On the composition of ices incorporated in Ceres

We use the clathrate hydrate trapping theory and gas drag formalism to calculate the composition of ices incorporated in the interior of Ceres. Utilizing a time-dependent solar nebula model, we show that icy solids can drift from beyond 5 au to the present location of the asteroid and be preserved from vaporization. We argue that volatiles were trapped in the outer solar nebula in the form of clathrate hydrates, hydrates and pure condensates prior to having been incorporated in icy solids and subsequently in Ceres. Under the assumption that most of volatiles were not vaporized during the accretion phase and the thermal evolution of Ceres, we determine the per mass abundances with respect to H₂O of CO₂, CO, CH₄, N₂, NH₃, Ar, Xe and Kr in the interior of the asteroid. The Dawn space mission, scheduled to explore Ceres in August 2014, may have the capacity to test some predictions. We also show that an in situ measurement of the D/H ratio in H₂O in Ceres could constrain the distance range in the solar nebula where its icy planetesimals were produced.     

Hydromechanical behaviour of a compacted swelling soil over a wide suction range

A study of the hydromechanical behaviour of a compacted swelling material in the range of suctions comprised between 0 and 40 MPa was performed. This study has required the development of two kinds of suction controlled oedometer devices based on two different suction control techniques. In the range of suctions higher than 8.5 MPa, the saturated salt solutions method was used and a new oedometer using this suction control technique was developed. For suctions lower than 8.5 MPa an osmotic oedometer was used. Despite the differences between the applied suction components (matric and total), the correlation between the two methods was verified for the tested material. The second part of the paper presents a set of oedometer tests conducted under various suctions. The effect of the applied suction on the hydromechanical parameters was studied. First, two swelling phases were highlighted: a low swelling phase above a suction of 4 MPa and a high swelling one below this value. These phases were considered as being related to the microstructure of compacted swelling clays. Secondly, it was shown that the slopes of the elastic part and of the plastic part of the consolidation curves were not influenced significantly by the applied suctions. In opposition, the preconsolidation pressure is affected by the decrease of the applied suctions even in the low swelling phase. Such a behaviour could be explained by the effects of wetting on the microstructure.     

Geophysical excitation of the Earth orientation parameters EOP and its contribution to GGOS

We discuss how the geophysical fluids affect the Earth orientation parameters (EOP) and in particular polar motion and nutation. We show that the Earth orientation modeling is a perfect example of the integrated approach recommended by GGOS. GGOS considers the Earth system as a whole, including the solid Earth as well as the fluid components; geodesy observes and models the dynamics inside this system through the static and time-varying gravity field, the station displacements, and the Earth orientation parameters and the associated length-of-day variation, nutation and polar motion. Global-scale transfer in the Earth system and its geodetic consequences is proposed to be the central theme of GGOS. We show that the Earth orientation parameters perfectly fit this theme.     

Morphology and sedimentology of a complex debris flow in a clay‐shale basin

Coupling morphological, sedimentological, and rheological studies to numerical simulations is of primary interest in defining debris‐flow hazard on alluvial fans. In particular, numerical runout models must be carefully calibrated by morphological observations. This is particularly true in clay‐shale basins where hillslopes can provide a large quantity of poorly sorted solid materials to the torrent, and thus change both the mechanics of the debris flow and its runout distance. In this context, a study has been completed on the Faucon stream (southeastern French Alps), with the objectives of (1) defining morphological and sedimentological characteristics of torrential watersheds located in clay‐shales, and (2) evaluating through a case study the scouring potential of debris flows affecting a clay‐shale basin. Morphological surveys, grain‐size distributions and petrographic analyses of the debris‐flow deposits demonstrate the granular character of the flow during the first hectometre, and its muddy character from there to its terminus on the debris fan. These observations and laboratory tests suggest that the contributing areas along the channel have supplied the bulk of the flow material. Copyright © 2005 John Wiley & Sons, Ltd.     

Molybdenite Re–Os dating constrains gravitational collapse of the Sveconorwegian orogen, SW Scandinavia

Re–Os dating of molybdenite from small deposits is used to define crustal domains exhibiting ductile versus brittle behaviour during gravitational collapse of the Sveconorwegian orogen in SW Scandinavia. A 1019 ± 3 Ma planar quartz vein defines a minimum age for brittle behaviour in central Telemark. In Rogaland–Vest Agder, molybdenite associated with deformed quartz and pegmatite veins formed between 982 ± 3 and 947 ± 3 Ma in the amphibolite-facies domain (three deposits) and between 953 ± 3 and 931 ± 3 Ma west of the clinopyroxene-in isograd (two deposits) in the vicinity of the 0.93–0.92 Ga Rogaland anorthosite complex. The data constrain the last increment of ductile deformation to be younger than 0.95 and 0.93 Ga in these two metamorphic zones, respectively. Molybdenite is the product of an equilibrium between biotite, oxide and sulfide minerals and a fluid or hydrated melt phase, after the peak of 1.03–0.97 Ga regional metamorphism. Molybdenite precipitation is locally episodic. A model for gravitational collapse of the Sveconorwegian orogen controlled by lithospheric extension after 0.97 Ga is proposed. In the west of the orogen, the Rogaland–Vest Agder sector is interpreted as a large shallow gneiss dome, formed slowly in two stages in a warm and structurally weak crust. The first stage at 0.96–0.93 Ga was associated with intrusion of the post-collisional hornblende–biotite granite suite. The second stage at 0.93–0.92 Ga, restricted to the southwesternmost area, was associated with intrusion of the anorthosite–mangerite–charnockite suite. Most of the central part of the orogen was already situated in the brittle upper crust well before 0.97 Ga, and did not undergo significant exhumation during collapse. In the east of the orogen, situated against the colder cratonic foreland, exhumation of high-grade rocks of the Eastern Segment occurred between 0.97 and 0.95 Ga, and included preservation of high-pressure rocks but no plutonism.     

