Inverse kinematic problem for a random gradient medium in geometric optics approximation

Scattering at random inhomogeneities in a gradient medium results in systematic deviations of the rays and travel times of refracted body waves from those corresponding to the deterministic velocity component. The character of the difference depends on the parameters of the deterministic and random velocity component. However, at great distances to the source, independently of the velocity parameters (weakly or strongly inhomogeneous medium), the most probable depth of the ray turning point is smaller than that corresponding to the deterministic velocity component, the most probable travel times also being lower. The relative uncertainty in the deterministic velocity component, derived from the mean travel times using methods developed for laterally homogeneous media (for instance, the Herglotz-Wiechert method), is systematic in character, but does not exceed the contrast of velocity inhomogeneities by magnitude. The gradient of the deterministic velocity component has a significant effect on the travel-time fluctuations. The variance at great distances to the source is mainly controlled by shallow inhomogeneities. The travel-time flucutations are studied only for weakly inhomogeneous media.     

A warm and wet little climatic optimum and a cold and dry little ice age in the southern rocky mountains,U.S.A.

The zenith of Anasazi Pueblo Indian occupation in the northern Colorado Plateau region of the southwestern U.S.A. coincides with the Little Climatic Optimum or Medieval Warm Period (A.D. 900–1300), and its demise coincides with the commencement of the Little Ice Age. Indexes of winter (jet-stream derived) and summer (monsoon derived) precipitation and growing season length were developed for the La Plata Mountains region of southwestern Colorado. The results show that during the height of the Little Climatic Optimum (A.D. 1000–1100) the region was characterized by a relatively long growing season and by a potential dry farming zone or elevational belt (currently located between 2,000 m and 2,300 m elevation) that was twice as wide as present and could support Anasazi upland dry farming down to at least 1,600 m, an elevation that is quite impossible to dry farm today because of insufficient soil moisture. This expanded dry-farm belt is attributable to a more vigorous circulation regime characterized by both greater winter and summer precipitation than that of today. Between A.D. 1100 and 1300 the potential dry-farm belt narrowed and finally disappeared with the onset of a period of markedly colder and drier conditions than currently exist. Finally, when the Little Ice Age terminated in the mid A.D. 1800s and warmer, wetter conditions returned to the region, another group of farmers (modern Anglos) were able to dry farm the area.The U.S. Government right to retain a non-exclusive, royalty-free license in and to any copyright is acknowledged.     

An evaluation of various forms of VAS retrievals in the analysis of a preconvective environment

Summary Quantitative retrievals derived from VISSR Atmospheric Sounder (VAS) radiances are combined with conventional surface and radiosonde data to evaluate the impact of the higher time and space resolution geosynchronous satellite soundings on the diagnosis of a preconvective environment over the central United States on 20 July 1981. Retrievals of temperature, dewpoint temperature, equivalent potential temperature, total column precipitable water, and lifted index, all derived at 60 km resolution over approximately three-hourly intervals, are shown to be physically consistent in space and time and to compare well with available radiosonde data. When VAS fields are used to augment qualitative VAS imagery and analyses from conventional data sources mesoscale regions with convective instability are more clearly delineated prior to the development of convection. The analysis of the VAS retrievals identifies significant spatial gradients and temporal changes in the thermal and moisture fields, especially at times and locations between radiosonde observations. Direct retrievals of vertically integrated bulk precipitable water and lifted index are particularly useful in this case since they correspond well to features in the VAS imagery and provide a strong preconvective signature. The nature of the VAS instrument dictates that these bulk parameters should display more consistency in space and time than the level-specific parameters due to the poor vertical resolution of the VAS instrument. The detailed analyses also point to limitations in using VAS data. Even with nearly optimal conditions for passive remote sounding (generally clear skies, minimal orographic effects, and a rapidly changing moisture field), the VAS retrievals were still degraded in some regions by VAS instrument noise and calibration errors and unresolved cloud contamination. Another problem is the cloud-free nature of the instrument data set, which biases the results toward a drier environment. In spite of these and other limitations, the analyses demonstrate that the geosynchronous VAS can be used in a case study mode to produce high-resolution spatial and temporal measurements which are useful for the quantitative analysis of a cloud-free preconvective environment.With 16 Figures     

