Cenozoic sediment distribution and tectonic movements in the Faroe region

A complex history of Cenozoic vertical movements in the Faroe region has been revealed from interpretation of geophysical and geological data, mainly offshore reflection seismic data, side-scan images, shallow cores, and onshore mapping. The history comprises several phases of tectonic disturbances observed at different scales. On the eastern margin of the Faroe Platform a late Eocene–early Oligocene phase of doming of the Faroe Platform has caused a postdepositional tilting of Eocene strata along the southern margin of the platform; a mid-Miocene phase of compressional tectonics is evidenced on seismic transects as gentle anticlines and associated reverse faults; and possible Pliocene uplift of the Faroe Islands is indicated by a progradational wedge of sediments deposited on the eastern Faroe Platform. At the continental margin/slope north of the Faroe Platform, reflection seismic data imaging the postbasalt sedimentary strata indicate three distinct tectonic events phases in the Eocene–Oligocene, Miocene and Pliocene, respectively. In contrast to the Faroe Platform the Faroe–Shetland Channel was characterised by more or less continuous subsidence dominated throughout the Cenozoic. During the Eocene, sediments deposited in the Faroe–Shetland Channel was mostly derived from a source area on the British shelf.     

Completely dark galaxies: their existence, properties and strategies for finding them

There are a number of theoretical and observational hints that large numbers of low-mass galaxies composed entirely of dark matter exist in the field. The theoretical considerations follow from the prediction of cold dark matter theory that there exist many low-mass galaxies for every massive one. The observational considerations follow from the observed paucity of these low-mass galaxies in the field but not in dense clusters of galaxies; this suggests that the lack of small galaxies in the field is due to the inhibition of star formation in the galaxies as opposed to the fact that their small dark matter haloes do not exist. In this work we outline the likely properties of low-mass dark galaxies, and describe observational strategies for finding them, and where in the sky to search. The results are presented as a function of the global properties of dark matter, in particular the presence or absence of a substantial baryonic dark matter component. If the dark matter is purely cold and has a Navarro, Frenk & White density profile, directly detecting dark galaxies will only be feasible with present technology if the galaxy has a maximum velocity dispersion in excess of 70 km s⁻¹, in which case the dark galaxies could strongly lens background objects. This is much higher than the maximum velocity dispersions in most dwarf galaxies. If the dark matter in galaxy haloes has a baryonic component close to the cosmic ratio, the possibility of directly detecting dark galaxies is much more realistic; the optimal method of detection will depend on the nature of the dark matter. A number of more indirect methods are also discussed.     

Darss Sill as a biological border in the fossil record of the Baltic Sea: evidence from diatoms

Biostratigraphical and palaeoecological analyses of cores along a transect from Femer Belt to the Arkona Basin reveal that North Sea waters began to enter the western Baltic Sea between 8600 and 8400 calibrated years BP. Studies of diatoms indicate that Mecklenburg Bay was characterised by slightly brackish-water conditions between 8400 and 8000 cal. years BP. At around 8000 cal. years BP increasing salinity is indicated by a strong dominance of the diatoms Paralia sulcata and Dimeregramma minor. Some centuries later another diatom assemblage appeared and became dominant in Mecklenburg Bay. This assemblage includes Hyalinella lateripunctata and Pravifusus hyalinus species typical of shallow water areas along the Atlantic coast today. At this time the first marine molluscs made their appearance. The oldest shell of a marine mollusc found in our material is dated to 7600 cal. years BP. The associated assemblage that includes adult specimens of the gastropod Aporrhais pespelicani indicates higher salinities than today.During the Littorina Sea stage a marine diatom flora with P. sulcata, Catenula adhaerens and D. minor crossed the Darss Sill and became widely distributed in the Arkona Basin, Pomeranian Bay and the Baltic Sea proper. In contrast, taxa indicative of the Hyalinella lateripunctata/P. hyalinus assemblage are only found west of the Darss Sill in Femer Belt and Mecklenburg Bay. Apparently, the Darss Sill threshold has been acting as an important salinity border from around 7800 cal. years BP until today.     

Ground Water Contamination from Creosote Sites

Field data from 44 waste sites contaminated with creosote have been compiled in a database. The data from each site included geological and hydrogeological parameters and the concentrations of creosote compounds in the ground water at various distances from the pollution sources. The creosote compounds that were measured included mononuclear aromatic hydrocarbons and polynuclear aromatic hydrocarbons (PAH) and phenols. Already 50 m down-gradient of the creosote waste sites, 90 percent of the concentrations were from three to 50 times lower than at the source, and most of the median concentrations were below detection limit (0.1 to 0.5 μg/L). The maximum concentrations of benzene, toluene, and xylenes (BTX) and phenols were much lower under aerobic than under anaerobic conditions. Among the phenols, the xylenols (dimethylphenols) appear in higher concentrations under aerobic conditions than phenol and the cresols do. The highest concentrations found were of the same order of magnitude as the calculated solubilities found in the literature, except the chrysene and benz(a)pyrene concentrations, which were one to two orders of magnitude higher than the solubilities.     

