IRNSS-1A: signal and clock characterization of the Indian regional navigation system

An initial characterization of the L5 and S-Band navigation signals transmitted by the first satellite of the Indian regional navigation satellite system (IRNSS) is presented. In the absence of a public signal specification, a 30 m high-gain antenna has been used to record the signal spectrum and the modulated chip sequences. For the IRNSS standard positioning service, use of a Gold ranging code is confirmed and relevant shift register parameters for the two frequencies are identified. Based on a prototype receiver, L5 single-frequency code and phase observations of IRNSS-1A have also been collected. The tracking performance is described, and the measurements are used to characterize the short-term clock stability of IRNSS-1A.     

The effect of climate change on glacier ablation and baseflow support in the Nooksack River basin and implications on Pacific salmonid species protection and recovery

The Nooksack Indian Tribe (Tribe) inhabits the area around Deming, Washington, in the northwest corner of the state. The Tribe is dependent on various species of Pacific salmonids that inhabit the Nooksack River for ceremonial, commercial, and subsistence purposes. Of particular importance to the Tribe are spring Chinook salmon. Since European arrival, the numbers of fish that return to spawn have greatly diminished because of substantial loss of habitat primarily due to human-caused alteration of the watershed. Although direct counts are not available, it is estimated that native salmonid runs are less than 8 % of the runs in the late 1800’s. In addition, climate change has caused and will continue to cause an increase in winter flows, earlier snowmelt, decrease in summer baseflows, and an increase in water temperatures that exceed the tolerance levels, and in some cases lethal levels, of several Pacific salmonid species. The headwaters of the Nooksack River originate from glaciers on Mount Baker that have experienced significant changes over the last century due to climate change. Melt from the glaciers is a major source of runoff during the low-flow critical summer season, and climate change will have a direct effect on the magnitude and timing of stream flow in the Nooksack River. Understanding these changes is necessary to protect the Pacific salmonid species from the harmful effects of climate change. All nine salmonid species that inhabit the Nooksack River will be adversely affected by reduced summer flows and increased temperatures. The most important task ahead is the planning for, and implementation of, habitat restoration prior to climate change becoming more threatening to the survival of these important fish species. The Tribe has been collaboratively working with government agencies and scientists on the effects of climate change on the hydrology of the Nooksack River. The extinction of salmonids from the Nooksack River is unacceptable to the Tribe since it is dependent on these species and the Tribe is place-based and cannot relocate to areas where salmon will survive.     

Assessment of the climate preparedness of 30 urban areas in the UK

Cities are increasingly aware of the need to mitigate greenhouse gas emissions and adapt to changes in weather patterns leading to the production of urban climate change plans. The few existing systematic studies of these plans have focused on either adaptation or mitigation issues, and are typically based on surveys completed by city officials rather than analysis of documented evidence. To gain insight into the status of adaptation and mitigation action across the UK, climate change documents from 30 urban areas (representing ~28 % of the UK’s population) were analysed. An Urban Climate Change Preparedness Score, which could be applied to other urban areas outside the UK, has been devised for comparative analysis. This analysis characterizes progress against (i) Assessment, (ii) Planning, (iii) Action, and (iv) Monitoring, for both adaptation and mitigation. The Preparedness Score allows a quantitative comparison of climate change strategies across the urban areas analysed. This methodology can be transferred to other countries and makes an international comparison of urban areas and their climate change adaptation and mitigation plans possible. We found that all areas acknowledge climate change being a threat and that adaptation and mitigation planning and action is required. However, two urban areas did not have official adaptation or mitigation plans. Typically, mitigation activities across all cities were more advanced than adaptation plans. Emissions reduction targets ranged from 10 %–80 % with differing baselines, timeframes and scopes, for defining and meeting these targets. Similar variability was observed across adaptation plans. Several reasons for these differences are considered, but particularly notable is that a combination of incentives and regulation seem to stimulate more comprehensive strategies and action in many urban areas.     

