Mapping soil pollution by spatial analysis and fuzzy classification

Spatial analysis and fuzzy classification techniques were used to estimate the spatial distributions of heavy metals in soil. The work was applied to soils in a coastal region that is characterized by intense urban occupation and large numbers of different industries. Concentrations of heavy metals were determined using geostatistical techniques and classes of risk were defined using fuzzy classification. The resulting prediction mappings identify the locations of high concentrations of Pb, Zn, Ni, and Cu in topsoils of the study area. The maps show that areas of high pollution of Ni and Cu are located at the northeast, where there is a predominance of industrial and agricultural activities; Pb and Zn also occur in high concentrations in the northeast, but the maps also show significant concentrations of Pb and Zn in other areas, mainly in the central and southeastern parts, where there are urban leisure activities and trade centers. Maps were also prepared showing levels of pollution risk. These maps show that (1) Cu presents a large pollution risk in the north–northwest, midwest, and southeast sectors, (2) Pb represents a moderate risk in most areas, (3) Zn generally exhibits low risk, and (4) Ni represents either low risk or no risk in the studied area. This study shows that combining geostatistics with fuzzy theory can provide results that offer insight into risk assessment for environmental pollution.     

Late Pleistocene raised beaches of coastal Estremadura,central Portugal

We present new stratigraphic, sedimentological, and chronological data for a suite of tectonically raised beaches dating to Marine Isotope Stages 5, 4, and 3 along the Estremadura coast of west-central Portugal. The beach deposits are found in association with ancient tidal channels and coastal dunes, pollen bearing mud and peat, and Middle Paleolithic archaeological sites that confirm occupation of the coastal zone by Neanderthal populations. The significance of these deposits is discussed in terms of the archaeological record, the tectonic and geomorphic evolution of the coast, and correlation with reconstructions of global climate and eustatic sea-level change. Direct correlation between the Estremadura beach sections is complicated by the tectonic complexity of the area and the age of the beach deposits (which are near or beyond the limit of radiocarbon dating). Evidence from multiple sites dated by AMS radiocarbon and optical luminescence methods suggests broad synchroneity in relative sea-level changes along this coast during Marine Isotope Stage 3. Two beach complexes with luminescence and radiocarbon age control date to about 35 ka and 42 ka, recording a rise in relative sea level around the time of Heinrich Event 4 at 39 ka. Depending on assumptions about eustatic sea level at the time they were deposited, we estimate that these beaches have been uplifted at rates of 0.4–4.3 mm yr^?1 by the combined effects of tectonic, halokinetic, and isostatic processes. Uplift rates of 1–2 mm yr^?1 are likely if the beaches represent sea level stands at roughly 40 m below modern, as suggested by recent eustatic sea level reconstructions. Evidence from coastal bluffs and the interior of the study area indicates extensive colluvial, fluvial, and aeolian sedimentation beginning around 31 ka and continuing into the Holocene. These geomorphic adjustments are related to concomitant changes in climate and sea level, providing context that improves our understanding of Late Pleistocene landscape change and human occupation on the western Iberian margin.     

Large shear zones with no relative displacement

In the Oman ophiolite, the large scale Makhibiyah shear zone, in Wadi Tayin massif was generated with no or little relative motion between the two adjacent blocks, in contrast with what is reported from otherwise similar shear zones in deep crust and upper mantle. This shear zone is asymmetrical with, along one margin an asthenospheric mantle (～1200 °C) and along the adjacent margin, a lithospheric mantle (～1000 °C). Within the hotter side and with increasing shear strain, horizontal flow lines smoothly swing towards the shear zone direction before abutting against the wall of the lithosphere side. Profuse mafic melts issued from the hotter mantle are frozen in the shear zone by cooling along this lithospheric wall. Tectonic and magmatic activities are entirely localized within the asthenospheric compartment. Mantle flow lines were rotated, during their channelling along this NW‐SE shear zone, in the NW and SE opposite directions. Depending on whether the flow lines are deviated NW or SE, dextral or sinistral shear sense is recorded in the shear band mylonitic peridotites. This demonstrates that the shear zone was not generated by strike‐slip motion, a conclusion supported by regional observations.     

Isotopic constraints on the Si-biogeochemical cycle of the Antarctic Zone in the Kerguelen area (KEOPS)

