Distribution of nitrate in groundwater affected by the presence of an aquitard at an agricultural area in Chiba, Japan

Geological and geographical parameters including land use, stratigraphic structure, groundwater quality, and N- and O-isotopic compositions of nitrate in groundwater were investigated to elucidate the mechanism of groundwater pollution by NO₃ ^? in the agricultural area of Katori, Chiba, Japan. An aquitard distributed in the western part of the study area has produced two unconfined aquifers. The average concentrations of NO₃ ^? and dissolved oxygen (DO) were high in the aquifer above the aquitard (7.5 and 7.6 mg/L, respectively) and in the aquifer of the eastern part of the study area that was not influenced by the aquitard (11.9 and 7.8 mg/L, respectively); however, the levels in the aquifer under the aquitard were relatively low (2.2 and 3.7 mg/L, respectively). The δ¹⁵N and δ¹⁸O values of NO₃ ^? generally increased exponentially in the groundwater that flowed into the aquifer under the aquitard as the concentration of NO₃ ^? decreased, although this decrease in NO₃ ^? also occasionally occurred without isotopic changes. These results indicated that the aquitard prevented the penetration of NO₃ ^?, DO, and gaseous O₂. Under the aquitard, denitrification and dilution with unpolluted water that entered from natural forested areas reduced the NO₃ ^? concentrations in the groundwater. The major sources of NO₃ ^? in groundwater in the study area were estimated to be NH₄-chemical fertilizer, livestock waste, and manure.     

Rayleigh scattering by aqueous colloidal silica as a cause for the blue color of hydrothermal water

Thermal waters in hydrothermal ponds, bathing pools and the brines of geothermal electric power plants commonly have a characteristic blue color. Although many researchers have assumed that the blue color is due to a colloidal suspension and/or absorption by dissolved ferrous iron or by water itself, there has been no specific effort to identify the physical nature of this phenomenon. We have tested, in synthetic and natural solutions, whether aqueous colloidal silica is responsible for the blue color. Aqueous colloidal silica is formed by silica polymerization in thermal waters of the neutral-chloride type which contain initially monomeric silica in concentrations up to three times above the solubilities of amorphous silica. The hue of the blue thermal waters in the pools tested agrees with that of a synthesized colloidal silica solution. Grain-size analyses of aqueous colloidal silica in the blue-colored thermal waters demonstrate that the color is caused by Rayleigh scattering from aqueous colloidal silica particles with diameters (0.1–0.45 μm) smaller than the wavelengths of visible radiation.     

Model experiment for the interaction of solar plasma stream and geomagnetic field

A laboratory experiment is designed to study the interaction of the solar wind with the geomagnetic field. Time-exposure and time-resolved photographs are taken when plasma hits a model Earth, and direct measurements are made of the magnetic field change, plasma density and electric current distribution. The shape of the magnetic cavity formed on the upstream side of the model Earth is almost the same as that calculated for the geomagnetic cavity. The charged particles, which penetrate the magnetic cavity formed on the upstream side of the model Earth with east-west asymmetry from the neutral points on the cavity surface, appear to concentrate towards the equator on the rear side of the model, forming a westward electric current belt within the magnetosphere. When the dipole axis is not perpendicular to the plasma gun—magnetic dipole line, the invasion of plasma is more pronounced at the cusp of the cavity nearer to the gun. Charged particles appear to penetrate to a greater extent if a uniform external magnetic field is applied parallel to the magnetic dipole than if one is applied antiparallel.     

A 27-kyr record of environmental change in central Asia inferred from the sediment record of Lake Hovsgol,northwest Mongolia

Geochemistry of a sediment core from Lake Hovsgol, northwest Mongolia provides a continuous, 27-kyr history of the response of the lake and the surrounding catchment to climate change. Principle component (PC) analysis of 19 major and trace elements, total inorganic carbon (TIC), and total organic carbon (TOC) in the bulk sediment samples revealed that the 21 chemical components can be grouped into four assemblages—group-1: Na, Mg, Ca, Sr, and TIC, hosted in carbonate minerals (calcite, dolomite, and magnesian calcite); group-2: Ni, Cu, and Zn, recognized as biophilic trace metals, and TOC; group-3: Al, K, Ti, V, Fe, Rb, Cs, Ba, and Pb, composed of rock-forming minerals; and group-4: Cr, Mn, and As, sensitive to the redox condition of the sediment. The four element assemblages originated from three relevant processes. Group-1 and group-2 components are authigenic products and comprise the end member on the PC-1 score, whose variation reflects changes in the water volume, i.e. the balance between precipitation and evaporation (P/E). Group-3 components from detrital materials of the catchment contribute to the PC-2 score, whose variability indicates erosion/weathering intensity in the drainage basin, which might be controlled by the amount of vegetation cover associated with moisture change. The group-4 components of redox-sensitive elements contribute to the PC-3 score and are not an end member because of their small amount. The first two PC scores suggest a sequential record of paleo-moisture evolution in central Asia. The P/E balance in the Lake Hovsgol region, inferred from the PC-1 score, gradually increased during the glacial/interglacial transition. This resembles climate change of the North Atlantic region on the glacial–interglacial scale, but does not reflect the abrupt climate shifts such as the warm Bølling-Allerød and the cold Younger Dryas of the North Atlantic on the millennial scale. A periodic variation of ~8.7 kyr was observed in the PC-2 score profile of detrital input to Lake Hovsgol over the last glacial and Holocene. The decrease in detrital input coincided with the copious supply of moisture from the Asian monsoon regime and the North Atlantic westerly winds to the Baikal drainage basin, which includes Lake Hovsgol. Our geochemical records from Lake Hovsgol demonstrate that the climate system of interior continental Asia was strongly influenced by change on both Milankovitch and sub-Milankovitch scales.     

