A review of pollutants in the sea-surface microlayer (SML): a unique habitat for marine organisms

Boundary layers between different environmental compartments represent critical interfaces for biological, chemical and physical processes. The sea-surface microlayer (uppermost 1-1000 microm layer) forms the boundary layer interface between the atmosphere and ocean. Environmental processes are controlled by the SML, and it is known to play a key role in the global distribution of anthropogenic pollutants. Due to its unique chemical composition, the upper organic film of the SML represents both a sink and a source for a range of pollutants including chlorinated hydrocarbons, organotin compounds, petroleum hydrocarbons, polycyclic aromatic hydrocarbons (PAH) and heavy metals. These pollutants can be enriched in the SML by up to 500 times relative to concentrations occurring in the underlying bulk water column. The SML is also a unique ecosystem, serving as an important habitat for fish eggs and larvae. Concentration ranges and enrichment factors of pollutants in the SML in different areas of the world's oceans have been critically reviewed, together with available toxicity data for marine biota found within the SML. Overall, the SML is highly contaminated in many urban and industrialized areas of the world, resulting in severe ecotoxicological impacts. Such impacts may lead to drastic effects on the marine food web and to fishery recruitment in coastal waters. Studies of the toxicity of fish eggs and larvae exposed to the SML contaminants have shown that the SML in polluted areas leads to significantly higher rates of mortality and abnormality of fish embryos and larvae.     

Characterization of Compass M-1 signals

An analysis of observations from China’s first medium earth orbit satellite Compass M-1 is presented, with main focus on the first orbit and clock solution for this satellite. The orbit is computed from laser ranging measurements. Based on this orbit solution, the apparent clock offset is estimated using measurements from two GNSS receivers, which allow Compass tracking. The analysis of the clock solutions reveals unexpectedly high dynamics in the pseudorange and carrier-phase observations. Furthermore, carrier-to-noise density ratio, pseudorange noise, and multipath are analyzed and compared to GPS and GIOVE. The results of the clock analysis motivate further research on the signals of the geostationary satellites of the Compass constellation.     

Properties of dusty tori in active galactic nuclei – I. The case of SWIRE/SDSS quasars

We derive the properties of dusty tori in active galactic nuclei from the comparison of observed spectral energy distributions (SEDs) of SDSS quasars and a precomputed grid of torus models. The observed SEDs comprise SDSS photometry, Two-Micron All-Sky Survey J , H and K data, whenever available, and mid-infrared (mid-IR) data from the Spitzer Wide-area InfraRed Extragalactic Survey. The adopted model is that of Fritz, Franceschini & Hatziminaoglou. The fit is performed by standard  χ²  -minimization; the model, however, can be a multicomponent comprising a stellar and a starburst component, whenever necessary. Models with low equatorial optical depth, τ_9.7, were allowed as well as 'traditional' models with  τ_9.7≥ 1.0  , corresponding to   A _V≥ 22  and the results were compared. Fits using high optical depth tori models only produced dust more compactly distributed than in the configuration where all τ_9.7 models were permitted. Tori with decreasing dust density with the distance from the centre were favoured while there was no clear preference for models with or without angular variation of the dust density. The computed outer radii of the tori are of some tens of parsecs large but can reach, in a few cases, a few hundreds of parsecs. The mass of dust, M _Dust, and IR luminosity, L _IR, integrated in the wavelength range between 1 and 1000 μm, do not show significant variations with redshift, once the observational biases are taken into account. Objects with 70-μm detections, representing 25 per cent of the sample, are studied separately and the starburst contribution (whenever present) to the IR luminosity can reach, in the most extreme but very few cases, 80 per cent.     

Mega-monsoon variability during the late Triassic: Re-assessing the role of orbital forcing in the deposition of playa sediments in the Germanic Basin

The formation of the supercontinent Pangaea during the Permo–Triassic gave rise to an extreme monsoonal climate (often termed ‘mega-monsoon’) that has been documented by numerous palaeo-records. However, considerable debate exists about the role of orbital forcing in causing humid intervals in an otherwise arid climate. To shed new light on the forcing of monsoonal variability in subtropical Pangaea, this study focuses on sediment facies and colour variability of playa and alluvial fan deposits in an outcrop from the late Carnian (ca 225 Ma) in the southern Germanic Basin, south-western Germany. The sediments were deposited against a background of increasingly arid conditions following the humid Carnian Pluvial Event (ca 234 to 232 Ma). The ca 2·4 Myr long sedimentary succession studied shows a tripartite long-term evolution, starting with a distal mud-flat facies deposited under arid conditions. This phase was followed by a highly variable playa-lake environment that documents more humid conditions and finally a regression of the playa-lake due to a return of arid conditions. The red–green (a*) and lightness (L*) records show that this long-term variability was overprinted by alternating wet/dry cycles driven by orbital precession and ca 405 kyr eccentricity, without significant influence of obliquity. The absence of obliquity in this record indicates that high-latitude forcing played only a minor role in the southern Germanic Basin during the late Carnian. This is different from the subsequent Norian when high-latitude signals became more pronounced, potentially related to the northward drift of the Germanic Basin. The recurring pattern of pluvial events during the late Triassic demonstrates that orbital forcing, in particular eccentricity, stimulated the occurrence and intensity of wet phases. It also highlights the possibility that the Carnian Pluvial Event, although most likely triggered by enhanced volcanic activity, may also have been modified by an orbital stimulus.     

