The European Large Area ISO Survey – III. 90-μm extragalactic source counts

We present results and source counts at 90 μm extracted from the preliminary analysis of the European Large Area ISO Survey (ELAIS). The survey covered about 12 deg² of the sky in four main areas and was carried out with the ISOPHOT instrument onboard the Infrared Space Observatory ( ISO ). The survey is at least an order of magnitude deeper than the IRAS 100-μm survey and is expected to provide constraints on the formation and evolution of galaxies. The majority of the detected sources are associated with galaxies on optical images. In some cases the optical associations are interacting pairs or small groups of galaxies, suggesting that the sample may include a significant fraction of luminous infrared galaxies. The source counts extracted from a reliable subset of the detected sources are in agreement with strongly evolving models of the starburst galaxy population.     

Obstructed minibasins on a salt-detached slope: An example from above the Sigsbee canopy,northern Gulf of Mexico

Salt-detached gravity gliding/spreading systems having a rugose base-of-salt display complex strain patterns. However, little was previously known about how welding of supra-salt minibasins to the sub-salt may influence both the downslope translation of minibasins on salt-detached slopes and the regional pattern of supra-salt strain. Using a regional 3D seismic reflection data set, we examine a large salt-stock canopy system with a rugose base on the northern Gulf of Mexico slope, on which minibasins both subside and translate downslope. Some minibasins are welded at their bases and others are not. We suggest that basal welds obstruct downslope translation of minibasins and control regional patterns of supra-canopy strain. The distribution of strain above the canopy is complex and variable. Each minibasin that becomes obstructed modifies the local strain field, typically developing a zone of shortening immediately updip and an extensional breakaway zone immediately downdip of the obstructed minibasin. This finding is corroborated by observations from a physical sandbox model of minibasin obstruction. We also find in our natural example that minibasins can be obstructed to different degrees, ranging from severe (e.g., caught in a feeder) to mild (e.g., welded to a flat or gently dipping base-of-salt). By mapping both the presence of obstructed minibasins and the relative degree of minibasin obstruction, we provide an explanation for the origin of complex 3-D strain fields on a salt-detached slope and, potentially, a mechanism that explains differential downslope translation of minibasins. In minibasin-rich salt-detached slope settings, our results may aid: i) structural restorations and regional strain analyses; ii) prediction of subsalt relief in areas of poor seismic imaging; and iii) prediction of stress fields and borehole stability. Our example is detached on allochthonous salt and where the base-of-salt is rugose, with the findings applicable to other such systems worldwide (e.g., Gulf of Mexico; Scotian Margin, offshore eastern Canada). However, our findings are also applicable to systems where the salt is autochthonous but has significant local basal relief (e.g., Santos Basin, Brazil; Kwanza Basin, Angola).     

Late Glacial and Holocene temperature changes at Egelsee,Switzerland, reconstructed using subfossil chironomids

A temperature reconstruction using chironomids was attempted at Egelsee, Switzerland, a site where pollen and macrofossil records showed a correspondence between vegetation and climatic changes inferred by other proxies in Europe. The general pattern of temperature changes inferred from chironomids during the Late Glacial [i.e. cold temperatures between ca. 16,500 and 14,800 cal BP, close to present-day temperature between 15,000 and 13,000 cal BP and colder temperatures during the Younger Dryas (YD)], and the major temperature changes of the Holocene (i.e. the Younger Dryas–Holocene transition and the Late Holocene cooling trend) at Egelsee, were mirrored in other European climate reconstructions using various proxies. However, the amplitude of temperature changes during the YD was smaller than reconstructed by other proxies at various sites, and the 8,200 years BP event was not apparent. These differences between records were probably due to the dominance of Corynocera ambigua, with percentages reaching 60% in parts of the Egelsee sequence. This taxon was not present in any of the 103 lakes used for the transfer function and its absence may have yielded less accurate inferences. Its presence in samples only associated with cold inferences at Egelsee suggests that this taxon is a cold indicator. However, it was also found in warm Danish lakes and the factors that determine the presence of C. ambigua remain unexplained. Most samples had a poor fit to temperature and instead, dissolved organic carbon seemed to be a factor influencing the chironomid assemblages during the Holocene. These results illustrate the need to better understand the ecology of chironomids and to disentangle the various factors that affect chironomid communities through time. Ultimately, such information will lead to more accurate temperature reconstructions.     

