Do reduction spots predate finite strain? A magnetic diagnosis of Cambrian slates in North Wales

The purple Cambrian slates of North Wales contain green-colored, irregular patches drawn out along cleavage and the more familiar ellipsoidal reduction spots that are parallel to cleavage. Because parallelism of pre-strain ellipsoids could only be produced by extremely high strain, we reject the hypothesis that these are strain markers. Here, we use magnetic methods to resolve this argument. The magnetic analysis reveals that the magnetic fabric of purple slate differs from the green variety of the slate only in the oxidation state, and indicates that the reduction process postdates cleavage. This suggests that the shape of reduction spots reflects the anisotropy of diffusion during reduction, not finite strain and alignment of an initially ellipsoidal object in the slates.     

δ15N of PON and Nitrate as a Clue to the Origin and Transformation of Nitrogen in the Subarctic North Pacific and Its Marginal Sea

Nitrogen isotope compositions of particulate organic matter and nitrate were analyzed for seawater sampled at five stations at the Alaskan Gyre, Western Subarctic Gyre and East China Sea, focusing on the samples from the surface to 5000 m water to characterize the nitrogen cycling in the subarctic North Pacific Ocean and its marginal sea. The ¹⁵N of particulate organic matter showed little agreement with a conceptual closed model that interprets isotopic variation as being caused by isotope discrimination on nitrate utilization. The ¹⁵N and ¹³C of particulate organic matter varied with the water depth. A correlation between isotope compositions and C/N elemental ratio was found generally at all stations, although some irregular data were also found in deep layers. We developed a hypothetical nitrogen balance model based on N₂ fixation and denitrification in seawater and attempted to apply it to distinguish nutrient cycling using both ¹⁵N-NO₃ ^– and N* variation in seawater. This model was applied to the observed data set of ¹⁵N-NO₃ ^– and N* in the North Pacific water and estimated the ¹⁵N-NO₃ ^– of primordial nitrate in the North Pacific deep water as 4.8. The North Pacific intermediate water for all stations showed similar ¹⁵N-NO₃ ^– and N* values of 6 and –3 µmol/kg, respectively, suggesting a similar nitrogen biogeochemistry. In the East China Sea, analysis showed evidence of water exchange with the North Pacific intermediate water but a significant influence of nitrogen from the river runoff was found in depths shallower than 400 m.     

Modeling boulder transport by coastal waves on cliff topography: Case study at Hachijo Island,Japan

Clifftop coastal boulders transported by storm waves or tsunamis have been reported around the world. Although numerical calculation of boulder transport is a strong tool for the identification of tsunami or storm boulders, and for estimation of the wave size emplacing boulders, models which can reasonably solve boulder transport from below a cliff or from a cliff-edge onto a cliff-top do not yet exist. In this study, we developed a new numerical formulation for cliff-top deposition of boulders from the cliff edge or below the cliff, with validation from laboratory tests. We then applied the model using storm and tsunami wave forcing to simulate the observed boulder deposits at the northwest coast of Hachijo Island, Japan. Using the model, the actual distribution of boulders was explained well using a reasonable storm wave height without assumption of anomalously high-water level by storm surge. Results show that boulder transport from the cliff edge or under the cliff onto the cliff-top was possible from a tsunami with periods of 5~10 min or storm waves with no storm surge. However, the actual distribution of boulders on the cliff was explained only by storm waves, but not by tsunami. Therefore, the boulders distributed at this site are likely of storm wave origin. Our developed model for the boulder transport calculation can be useful for identifying a boulder's origin and can reasonably calculate cliff-top deposition of boulders by tsunami and storm waves. © 2019 John Wiley & Sons, Ltd. © 2019 John Wiley & Sons, Ltd.     

