionalities is rather easy. Each numerical model is programmed and implemented as an independent program that is launched from the system and, when it finishes the computation, returns the control to the GIS, where the results are shown. This structure allows that further analyses (specifically, risk analyses, that use as an input a hazard or a scenario map), could be also automated inside the system. Additional information, including tutorial and downloadable files can be found in www.gvb-csic.es.     

Assessment of business interruption time due to direct and indirect effects of the Chiapas earthquake on September 7th 2017

Natural Hazards - After an earthquake, a business often stops operating temporarily or permanently due to direct effects on the building (Initial security protocols and Physical damage to building...     

Prospects of solar axion searches with crystal detectors

A calculation of the expected signal due to Primakoff coherent conversion of solar axions into photons via Bragg scattering in several crystal detectors is presented. The results are confronted with the experimental sensitivities of present and future experiments concluding that the sensitivity of crystal detectors does not challenge the globular cluster limit on the axion-photon coupling g_aγγ. In particular, in the axion mass window m_a 0.03 eV explored with this technique (not accessible at present by other methods), g_aγγ might be constrained down to 10⁻⁹ GeV⁻¹ (the recent helioseismological bound) provided that significant improvements in the parameters and performances of these detectors be achieved and large statistics accumulated. This bound should be considered as a minimal goal for the sensitivity of future crystal experiments. Consequently, finding a positive signal at this level of sensitivity would necessarily imply revisiting other more stringent astrophysical limits derived for the same range of m_a values.     

A long-term volcanic hazard event tree for Teide-Pico Viejo stratovolcanoes (Tenerife,Canary Islands)

We propose a long-term volcanic hazards event tree for Teide-Pico Viejo stratovolcanoes, two complex alkaline composite volcanoes that have erupted 1.8–3 km³ of mafic and felsic magmas from different vent sites during the last 35 ka. This is the maximum period that can be investigated from surface geology and also represents an upper time limit for the appearance of the first phonolites on that volcano. The whole process of the event tree construction was divided into three stages. The first stage included the determination of the spatial probability of vent opening for basaltic and phonolitic eruptions, based on the available geological and geophysical data. The second, involved the analysis of the different eruption types that have characterised the volcanic activity from Teide during this period. The third stage focussed on the generation of the event tree from the information obtained in the two previous steps and from the application of a probabilistic analysis on the occurrence of each possible eruption type. As for other volcanoes, the structure of the Teide-Pico Viejo Event Tree was subdivided into several steps of eruptive progression from general to more specific events. The precursory phase was assumed as an unrest episode of any geologic origin (magmatic, hydrothermal or tectonic), which could be responsible for a clear increase of volcanic activity revealed by geophysical and geochemical monitoring. According to the present characteristics of Teide-Pico Viejo and their past history, we started by considering whether the unrest episode would lead to a sector collapse or not. If the sector collapse does not occur but an eruption is expected, this could be either from the central vents or from any of the volcanoes' flanks. In any of these cases, there are several possibilities according to what has been observed in the period considered in our study. In the case that a sector collapse occurs and is followed by an eruption we considered it as a flank eruption. We conducted an experts elicitation judgement to assign probabilities to the different possibilities indicated in the event tree. We assumed long term estimations based on existing geological and historical data for the last 35 Ka, which gave us a minimum estimate as the geological record for such a long period is incomplete. However, to estimate probabilities for a short term forecast, for example during an unrest episode, we would need to include in the event tree additional information from the monitoring networks, as any possible precursors that may be identified could tell us in which direction the system will evolve. Therefore, we propose to develop future versions of the event tree to include also the precursors that might be expected on each path during the initial stages of a new eruptive event.     

Determination of EC50 Values for Cu,Zn, and Cr on Microorganisms Activity in a Mediterranean Sandy Soil

Ecotoxicity of three potentially toxic metals (PTM) (Cu, Zn, and Cr) in a slightly acidic sandy soil is tested using the soil respiration test (OECD‐217) in order to determine EC₅₀ values for the carbon transformation activity of microorganisms. Addition of an organic amendment of Populus leaves is also crossed with metal spiking in order to investigate possible interaction with metal toxicity. Soil respiration is measured at day 1 and 28 after the soil spiking with the PTM to assess short‐term effects on soil microbial activity. Of the three metals tested, Cu shows the highest toxicity at the longest exposure times (day 28) and Zn shows a strong inhibitory effect in the short‐term (day 1), even though later toxicity diminish significantly. Cr is the least toxic studied PTM. Organic amendment outweighs any adverse effects of these metals, increasing soil respiration, even in the treatments with high doses of metals.     

Organic matter accumulation during the Holocene in the Guadalquivir marshlands (SW Spain)

The distribution of biomarker compounds and magnetic susceptibility observed in the sediment from a 20 m core drilled in the marshlands of the estuarine region of the Guadalquivir River (southwest coast of Spain) has allowed us to reconstruct the palaeoenvironmental evolution of this area during the Holocene. Several organic compounds (n‐alkanes, n‐ketones, n‐alkanols, n‐alkanoic acids and organic sulphur), as well as different biomarker ratios, have been used to show changing environmental conditions through time. These geochemical proxies suggest good preservation of the organic matter, although some diagenesis has occurred to particular organic compounds, especially the n‐alkanoic acids. Our data indicate a major allochthonous supply of terrestrial plants, with less influence from aquatic plants or algae through the core. There are markedly different palaeoenvironmental conditions between the uppermost 5 m (last 6 ka cal. B.P.) and the rest of the core. From 5 m (ca 6 ka cal. B.P.) to 19 m (ca 8 ka cal. B.P.) depth the palaeoenvironmental conditions were almost constant. Based on organic sulphur content and n‐alkane content logs, anoxic conditions prevailed from 8 to 6 ka cal. B.P., while oxic conditions with enhanced convection of water (prevalence of fluvial input), and consequently a greater organic matter supply, predominated in the upper 5 m of the core. Similarly, little variation in the magnetic susceptibility profile below 5 m indicates stable environmental conditions, while in the upper 5 m conditions shifted to one with elevated water input and clastic sediment supply. This is linked to palaeofloral alterations in the Guadiamar/Guadalquivir drainage basins and/or anthropogenic effects. We propose that from ca 8 to 6 ka cal. B.P. a stable landscape physiognomy in the surroundings of the estuarine area of the Guadalquivir River, with a predominance of pines and grassland. However, over the last 6 ka cal. B.P. a variation in the terrestrial plant biomarker compounds suggests an alternation of relatively dry and humid phases and/or the impact of human populations on altering the vegetation community have occurred. Copyright © 2007 John Wiley & Sons, Ltd.     

Variogram-Based Descriptors for Comparison and Classification of Rock Texture Images

Mathematical Geosciences - Rock characterization is typically performed by geologists in mining companies and involves the analysis of several meters of drill-hole samples to describe distinctive...