Orbital signals found in physical and chemical properties of bottom sediments from Lake Baikal

Physical and chemical properties of two 100 m sediment cores (BDP-93-1, 93-2) obtained from the Buguldeika saddle of Lake Baikal in the eastern Siberia and a ¹⁴C-based age scale for the core show that the core bottom is about 400000 years ago and that the changes in the sedimentological environment of the area during the interval were that comparatively coarse and high C/N ratio sediments accumulated in the lake during interglacial periods, and fine material and low C/N ratio during glacial periods. The tentative age scale suggests that the first excursion in the earth's magnetic field at about 26 m (BDP-93-1 and 93-2) from the sediment surface corresponds to the Blake event. Statistical analyses of the data-sets for the some properties show that the fluctuations have distinct periods; 20000 years, 40000 years and 100000 years, that are related to the Milankovitch parameters and support that the tentative age scale is approximately acceptable.     

Integrating Arc Hydro Features with a Schematic Network

A framework for integrating GIS features with processing engines to simulate hydrologic behavior is presented. The framework is designed for compatibility with the ArcGIS ModelBuilder environment, and utilizes the data structure provided by the SchemaLink and SchemaNode feature classes from the ArcGIS Hydro data model. SchemaLink and SchemaNode form the links and nodes, respectively, in a schematic network representing the connectivity between hydrologic features pertinent to the movement of surface water in the landscape. A specific processing engine is associated with a given schematic feature, depending on the type of feature the schematic feature represents. Processing engines allow features to behave as individual hydrologic processors in the landscape. The framework allows two types of processes for each feature, a Receive process and a Pass process. Schematic network features operate with four types of values: received values, incremental values, total values, and passed values. The framework assumes that the schematic network is dendritic, and that no backwater effects occur between schematic features. A case study is presented for simulating bacterial loading in Galveston Bay in Texas from point and nonpoint sources. A second case study is presented for simulating rainfall‐runoff response and channel routing for the Llano River in Texas.     

Fourth‐ to third‐order cycles in the Hakobuchi Formation: Shallow‐marine Campanian final deposition of the Yezo Group,Nakagawa area,northern Hokkaido,Japan

The Yezo Group has a wide longitudinal distribution across Hokkaido, northern Japan. It represents a Cretaceous (Early Aptian–Late Maastrichtian) and Late Paleocene forearc basin‐fill along the eastern margin of the paleo‐Asian continent. In the Nakagawa area of northern Hokkaido, the uppermost part of the Yezo Group consists of the Hakobuchi Formation. Along the western margin of the Yezo basin, 24 sedimentary facies (F) represent 6 facies associations (FA), suggesting prevailing storm‐dominated inner shelf to shoreface environments, subordinately associated with shoreface sand ridges, outer shelf, estuary and fluvial environments. The stacking patterns, thickness and facies trends of these associations allow the discrimination of six depositional sequences (DS). Inoceramids Sphenoceramus schmidti and Inoceramus balticus, and the ammonite Metaplacenticeras subtilistriatum, provide late Early to Late Campanian age constraints to this approximately 370‐m thick final stage of deposition and uplift of the Yezo forearc basin. Six shallow‐marine to subordinately non‐marine sandstone‐dominated depositional sequences include four 10 to 110‐m thick upward‐coarsening regressive successions (FS1), occasionally associated with thin, less than 10‐m thick, upward‐fining transgressive successions (FS2). The lower DS1–3, middle DS4–5 and upper DS6 represent three depositional sequential sets (DSS1–3). These eastward prograding and westward retrograding recurring shallow‐marine depositional systems may reflect third‐ and fourth‐order relative sealevel changes, in terms of sequence stratigraphy.