Deep learning approaches for improving prediction of daily stream temperature in data-scarce,unmonitored, and dammed basins

Basin-centric long short-term memory (LSTM) network models have recently been shown to be an exceptionally powerful tool for stream temperature (T_s) temporal prediction (training in one period and predicting in another period at the same sites). However, spatial extrapolation is a well-known challenge to modelling T_s and it is uncertain how an LSTM-based daily T_s model will perform in unmonitored or dammed basins. Here we compiled a new benchmark dataset consisting of >400 basins across the contiguous United States in different data availability groups (DAG, meaning the daily sampling frequency) with and without major dams, and studied how to assemble suitable training datasets for predictions in basins with or without temperature monitoring. For prediction in unmonitored basins (PUB), LSTM produced a root-mean-square error (RMSE) of 1.129°C and an R² of 0.983. While these metrics declined from LSTM's temporal prediction performance, they far surpassed traditional models' PUB values, and were competitive with traditional models' temporal prediction on calibrated sites. Even for unmonitored basins with major reservoirs, we obtained a median RMSE of 1.202°C and an R² of 0.984. For temporal prediction, the most suitable training set was the matching DAG that the basin could be grouped into (for example, the 60% DAG was most suitable for a basin with 61% data availability). However, for PUB, a training dataset including all basins with data was consistently preferred. An input-selection ensemble moderately mitigated attribute overfitting. Our results indicate there are influential latent processes not sufficiently described by the inputs (e.g., geology, wetland covers), but temporal fluctuations can still be predicted well, and LSTM appears to be a highly accurate T_s modelling tool even for spatial extrapolation.     

Assessment of undiscovered nickel sulphide resources,Kalgoorlie Terrane,Western Australia: Part 1. Deposit and endowment density models

The use of mineral deposit density regression models to estimate the number of undiscovered deposits is gaining acceptance in mineral resources assessments. The deposit density regression models currently in use are based on well-established power law relationships between deposit density (deposits/km²) and the areal extent of the host rocks in well explored regions (control areas) worldwide. Although these generalized or global deposit density models can generate guideline estimates that are useful at the terrane scale, locally-derived terrane-based deposit density regression models may potentially yield more relevant estimates at the terrane scale. Using 12 selected komatiite-defined control areas in the Kalgoorlie Terrane, Western Australia, we found that the size (km²) of the control areas had power law relationships with (i) nickel sulphide deposit density, and (ii) nickel endowment density (nickel metal/km²). Regression analyses showed that both power law relationships are statistically significant at the 5% level. This suggests that nickel sulphide deposit and endowment density models could be used to estimate the number of undiscovered nickel sulphide deposits and amount of nickel metal endowment in less explored komatiites in the Kalgoorlie Terrane. This study shows that global geological relationships can be viably downscaled onto local geological terranes thereby supporting the hypothesis that the processes of mineral deposit formation and preservation are scale-independent and self-similar.     

Characterization of a french clay barrier and outline of the experimental programme

This paper presents the process of ANDRA for the characterization of backfilling materials for a deep radioactive waste disposal in crystalline rocks.

The experimental programme was developed in collaboration with the CEA/DRDD; the main objective was to build a comprehensive methodology of characterization, applied to the French Ca-smectite clay, ldFo-Card clay selected from several French deposits.

For this programme specific experimental facilities are needed adapted to this kind of material. The main results concerning thermal, hydraulic and radioelement transfer properties are presented for pure Fo-Ca clay, or used in mixtures with different components such as sand, graphite or talc.

Hydraulic properties of Fo-Ca and Na-bentonite MX-80 are compared and discussed.     