Estimation of the silicon (Si) mass balance in the ocean from direct measurements (Si uptake-dissolution rates …) is plagued by the strong temporal and spatial variability of the surface ocean as well as methodological artifacts. Tracers with different sensitivities toward physical and biological processes would be of great complementary use. Silicon isotopic composition is a promising proxy to improve constraints on the Si-biogeochemical cycle, since it integrates over longer timescales in comparison with direct measurements and since the isotopic balance allows to resolve the processes involved, i.e. uptake, dissolution, mixing. Si-isotopic signatures of seawater Si(OH)₄ and biogenic silica (bSiO₂) were investigated in late summer 2005 during the KEOPS experiment, focusing on two contrasting biogeochemical areas in the Antarctic Zone: a natural iron-fertilized area above the Kerguelen Plateau (< 500 m water depth) and the High Nutrient Low Chlorophyll area (HNLC) east of the plateau (> 1000 m water depth). For the HNLC area the Si-isotopic constraint identified Upper Circumpolar Deep Water as being the ultimate Si-source. The latter supplies summer mixed layer with 4.0 ± 0.7 mol Si m^? 2 yr^? 1. This supply must be equivalent to the net annual bSiO₂ production and exceeds the seasonal depletion as estimated from a simple mixed layer mass balance (2.5 ± 0.2 mol Si m^? 2 yr^? 1). This discrepancy reveals that some 1.5 ± 0.7 mol Si m^? 2 yr^? 1 must be supplied to the mixed layer during the stratification period. For the fertilized plateau bloom area, a low apparent mixed layer isotopic fractionation value (?³⁰Si) probably reflects (1) a significant impact of bSiO₂ dissolution, enriching the bSiO₂ pool in heavy isotope; and/or (2) a high Si uptake over supply ratio in mixed layer at the beginning of the bloom, following an initial closed system operating mode, which, however, becomes supplied toward the end of the bloom (low Si uptake over supply ratio) with isotopically light Si(OH)₄ from below when the surface Si(OH)₄ pool is significantly depleted. We estimated a net integrated bSiO₂ production of 10.5 ± 1.4 mol Si m^? 2 yr^? 1 in the AASW above the plateau, which includes a significant contribution of bSiO₂ production below the euphotic layer. However, advection which could be significant for this area has not been taken into account in the latter estimation based on a 1D approach of the plateau system. Finally, combining the KEOPS Si-isotopic data with those from previous studies, we refined the average Si-isotopic fractionation factor to ? 1.2 ± 0.2‰ for the Antarctic Circumpolar Current.     

A theoretical analysis of the systematic errors in the red clump distance to the Large Magellanic Cloud (LMC)

We present a detailed analysis of the uncertainty on the theoretical population corrections to the Large Magellanic Cloud (LMC) red clump (RC) absolute magnitude, by employing a population synthesis algorithm to simulate theoretically the photometric and spectroscopic properties of RC stars, under various assumptions concerning the LMC star formation rate (SFR) and age–metallicity relationship (AMR). A comparison of the outcome of our simulations with observations of evolved low- to intermediate-mass stars in the LMC allows one to select the combinations of SFR and AMR that bracket the real LMC star formation history, and to estimate the systematic error on the associated RC population corrections.
The most accurate estimate of the LMC distance modulus from the RC method (adopting the OGLE-II reddening maps for the LMC) is obtained from the K -band magnitude, and provides  ( m − M )_0,LMC= 18.47 ± 0.01(random)^+0.05_−0.06(systematic)  . Distances obtained from the I band, or from the multicolour RC technique which determines at the same time reddening and distance, both agree (albeit with a slightly larger error bar) with this value.     

Merging circulations on Jupiter: Observed differences between cyclonic and anticyclonic mergers

The dynamics of mergers of large circulations in Jupiter's atmosphere may permit different models of the atmosphere to be tested. We report well-resolved observations of such events at visible wavelengths: three anticyclonic and three cyclonic events. A merger of anticyclonic white ovals in the South South Temperate domain (2002 March) is compared with the previously reported merger of ovals BE and FA in the South Temperate domain (2000 March). In each case, the two similar-sized ovals converged rapidly once they were separated by less than the sum of their diameters; they orbited around each other anticyclonically during the merger; the merged oval initially had the same rapid drift as the western parent; and, in an unexpected similarity, a cyclonic oval emerged westward from the point of merger. Evidence suggests that a merger of smaller ovals in the North North Temperate domain (2002 February) had similar dynamics. In contrast, mergers of cyclonic ovals in the North Equatorial Belt (‘barges’: 2001 November, 2005 May) proceeded in a different manner. The two parent barges showed no consistent acceleration towards each other as they converged; on contact there was no obvious sign of mutual circulation, and the low-albedo regions had almost passed each other before they finally merged; and the resulting barge had a drift rate intermediate between the two parents, and a length that was greater than either parent. Again, a third such event involving a smaller barge (2002 December) showed many of the same characteristics. These observations define different dynamical behaviour during anticyclonic and cyclonic mergers.     

Large-scale slope failure involving Triassic and Middle Miocene salt and shale in the Gulf of Cádiz (Atlantic Iberian Margin)

Sheets of salt and ductile shale advancing beyond the thrust front of the Gibraltar Arc (Iberian–Moroccan Atlantic continental margin) triggered downslope movements of huge allochthonous masses. These allochthons represent the Cádiz Nappe, which detached from the Gibraltar Arc along low‐angle normal faults and migrated downslope from the Iberian and Moroccan continental margins towards the Atlantic Ocean. Extensional tectonics initiated upslope salt withdrawal and downslope diapirism during large‐scale westward mass wasting from the shelf and upper slope. Low‐angle salt and shale detachments bound by lateral ramps link extensional structures in the shelf to folding, thrusting and sheets of salt and shale in the Gulf of Cádiz. From backstripping analyses carried out on the depocentres of the growth‐fault‐related basins on the shelf, we infer two episodes of rapid subsidence related to extensional collapses; these were from Late Tortonian to Late Messinian (200–400 m Myr^?1) and from Early Pliocene to Late Pliocene (100–150 m Myr^?1). The extensional events that induced salt movements also affected basement deformation and were, probably, associated with the westward advance of frontal thrusts of the Gibraltar Arc as a result of the convergence between Africa and Eurasia. The complexities of salt and/or shale tectonics in the Gulf of Cádiz result from a combination of the deformations seen at convergent and passive continental margins.