Temperature and precipitation responses to El Niño-Southern Oscillation in a hierarchy of datasets with different levels of observational constraints

Climate Dynamics - El Niño-Southern Oscillation (ENSO) is the dominant mode of climate variability, affecting climate conditions over large areas of the globe. There are, however, substantial...     

Distribution of organochlorines in the dissolved and suspended phase of the sea-surface microlayer and seawater in Hong Kong, China

Polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) were measured in the dissolved and suspended particulate phase in the sea-surface microlayer (SML) and subsurface water (SSW) collected from Hong Kong's coastal environment. The concentration ranges (pg/L) for summation sigmaHCHs, summation sigmaDDTs and summation sigmaPCBs in the SSW dissolved phase (DP i.e. sum of truly dissolved and colloidal phase) were 409-940 (mean 602), 774-5583 (mean 1908) and 266-433 (mean 278), respectively. The concentration ranges (pg/L) for summation sigmaHCHs, summation sigmaDDTs and summation sigmaPCBs in SSW suspended particulate matter (SPM) were <5-85 (mean 59), 358-1369 (mean 787) and 85.6-273 (mean 172), respectively. The enrichment factor of PCBs and OCPs in the SML varied between 1.1 and 4.5 for the DP, and 0.4-8.2 for the SPM. The distribution of contaminants between DP and SPM in both the SML and SSW indicates that particulate matter plays an important role in the distribution and fate of DDTs and PCBs, but not for HCH isomers. The Pearl River Estuary is likely to be a major source of contaminants transported to Hong Kong.     

Scale dependency of regional climate modeling of current and future climate extremes in Germany

A 26-year simulation (1980–2005) was performed with the Weather Research and Forecast (WRF) model over the Volta Basin in West Africa. This was to investigate the ability of a climate version of WRF to reproduce present day temperature and precipitation over the Volta Basin. The ERA-Interim reanalysis and one realization of the ECHAM6 global circulation model (GCM) data were dynamically downscaled using two nested domains within the WRF model. The outer domain had a horizontal resolution of 50 km and covered the whole of West Africa while the inner domain had a horizontal resolution of 10 km. It was observed that biases in the respective forcing data were carried over to the RCM, but also the RCM itself contributed to the mean bias of the model. Also, the biases in the 50-km domain were transferred unchanged, especially in the case of temperature, to the 10-km domain, but, for precipitation, the higher-resolution simulations increased the mean bias in some cases. While in general, WRF underestimated temperature in both the outer (mean biases of ?1.6 and ?2.3 K for ERA-Interim and ECHAM6, respectively) and the inner (mean biases of ?0.9 K for the reanalysis and ?1.8 K for the GCM) domains, WRF slightly underestimated precipitation in the coarser domain but overestimated precipitation in the finer domain over the Volta Basin. The performance of the GCM, in general, is good, particularly for temperature with mean bias of ?0.7 K over the outer domain. However, for precipitation, the added value of the RCM cannot be overlooked, especially over the whole West African region on the annual time scale (mean biases of ?3% for WRF and ?8% for ECHAM6). Over the whole Volta Basin and the Soudano-Sahel for the month of April and spring (MAM) rainfall, respectively, mean bias close to 0% was simulated. Biases in the interannual variability in both temperature and precipitation over the basin were smaller in the WRF than the ECHAM6. High spatial pattern correlations between 0.7 and 0.8 were achieved for the autumn precipitation and low spatial correlation in the range of 0.0 and 0.2 for the winter season precipitation over the whole basin and all the three belts over the basin.     

