Fate and effects of picric acid and 2,6-DNT in marine environments: toxicity of degradation products

The toxicity of transformation products of 2,6-dinitrotoluene (2,6-DNT) and 2,4,6-trinitrophenol (picric acid) were assessed in spiked sandy and fine-grained marine sediments and in seawater. Toxicity of pore water from sediments spiked with 2,6-DNT decreased for the macro-alga, Ulva fasciata, zoospores as biotransformation proceeded, but increased for the copepod, Schizopera knabeni, nauplii. The primary biotransformation product of 2,6-DNT, 2-amino-6-nitrotoluene, was also more toxic than the parent compound to copepod nauplii, but not to alga zoospores, in spiked seawater tests. Two biotransformation products of picric acid, picramic acid and 2,4-DNP, were more toxic than their parent compound. Porewater toxicity from picric acid-spiked sediments decreased significantly at the end of six-months incubation. Fine-grained sediment spiked with either ordnance compound had lower toxicity than its sandy counterpart after six months, suggesting faster microbial transformation in the former and production of less toxic products. Photo-transformation of 2,6-DNT in seawater resulted in a reduction in toxicity.     

Zum Verhalten von Ankerit im geschlossenen Gefüge und als Einzelkorn.

Ohne ZusammenfassungMit 14 Gefügediagrammen.     

Toxicological and chemical assessment of ordinance compounds in marine sediments and porewaters

Toxicological and chemical studies were performed with a silty and a sandy marine sediment spiked with 2,6-dinitrotoluene (2,6-DNT), 2,4,6-trinitrophenylmethylnitramine (tetryl), or 2,4,6-trinitrophenol (picric acid). Whole sediment toxicity was analyzed by the 10-day survival test with the amphipod Ampelisca abdita, and porewater toxicity tests assessed macro-algae (Ulva fasciata) zoospore germination and germling growth, sea urchin (Arbacia punctulata) embryological development, and polychaete (Dinophilus gyrociliatus) survival and reproduction. Whole sediments spiked with 2,6-DNT were not toxic to amphipods. The fine-grained sediment spiked with tetryl was also not acutely toxic. The tetryl and picric acid LC50 values in the sandy sediment were 3.24 and 144 mg/kg dry weight, respectively. The fine-grained sediment spiked with picric acid generated a U-shaped concentration-response curve in the amphipod test, with increased survival both in the lowest and highest concentration. Grain-size distribution and organic carbon content strongly influenced the behavior of ordnance compounds in spiked sediments. Very low concentrations were measured in some of the treatments and irreversible binding and biodegradation are suggested as the processes responsible for the low measurements. Porewater toxicity varied with its sedimentary origin and with ordnance compound. The sea urchin embryological development test tended to be the least sensitive. Tetryl was the most toxic chemical in all porewater tests, and picric acid the least toxic. Samples spiked with 2,6-DNT contained a degradation product identified as 2-methyl-3-nitroaniline (also known as 2-amino-6-nitrotoluene), and unidentified peaks, possibly degradation products, were also seen in some of the picric acid- and tetryl-spiked samples. Degradation products may have played a role in observed toxicity.     

Comparison of Solar and Geomagnetic Activity Effects on the Northern Hemisphere Weather Changes

The changes of pressure and temperature fields in the winter lower troposphere observed in association with changes in solar and/or geomagnetic activity are compared. It is shown that the fact whether it was solar or geomagnetic activity was not so important as whether the levels of the two activities were high or low. The differences between the effects of solar/geomagnetic activity, however, are revealed, the pressure and temperature data being stratified according to the QBO phase. The relationship obtained are discussed from the viewpoint of mechanisms resting upon both the planetary wave propagation and the changes of atmospheric air currents in the global electric circuit.     

Analysis of State of Stress During The 1997 Earthquake Swarm In Western Bohemia

Focal mechanisms of 70 events of the January 1997 earthquake swarm were analysed using the Gephart and Forsyth method to determine the state of stress in the West Bohemia/Vogtland region and to reveal possible stress variations during the swarm activity. The method was applied to the whole set of 70 focal mechanisms and to several subsets distinguishing magnitudes of events and the spatial and temporal distribution of the swarm. The three representative stress models A ( ₁ ,A: 0/45 (az/dip), ₂ A: 134/35, ₃ A: 243/25), B ( ₁ ,B: 162/38, ₂ B: 263/14, ₃ B: 10/49), and C ( ₁ C: 135/30, ₂ C: 1/50, ₃ C: 239/23) which could characterise the state of stress in the region were found. Model C can be considered to be the most probable stress model because of its consistency with the European stress field. The results of the stress analysis applied to the individual subsets of focal mechanisms indicate that the state of stress was more uniform during the first phase of the swarm. To distinguish between the fault plane and the auxiliary plane of fault plane solutions a statistical approach was used. The results showed that the fault planes striking NW-SE and dipping 45° to NE were activated during the swarm.     

Comparison of Absolute and Relative Moment Tensor Solutions For The January 1997 West Bohemia Earthquake Swarm

Moment tensor solutions for 70 clustered events of the 1997 West Bohemia microearthquake swarm, as calculated by two different methods, are given. The first method is a single-event, absolute moment tensor inversion which inverts body-wave peak amplitudes using synthetic Green functions. The second method is a multiple-event, relative method for which Green functions are reduced to 2 geometrical angles of rays at the sources. Both methods yield similar moment tensors, which can be divided into at least two or three different classes of focal solutions, indicating that, during the swarm activity, different planes of weakness were active. The major source component of most events is a double couple. However, the deviations from the double-couple mechanisms seem to be systematic for some classes of solutions. Error analysis was based on transforming the estimate of the standard deviation of amplitudes extracting from the seismograms into confidence regions of the absolute moment tensor. They show that the non-DC components are significant at a fairly high confidence level.