Germanium isotopic variations in igneous rocks and marine sediments

A new technique for the precise and accurate determination of Ge stable isotope compositions has been developed and applied to silicate rocks and biogenic opal. The analyses were performed using a continuous flow hydride generation system coupled to a MC-ICPMS. Samples have been purified through anion- and cation-exchange resins to separate Ge from matrix elements and eliminate potential isobaric interferences. Variations of ⁷⁴Ge/⁷⁰Ge ratios are expressed as δ⁷⁴Ge values relative to our internal standard and the long-term external reproducibility of the data is better than 0.2‰ for sample size as low as 15 ng of Ge. Data are presented for igneous and sedimentary rocks, and the overall variation is 2.4‰ in δ⁷⁴Ge, representing 12 times the uncertainty of the measurements and demonstrating that the terrestrial isotopic composition of Ge is not unique. Co-variations of ⁷⁴Ge/⁷⁰Ge, ⁷³Ge/⁷⁰Ge and ⁷²Ge/⁷⁰Ge ratios follow a mass-dependent behaviour and imply natural isotopic fractionation of Ge by physicochemical processes. The range of δ⁷⁴Ge in igneous rocks is only 0.25‰ without systematic differences among continental crust, oceanic crust or mantle material. On this basis, a Bulk Silicate Earth reservoir with a δ⁷⁴Ge of 1.3 ± 0.2‰ can be defined. In contrast, modern biogenic opal such as marine sponges and authigenic glauconite displayed higher δ⁷⁴Ge values between 2.0‰ and 3.0‰. This suggests that biogenic opal may be significantly enriched in light isotopes with respect to seawater and places a lower bound on the δ⁷⁴Ge of the seawater to +3.0‰.This suggests that seawater is isotopically heavy relative to Bulk Silicate Earth and that biogenic opal may be significantly fractionated with respect to seawater. Deep-sea sediments are within the range of the Bulk Silicate Earth while Mesozoic deep-sea cherts (opal and quartz) have δ⁷⁴Ge values ranging from 0.7‰ to 2.0‰. The variable values of the cherts cannot be explained by binary mixing between a biogenic component and a detrital component and are suggestive of enrichment in the light isotope of diagenetic quartz. Further work is now required to determine Ge isotope fractionation by siliceous organisms and to investigate the effect of diagenetic processes during chert lithification.     

Unusual variations of dissolved As, Sb and Ni in the Rhône River during flood events

Dissolved major and trace element concentrations were determined from November 2000 to December 2003 in the lower Rhône River (France). Subsurface water samples were collected about twice a month and more regularly during flood events. An unusual trend was observed for As, Sb, Ni and Ba concentrations which increased with river discharge at the beginning of the floods, in contrast with other elements. Variations of Sb/Na and As/Na molar ratios show that it is related to higher contributions of waters from western tributaries of the Rhône River enriched in As, Sb, Ni and Ba due to ancient mining activities. These unusual variations of dissolved element concentrations are thus interpreted as mark of a water mass origin within the watershed.     

Origine des eaux des émergences karstiques chlorurées du Languedoc-Roussillon

The origin of chloride-rich karstic spring waters representative of the Languedoc-Roussillon region has been investigated with a hydrochemical approach. To this end, the major and trace elements most often used in the study of saline environments have been considered (Cl, SO₄, Br, B, Li). This study allowed distinguishing the different end-members of the various chloride-rich karstic spring waters (evaporitic, marine, geothermal). Associated with the Cl, Br and B contents, the Li/SO₄ ratio appeared as a relevant tracer for the determination of the origin of lithium and by extension of the considered waters. To cite this article: O. Hébrard et al., C. R. Geoscience 338 (2006).     

Is the instrumental drift of superconducting gravimeters a linear or exponential function of time?

The instrumental drift of the superconducting gravimeter in Membach, Belgium, is estimated using 9 years of co-located and episodic absolute gravity measurements. We show that the best model of the long-term drift of the SG-C021 is an exponential. The thermal levelers used to compensate tilts are unlikely to induce the observed drift. Rather, the capacitance bridge, magnetic variations, gas adsorption on the levitating sphere, or helium gas pressure variations around it are most likely the possible combined causes of the observed instrumental drift. In practice, either linear or exponential drift models are equivalent as long as the record duration does not exceed 10 years. For longer records, this study demonstrates that an exponential models the drift better than a simple linear trend.