Mechanisms of fine extinction band development in vein quartz: new insights from correlative light and electron microscopy

Fine extinction bands (FEBs) (also known as deformation lamellae) visible with polarized light microscopy in quartz consist of a range of nanostructures, inferring different formation processes. Previous transmission electron microscopy studies have shown that most FEB nanostructures in naturally deformed quartz are elongated subgrains formed by recovery of dislocation slip bands. Here we show that three types of FEB nanostructure occur in naturally deformed vein quartz from the low-grade metamorphic High-Ardenne slate belt (Belgium). Prismatic oriented FEBs are defined by bands of dislocation walls. Dauphiné twin boundaries present along the FEB boundaries probably formed after FEB formation. In an example of two sub-rhombohedral oriented FEBs, developed as two sets in one grain, the finer FEB set consists of elongated subgrains, similar to FEBs described in previous transmission electron microscopy studies. The second wider FEB set consists of bands with different dislocation density and fluid-inclusion content. The wider FEB set is interpreted as bands with different plastic strain associated with the primary growth banding of the vein quartz grain. The nanometre-scale fluid inclusions are interpreted to have formed from structurally bounded hydroxyl groups that moreover facilitated formation of the elongate subgrains. Larger fluid inclusions aligned along FEBs are explained by fluid-inclusion redistribution along dislocation cores. The prismatic FEB nanostructure and the relation between FEBs and growth bands have not been recognized before, although related structures have been reported in experimentally deformed quartz.     

Weathering, dust, and biocycling effects on soil silicon isotope ratios

Silicon isotope ratios (δ³⁰Si) of bulk mineral materials in soil integrate effects from both silicon sources and processing. Here we report δ³⁰Si values from a climate gradient of Hawaiian soils developed on 170 ka basalt and relate them to patterns of soil chemistry and mineralogy. The results demonstrate informative relationships between the mass fraction of soil Si depletion and δ³⁰Si. In upper (<1 m deep) soil horizons along the climate gradient, Si depletion correlates with decreases of residual δ³⁰Si values in low rainfall soils and increases in high rainfall soils. Strong positive correlation between soil δ³⁰Si and dust-derived quartz and mica content show that both trends are largely controlled by the abundance of these weathering-resistant minerals. The data also lend support to the idea that fractionation of Si isotopes in secondary phases is controlled by partitioning of silicon between dissolved and precipitated products during the initial weathering of primary basalt. Secondary mineral δ³⁰Si values from lower (>1 m deep) soil horizons generally correlate with the isotope fractionation predicted by a study of dissolved Si in basalt-watershed rivers and driven by preferential ²⁸Si removal from the dissolved phase during precipitation. In contrast, after correcting for the influence of dust, secondary mineral Si depletion and δ³⁰Si values in shallow (<1 m deep) soil horizons showed evidence of biocycling induced Si redistribution and substantially lower δ³⁰Si values than predicted. Low δ³⁰Si values in shallow soil horizons compared to predictions can be attributed to repeated fractionation as secondary minerals undergo additional cycles of dissolution and precipitation. Primary mineral weathering, secondary mineral weathering, dust accumulation, and biocycling are major processes in terrestrial Si cycling and these results demonstrate that each can be traced by δ³⁰Si values interpreted in conjunction with mineralogy and measures of Si depletion.     

Degradation of chlorinated ethylenes by Fe0: inhibition processes and mineral precipitation

. Granular zero-valent iron was used for the treatment of groundwater pollution caused by chlorinated ethylenes, mainly TCE, cis-DCE and VC at an industrial site. The rapidly decreasing rates of de-chlorination in the initial phase were attributed to the precipitation of carbonates and the development of hydrogen by anaerobic corrosion. After 70 pore volumes, sulphate was reduced by bacteria. From this point in time, the degradation of TCE was slightly accelerated whereas the de-chlorination rates of the other chlorinated ethylenes decreased only slowly. This relative improvement was assumed to be caused by the uptake of electron-transfer-blocking hydrogen by bacteria. Because the overall trend of the degradation rates is negative we conclude that the inhibitive effect of carbonate precipitation and hydrogen formation cannot be compensated for by the positive influence of the activity of sulphate-reducing bacteria.