Textures in deforming forsterite aggregates up to 8 GPa and 1673 K

We report results from axisymmetric deformation experiments carried out on forsterite aggregates in the deformation-DIA apparatus, at upper mantle pressures and temperatures (3.1–8.1 GPa, 1373–1673 K). We quantified the resulting lattice preferred orientations (LPO) and compare experimental observations with results from micromechanical modeling (viscoplastic second-order self-consistent model—SO). Up to 6 GPa (~185-km depth in the Earth), we observe a marked LPO consistent with a dominant slip in the (010) plane with one observation of a dominant [100] direction, suggesting that [100](010) slip system was strongly activated. At higher pressures (deeper depth), the LPO becomes less marked and more complex with no evidence of a dominant slip system, which we attribute to the activation of several concurrent slip systems. These results are consistent with the pressure-induced transition in the dominant slip system previously reported for olivine and forsterite. They are also consistent with the decrease in the seismic anisotropy amplitude observed in the Earth’s mantle at depth greater than ~200 km.     

Slow-ridge/hotspot interactions from global gravity, seismic tomography and 87Sr/86Sr isotope data

Among the mantle hotspots present under oceanic areas, a large number are located on—or close to—active oceanic ridges. This is especially true in the slow-spreading Atlantic and Indian oceans. The recent availability of worldwide gravity grids and the increasing coverage of geochemical data sets along active spreading centres allow a fruitful comparison of these data with global geoid and seismic tomography models, and allow one to study interactions between mantle plumes and active slow-spreading ridges. The observed correlations allow us to draw preliminary conclusions on the general links between surficial processes, which shape the detailed morphology of the ridge axes, and deeper processes, active in the upper mantle below the ridge axial domains as a whole. The interactions are first studied at the scale of the Atlantic (the Mid-Atlantic Ridge from Iceland to Bouvet Island) from the correlation between the zero-age free-air gravity anomaly, which reflects the zero-age depth of the ridge axis, and Sr isotopic ratios of ridge axis basalts. The study is then extended to a more global scale (the slow ridges from Iceland to the Gulf of Aden) by including geoid and upper-mantle tomography models. The interactions appear complex, ranging from the effect of large and very productive plumes, almost totally overprinting the long-wavelength segmentation pattern of the ridge, to that of weaker hotspots, barely marking some of the observables in the ridge axial domain. Intermediate cases are observed, in which hotspots of medium activity (or whose activity has gradually decreased) located at some distance from the ridge axis produce geophysical or geochemical signals whose variation along the axis can be correlated with the geometry of the plume head in the upper mantle. Such observations tend to preclude the use of a single hotspot/ridge interaction model and stress the need for additional observations in various plume/ridge configurations.     

LA‐ICP‐MS dating of detrital zircon grains from the Cretaceous allochthonous bauxites of Languedoc (south of France): Provenance and geodynamic consequences

The Cretaceous of southern France is characterised by a long erosional hiatus, outlined with bauxite deposits, which represent the only remaining sedimentary record of a key period for geodynamic reconstructions. Detrital zircons from allochthonous karst bauxites of Languedoc (Southern France) have been dated using LA‐ICP‐MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry), in order to specify the age of deposition and to constrain the provenance of the weathered material. We analysed 671 single detrital zircons grains from three karst bauxitic basins, stretching from close to the Variscan Montagne Noire to the present‐day Mediterranean Sea. Analytical results provide Variscan (300–350 Ma) and Late Proterozoic (550–700 Ma) ages as primary groups. In addition, Middle‐, Late Proterozoic and Early Archean (oldest grain at 3.55 Ga) represent significant groups. Mid‐Cretaceous zircons (118–113 Ma) provide a pooled age of 115.5 ± 3.8 Ma, which constitutes the maximum age for bauxite deposition. Results also suggest a dual source for the Languedoc bauxite: one generalised sedimentary source of regional extent and a localised source in the Variscan basement structural high, that has been progressively unroofed during Albian. Integration of these new findings with previously published thermochronological data support the presence of an Early Cretaceous marly cover on the Variscan basement, which has been weathered and then, removed during the Albian. The Languedoc bauxite provide a spatial and temporal link between the uplift of southern French Massif Central to the north, and the Pyrenean rift and its eastward extension to the south. These new results allow to constrain the timing and distribution of uplift/subsidence during the mid‐Cretaceous events in relation with the motion of the Iberian plate relative to Eurasia.     