Lateglacial and early Holocene summer temperatures in the southern Swiss Alps reconstructed using fossil chironomids

We present a Lateglacial and early Holocene chironomid‐based July air temperature reconstruction from Foppe (1470 m a.s.l.) in the Swiss Southern Alps. Our analysis suggests that chironomid assemblages have responded to major and minor climatic fluctuations during the past 17 000 years, such as the Oldest Dryas, the Younger Dryas and the Bølling/Allerød events in the Lateglacial and the Preboreal Oscillation at the beginning of the Holocene. Quantitative July air temperature estimates were produced by applying a combined Norwegian and Swiss temperature inference model consisting of 274 lakes to the fossil chironomid assemblages. The Foppe record infers average July air temperatures of ca. 9.9 °C during the Oldest Dryas, 12.2 °C during most of the Bølling/Allerød and 11.1 °C for the Younger Dryas. Mean July air temperatures during the Preboreal were 14 °C. Major temperature changes were observed at the Oldest Dryas/Bølling (+2.7 °C), the Allerød/Younger Dryas (?2 °C) and the Younger Dryas/Holocene transitions (+3.9 °C). The temperature reconstruction also shows centennial‐scale coolings of ca. 0.8–1.4 °C, which may be synchronous with the Aegelsee (Greenland Interstadial 1d) and the Preboreal Oscillations. A comparison of our results with other palaeoclimate records suggests noticeable temperature gradients across the Alps during the Lateglacial and early Holocene. Copyright © 2011 John Wiley & Sons, Ltd.     

Supra‐glacial deposition and flux of catastrophic rock–slope failure debris,south‐central Alaska

The ongoing debate over the effects of global environmental change on Earth's cryosphere calls for detailed knowledge about process rates and their variability in cold environments. In this context, appraisals of the coupling between glacier dynamics and para‐glacial erosion rates in tectonically active mountains remain rare. We contribute to filling this knowledge gap and present an unprecedented regional‐scale inventory of supra‐glacial sediment flux and hillslope erosion rates inferred from an analysis of 123 large (> 0·1 km²) catastrophic bedrock landslides that fell onto glaciers in the Chugach Mountains, Alaska, as documented by satellite images obtained between 1972 to 2008. Assuming these supra‐glacial landslide deposits to be passive strain markers we infer minimum decadal‐scale sediment yields of 190 to 7400 t km^–2 yr^–1 for a given glacier‐surface cross‐section impacted by episodic rock–slope failure. These rates compare to reported fluvial sediment yields in many mountain rivers, but are an order of magnitude below the extreme sediment yields measured at the snouts of Alaskan glaciers, indicating that the bulk of debris discharged derives from en‐glacial, sub‐glacial or ice‐proximal sources. We estimate an average minimum para‐glacial erosion rate by large, episodic rock–slope failures at 0·5–0·7 mm yr^–1 in the Chugach Mountains over a 50‐yr period, with earthquakes likely being responsible for up to 73% of this rate. Though ranking amongst the highest decadal landslide erosion rates for this size of study area worldwide, our inferred rates of hillslope erosion in the Chugach Mountains remain an order of magnitude below the pace of extremely rapid glacial sediment export and glacio‐isostatic surface uplift previously reported from the region. Copyright © 2012 John Wiley & Sons, Ltd.     

Volatile organic compounds in coastal seawater

The occurence and temporal variations of a variety of low to medium polarity organic compounds in the volatility range bracketed by n-heptane and n-octadecane have been studied in seawater from a station in Vineyard Sound, Massachusetts, and from a tidal creek in Sippewisset Marsh, Massachusetts. The closed-loop vapor phase stripping method of Grob and Zürcher (J. Chromatogr., v. 117, p. 285–294), high resolution glass capillary gas chromatography, and gas chromatography-mass spectrometry were used. Approximately 50 compounds were found at ≥ 2 ng/kg; most were recovered at less than 10 ng/kg, while the 20 ng/kg level was only rarely exceeded by a few components. The total material recovered was 0.2–1.0 μg organic carbon equivalent/kg seawater. The major compound classes found were normal alkanes, alkenes, aromatic and alkylaromatic hydrocarbons, n-aldehydes, dimethyldisulfide and dimethyltrisulfide, and a few halogenated hydrocarbons. The preliminary results suggest that both biogenic and anthropogenic sources were representted. Also, air-sea gas exchange and other physical processes may be important non-biological sinks.