Modelling of fractured carbonate reservoirs: outline of a novel technique via a case study from the Molasse Basin, southern Bavaria, Germany

Fluid flow in low-permeable carbonate rocks depends on the density of fractures, their interconnectivity and on the formation of fault damage zones. The present-day stress field influences the aperture hence the transmissivity of fractures whereas paleostress fields are responsible for the formation of faults and fractures. In low-permeable reservoir rocks, fault zones belong to the major targets. Before drilling, an estimate for reservoir productivity of wells drilled into the damage zone of faults is therefore required. Due to limitations in available data, a characterization of such reservoirs usually relies on the use of numerical techniques. The requirements of these mathematical models encompass a full integration of the actual fault geometry, comprising the dimension of the fault damage zone and of the fault core, and the individual population with properties of fault zones in the hanging and foot wall and the host rock. The paper presents both the technical approach to develop such a model and the property definition of heterogeneous fault zones and host rock with respect to the current stress field. The case study describes a deep geothermal reservoir in the western central Molasse Basin in southern Bavaria, Germany. Results from numerical simulations indicate that the well productivity can be enhanced along compressional fault zones if the interconnectivity of fractures is lateral caused by crossing synthetic and antithetic fractures. The model allows a deeper understanding of production tests and reservoir properties of faulted rocks.     

Groundwater deterioration in Nankou—a suburban area of Beijing: data assessment and remediation scenarios

Since the 1980s, high-nitrate concentration in one of the groundwater sampling wells at the Nankou site, northwest of the Beijing Plain, has become a major concern for the local water authority. In a previous study (Sun et?al. in Environ Earth Sci 64(5):1323?C1333, 2011), a hydrogeological structural model was developed based on the borehole logs of this area and the steady, as well as transient groundwater-flow models, were calibrated using the measured hydraulic heads. In this paper, the potential pollution sources in this area are investigated. The chemical analysis of the groundwater is also presented. The results demonstrate that the most likely pollution source is the untreated wastewater discharge from a nearby fertilizer factory. Furthermore, a mass transport model is developed to reproduce the nitrate transport process in the aquifer at the Nankou site under different pollution sources, i.e., a fertilizer factory, river with wastewater and an agriculture field. The combined effects of the river and agriculture fields present a better understanding of the nitrate transport in the local aquifer. In addition, a pumping scenario is designed to clean up the current nitrate concentration. The pumping rate and the well location are first estimated with 2-D analytical solutions of the type curves method. Then a 3-D numerical model is used to calculate the nitrate-concentration changes after the pumping activities start. In the downstream direction of the regional groundwater flow, three pumping wells are set up for the clean-up strategy. The calculated pumping rate in each well is about 1,500 m³/day. After 1?year, the nitrate concentration in the observation well recedes to 68?mg/l from the initial value of 72.9?mg/l, and it will be lower than the limitation value (20?mg/l) after 5,400 days of groundwater extraction. The data assessment and clean-up scenarios reported in this paper are fundamental for the contaminated aquifer management in the future.     

Application of the Pi theorem to the wear rate of gouge formation in frictional sliding of rocks

A simple law of wear rate is examined for the process of gouge generation during the frictional sliding of simulated faults in rocks, by use of the Pi theorem method (dimensional analysis) and existing experimental data. The relationship between wear rate (t/d) and the applied stress can be expressed by the power-law relations $$\frac{t}{d} = C_\sigma \sigma ^{m\sigma } ,\frac{t}{d} = C_\tau \tau ^{m\tau }$$ wheret is the thickness of the gouge generated on the frictional surfaces,d is the fault displacement, σ and τ are normal stress and shear stress, respectively, andC _σ,C _τ,m _σ andm _τ are constants. These results indicate that the exponent coefficientsm _σ andm _τ and the coefficientsC _σ andC _τ depend on the material hardness of the frictional surfaces. By using the wear rates of natural faults, these power-law relationships may prove to be an acceptable palaeopiezometer of natural faults and the lithosphere.     

Laboratory verification of submicron magnetite production in pseudotachylytes: relevance for paleointensity studies

Pseudotachylytes generally possess stable remanent magnetizations but the processes by which pseudotachylytes are magnetized remain poorly understood. Magnetic hysteresis and scanning electron microscope studies reveal that experimental frictional melting of granites produces dispersed submicron inclusions of weakly interacting pseudo-single-domain (PSD) magnetite, in artificial pseudotachylyte. The magnetite inclusions are absent in the undeformed granite protolith and result from oxidation of Fe in melt-susceptible mafic minerals during the melt-quenched event. The pseudotachylytes acquired a stable thermal remanence in fine-grained PSD magnetites during the rapid cooling of the melt, implying that fine-grained magnetite has the potential for paleointensity determinations of contemporaneous magnetic fields with co-seismic faulting in granitoids.