Modelling metolachlor exports in subsurface drainage water from two structured soils under maize (eastern France)

The study investigated the processes involved in metolachlor transport in two artificially drained, structured soils in eastern France. Measured losses of bromide and metolachlor in drainage water were compared with results simulated by the mechanistic, stochastic AgriFlux model. Simulated drainage water volumes were generally similar to the measured volumes when the spatial variability of the soil water properties was taken into account. When such variability was disregarded, cumulative water volumes of the clay soil were over- or underestimated by more than 20%. Two types of adsorption were tested. For instantaneous, reversible adsorption, using the partition coefficient Koc, metolachlor losses were underestimated in the first drainage water volumes and overestimated for the total study period. The use of slow adsorption and desorption kinetics (ADK) produced an export pattern similar to the observed one. A sensitivity analysis indicated that the simulated results are very sensitive to the values of the ADK rates, especially for the silty loam soil. The effect of ADK on the attenuation of metolachlor exports was more significant than the effect of degradation (2.3 and 6.7 times higher for the clay and silty loam soils, respectively). For the same four-month period, the bromide and metolachlor losses (using ADK) in the clay soil were 2.1 and 1.3 times greater, respectively, if the macroporosity was set at 10% than if it was not simulated. Conversely, macroporosity did not significantly affect these losses in the silty loam. The main factors involved in the metolachlor transport in the studied soils were: (i) the macroporosity, especially in the clay soil because of the low hydraulic conductivity of the matrix and (ii) the sorption kinetics rates which varied according to the soil physico-chemical characteristics.     

The Cenozoic evolution of the Roer Valley Rift System integrated at a European scale

The Roer Valley Rift System (RVRS) is located between the West European rift and the North Sea rift system. During the Cenozoic, the RVRS was characterized by several periods of subsidence and inversion, which are linked to the evolution of the adjacent rift systems. Combination of subsidence analysis and results from the analysis of thickness distributions and fault systems allows the determination of the Cenozoic evolution and quantification of the subsidence. During the Early Paleocene, the RVRS was inverted (Laramide phase). The backstripping method shows that the RVRS was subsequently mainly affected by two periods of subsidence, during the Late Paleocene and the Oligocene–Quaternary time intervals, separated by an inversion phase during the Late Eocene. During the Oligocene and Miocene periods, the thickness of the sediments and the distribution of the active faults reveal a radical rotation of the direction of extension by about 70–80° (counter clockwise). Integration of these results at a European scale indicates that the Late Paleocene subsidence was related to the evolution of the North Sea basins, whereas the Oligocene–Quaternary subsidence is connected to the West European rift evolution. The distribution of the inverted provinces also shows that the Early Paleocene inversion (Laramide phase) has affected the whole European crust, whereas the Late Eocene inversion was restricted to the southern North Sea basins and the Channel area. Finally, comparison of these deformations in the European crust with the evolution of the Alpine chain suggests that the formation of the Alps has controlled the evolution of the European crust since the beginning of the Cenozoic.     

Study on the cross-correlation of GNSS signals and typical approximations

In global navigation satellite system (GNSS) receivers, the first signal processing stage is the acquisition, which consists of detecting the received GNSS signals and determining the associated code delay and Doppler frequency by means of correlations with a code and carrier replicas. These codes, as part of the GNSS signal, were chosen to have very good correlation properties without considering the effect of a potential received Doppler frequency. In the literature, it is often admitted that the maximum GPS L1 C/A code cross-correlation is about ?24 dB. We show that this maximum can be as high as ?19.2 dB when considering a Doppler frequency in a typical range of [?5, 5] kHz. We also show the positive impact of the coherent integration time on the cross-correlation and that even a satellite with Doppler outside the frequency search space of a receiver impacts the cross-correlation. In addition, the expression of the correlation is often provided in the continuous time domain, while its implementation is typically made in the discrete domain. It is then legitimate to ask the validity of this approximation. Therefore, the purpose of this research is twofold: First, we discuss typical approximations and evaluate their regions of validity, and second, we provide characteristic values such as maximums and quantiles of the auto- and cross-correlation of the GPS L1 C/A and Galileo E1 OS codes in the presence of Doppler, for frequency ranges up to 50 kHz and for different integration times.     

The high temperature reaction zone of the Oman ophiolite: new field data,microthermometry of fluid inclusions,PIXE analyses and oxygen isotopic ratios

Marine Geophysical Research - The present study is focused on the so-called High Temprature Reaction Zone of the Oman ophiolite, a thin zone located between the roots of the sheeted dyke complex...