Forward induced seismic hazard assessment: application to a synthetic seismicity catalogue from hydraulic stimulation modelling

The M _w 3.2-induced seismic event in 2006 due to fluid injection at the Basel geothermal site in Switzerland was the starting point for an ongoing discussion in Europe on the potential risk of hydraulic stimulation in general. In particular, further development of mitigation strategies of induced seismic events of economic concern became a hot topic in geosciences and geoengineering. Here, we present a workflow to assess the hazard of induced seismicity in terms of occurrence rate of induced seismic events. The workflow is called Forward Induced Seismic Hazard Assessment (FISHA) as it combines the results of forward hydromechanical-numerical models with methods of time-dependent probabilistic seismic hazard assessment. To exemplify FISHA, we use simulations of four different fluid injection types with various injection parameters, i.e. injection rate, duration and style of injection. The hydromechanical-numerical model applied in this study represents a geothermal reservoir with preexisting fractures where a routine of viscous fluid flow in porous media is implemented from which flow and pressure driven failures of rock matrix and preexisting fractures are simulated, and corresponding seismic moment magnitudes are computed. The resulting synthetic catalogues of induced seismicity, including event location, occurrence time and magnitude, are used to calibrate the magnitude completeness M _c and the parameters a and b of the frequency-magnitude relation. These are used to estimate the time-dependent occurrence rate of induced seismic events for each fluid injection scenario. In contrast to other mitigation strategies that rely on real-time data or already obtained catalogues, we can perform various synthetic experiments with the same initial conditions. Thus, the advantage of FISHA is that it can quantify hazard from numerical experiments and recommend a priori a stimulation type that lowers the occurrence rate of induced seismic events. The FISHA workflow is rather general and not limited to the hydromechanical-numerical model used in this study and can therefore be applied to other fluid injection models.     

Benchmarking spatial joins a la carte

Spatial joins are join operations that involve spatial data types and operators. Spatial access methods are often used to speed up the computation of spatial joins. This paper addresses the issue of benchmarking spatial join operations. For this purpose, we first present a WWW-based benchmark generator to produce sets of rectangles. Using a Web browser, experimenters can specify the number of rectangles in a sample, as well as the statistical distributions of their sizes, shapes, and locations. Second, using the generator and a well-defined set of statistical models we define several tests to compare the performance of three spatial join algorithms: nested loop, scan-and-index, and synchronized tree traversal. We also added two real-life data sets from the Sequoia 2000 storage benchmark. Our results show that the relative performance of the different techniques mainly depends on the selectivity factor of the join predicate. All of the statistical models and algorithms are available on the Web, which allows for easy verification and modification of our experiments.     

Generalized LSG models with spatially varying Coriolis parameter

In this paper, we derive and study approximate balance models for nearly geostrophic shallow water flow where the Coriolis parameter is permitted to vary across the domain as long as it remains nondegenerate. This situation includes, for example, the β-plane approximation to the shallow water equations at mid-latitudes. Our approach is based on changing configuration space coordinates in the underlying variational principle in such a way that consistent asymptotics in the transformed Lagrangian leads to a degenerate Lagrangian structure. In this paper, we restrict our attention to first-order models. We show that the resulting models can be formulated in terms of an advected potential vorticity with a nonlinear vorticity inversion relation. We study the associated solvability conditions and identify a subfamily of models for which these conditions are satisfied without additional restrictions on the data. Finally, we provide the link between our framework and the theory of constrained Hamiltonian systems.     

Effective sea ice area based on a thickness threshold

As Arctic sea ice declines in response to climate change, a shift from thick multiyear ice to a thinner ice cover is occurring. With this transition, ice thicknesses approach a threshold below which ice no longer insulates the atmosphere from oceanic surface fluxes. While this is well known, there are no estimates of the magnitude of this threshold, nor of the proportion of sea ice area that is below this threshold as ice thins. We determine this threshold by simulating the atmospheric response to varying thicknesses, ranging from 0.0 to 2.0 m and determine that threshold to be 0.40–0.50 m. The resulting “effective” ice area is 4–14% lower than reported total ice area, as 0.39–0.97 × 10⁶ km² of the total ice area falls below the threshold throughout the twentieth century, including during notable ice minima. The atmosphere above large non-insulating ice-covered regions is susceptible to more than 2 °C of warming despite ice presence. Observed mean Arctic Ocean ice thickness is projected to fall below this threshold as early as the mid-2020s. Studies on ocean–atmosphere interactions in relation to sea ice area should focus on this insulating sea ice area, where ice is at least 0.40–0.50 m thick, and treat ice regions below 0.40–0.50 m thickness with caution.