Effect of grain scale alignment on seismic anisotropy and reflectivity of shales

The elastic properties and anisotropy of shales are strongly influenced by the degree of alignment of the grain scale texture. In general, an orientation distribution function (ODF) can be used to describe this alignment, which, in practice, can be characterized by two Legendre coefficients. We discuss various statistical ODFs that define the alignment by spreading from a mean value; in particular, the Gaussian, Fisher and Bingham distributions. We compare the statistical models with an ODF resulting from pure vertical compaction (no shear strain) of a sediment. The compaction ODF may be used to estimate how the elastic properties and anisotropy evolve due to burial of clayey sediments. Our study shows that the three statistical ODFs produce almost identical correspondence between the two Legendre coefficients as a function of the spreading parameter, so that the spreading parameter of one ODF can be converted to the spreading parameter of another ODF. In most cases it is then sufficient to apply the spreading parameter for the ODF instead of the two Legendre coefficients. The effect of compaction on the ODF gives a slightly different correspondence between the two Legendre coefficients from that for the other models. In principle, this opens up the possibility of distinguishing anisotropy effects due to compaction from those due to other processes. We also study reflection amplitudes versus angle of incidence (AVA) for all wave modes, where shales having various ODFs overlie an isotropic medium. The AVA responses are modelled using both exact and approximation formulae, and their intercepts and gradients are compared. The modelling shows that the S‐wave velocity is sensitive to any perturbation in the spreading parameter, while the P‐wave velocity becomes increasingly sensitive to a perturbation of a less ordered system. Similar observations are found for the AVA of the P‐P and P‐SV waves. Modelling indicates that a combined use of the amplitude versus offset of P‐P and P‐SV reflected waves may reveal certain grain scale alignment properties of shale‐like rocks.     

Cichlid species diversity in naturally and anthropogenically turbid habitats of Lake Victoria, East Africa

During the past decades, major anthropogenic environmental changes occurred in Lake Victoria, including increased predation pressure due to Nile perch introduction, and decreases in water transparency and dissolved oxygen concentrations due to eutrophication. This resulted in a collapse of the haplochromine cichlids in the sub-littoral waters of the Mwanza Gulf in 1986–1990, followed by a recovery of some species in the 1990s and 2000s, when Nile perch densities declined. We studied two data sets: (1) haplochromines from sand and mud bottoms in the pre-collapse period; (2) haplochromines from sub-littoral areas during the pre-collapse, collapse and recovery periods. Water over mud is murkier and poorer in oxygen than water over sand, and differences in haplochromine communities in these natural habitats during the pre-collapse period may predict the effects of anthropogenic eutrophication during the collapse and recovery periods. In the pre-collapse period, haplochromine densities over sand and mud did not differ, but species richness over sand was 1.6 times higher than over mud bottoms. Orange- and white-blotched colour morphs were most common at the shallowest sand station. More specifically, insectivores and mollusc-shellers had higher numbers of species over sand than over mud, whereas for mollusc-crushers no difference was found. Laboratory experiments revealed that mollusc shelling was more affected by decreased light intensities than mollusc crushing. During the pre-collapse period, spawning occurred year-round in shallow areas with hard substrates and relatively clear water. In deeper areas with mud bottoms, spawning mainly occurred during months in which water clarity was high. No effects of hypoxia on spawning periods were found. It follows that clearer water seems to support differentiation in feeding techniques as well as year-round spawning, and both may facilitate species coexistence. Water clarity is also known to be important for mate choice. These observations may explain why, since the decline of Nile perch, haplochromine densities have recovered, the numbers of hybrids increased and species diversity in the current eutrophic sub-littoral waters has remained 70 % lower than before the environmental changes.     

Reactions of Cl Atoms with Selected VOCs: Kinetics, Products and Mechanisms

The reactions of isoprene, MBO (2-methyl-3-buten-2-ol) and toluene with chlorine atoms have been studied at 298 ± 5 K and 740 ± 5 Torr with the use of FTIR spectroscopy. Major products of the isoprene-Cl reaction and of the MBO-Cl reaction have been identified and quantified, and reaction mechanisms have been tentatively proposed in order to explain the products formed. The reaction between isoprene and Cl atoms yields mainly HCl, formyl chloride, formic acid, methylglyoxal (pyruvic aldehyde), CO and CO2, while the MBO-Cl reaction forms acetone, HCl, formyl chloride, formic acid, CO, CO2. As products from the reaction between toluene and Cl we identified and quantified HCl and benzaldehyde. The rate constants for the reactions of isoprene and toluene with Cl atoms have also been determined using a relative rate method. The measured values are: kisoprene = (5.5 ± 1.0) × 10–10 cm3 molecule–1 s–1 and ktoluene = (5.6 ± 1.3) × 10–11 cm3 molecule–1 s–1. Atmospheric lifetimes have been estimated from these values.     

An inter-comparison of regional climate models for Europe: model performance in present-day climate

The analysis of possible regional climate changes over Europe as simulated by 10 regional climate models within the context of PRUDENCE requires a careful investigation of possible systematic biases in the models. The purpose of this paper is to identify how the main model systematic biases vary across the different models. Two fundamental aspects of model validation are addressed here: the ability to simulate (1) the long-term (30 or 40 years) mean climate and (2) the inter-annual variability. The analysis concentrates on near-surface air temperature and precipitation over land and focuses mainly on winter and summer. In general, there is a warm bias with respect to the CRU data set in these extreme seasons and a tendency to cold biases in the transition seasons. In winter the typical spread (standard deviation) between the models is 1 K. During summer there is generally a better agreement between observed and simulated values of inter-annual variability although there is a relatively clear signal that the modeled temperature variability is larger than suggested by observations, while precipitation variability is closer to observations. The areas with warm (cold) bias in winter generally exhibit wet (dry) biases, whereas the relationship is the reverse during summer (though much less clear, coupling warm (cold) biases with dry (wet) ones). When comparing the RCMs with their driving GCM, they generally reproduce the large-scale circulation of the GCM though in some cases there are substantial differences between regional biases in surface temperature and precipitation.