The settling behavior and benthic transport of fish feed pellets under steady flows

Settling and erosion experiments were carried out on a size range of fish feed pellets using an annular flume. A strong positive correlation was observed between settling rate and pellet dimension (pellet length, pellet dimeter, and equivalent sedimentation diameter). Erosion thresholds also showed a strong positive correlation with pellet dimensions. Experiments were also carried out to examine the effect of the number of pellets on erosion threshold of two sizes. The results show an asymptotic increase in erosion threshold with increasing number of pellets present, possibly due to sheltering effects. The chemical composition of the pellets was analyzed in terms of water and organic, carbon, and nitrogen contents as well as stable carbon and nitrogen isotopes. The results arising from this study will provide, information regarding potential tracers of waste feed material and help validate model predictions associated with dispersal of waste material.     

Surface wave tomography of the Barents Sea and surrounding regions

The goal of this study is to refine knowledge of the structure and tectonic history of the European Arctic using the combination of all available seismological surface wave data, including historical data that were not used before for this purpose. We demonstrate how the improved data coverage leads to better depth and spatial resolution of the seismological model and discovery of intriguing features of upper-mantle structure. To improve the surface wave data set in the European Arctic, we extensively searched for broad-band data from stations in the area from the beginning of the 1970s until 2005. We were able to retrieve surface wave observations from regional data archives in Norway, Finland, Denmark and Russia in addition to data from the data centres of IRIS and GEOFON. Rayleigh and Love wave group velocity measurements between 10 and 150 s period were combined with existing data provided by the University of Colorado at Boulder. This new data set was inverted for maps showing the 2-D group-velocity distribution of Love and Rayleigh waves for specific periods. Using Monte Carlo inversion, we constructed a new 3-D shear velocity model of the crust and upper mantle beneath the European Arctic which provides higher resolution and accuracy than previous models. A new crustal model of the Barents Sea and surrounding areas, published recently by a collaboration between the University of Oslo, NORSAR and the USGS, constrains the 3-D inversion of the surface wave data in the shallow lithosphere. The new 3-D model, BARMOD, reveals substantial variations in shear wave speeds in the upper mantle across the region with a nominal resolution of 1°× 1°. Of particular note are clarified images of the mantle expression of the continent-ocean transition in the Norwegian Sea and a deep, high wave speed lithospheric root beneath the Eastern Barents Sea, which presumably is the remnant of several Palaeozoic collisions.     

Molecular signature and sources of biochemical recalcitrance of organic C in Amazonian Dark Earths

Amazonian Dark Earths (ADE) are a unique type of soils developed through intense anthropogenic activities that transformed the original soils into Anthrosols throughout the Brazilian Amazon Basin. We conducted a comparative molecular-level investigation of soil organic C (SOC) speciation in ADE (ages between 600 and 8700 years B.P.) and adjacent soils using ultraviolet photo-oxidation coupled with ¹³C cross polarization-magic angle spinning nuclear magnetic resonance (CP-MAS NMR), synchrotron-based Fourier transform infrared-attenuated total reflectance (Sr-FTIR-ATR) and C (1s) near edge X-ray absorption fine structure (NEXAFS) spectroscopy to obtain deeper insights into the structural chemistry and sources of refractory organic C compounds in ADE. Our results show that the functional group chemistry of SOC in ADE was considerably different from adjacent soils. The SOC in ADE was enriched with: (i) aromatic-C structures mostly from H- and C-substituted aryl-C, (ii) O-rich organic C forms from carboxylic-C, aldehyde-C, ketonic-C and quinine-C, and (iii) diverse group of refractory aliphatic-C moieties. The SOC in adjacent soils was predominantly composed of O-alkyl-C and methoxyl-C/N-alkyl-C structures and elements of labile aliphatic-C functionalities. Our study suggests that the inherent molecular structures of organic C due to selective accumulation of highly refractory aryl-C structures seems to be the key factor for the biochemical recalcitrance and stability of SOC in ADE. Anthropogenic enrichment with charred carbonaceous residues from biomass-derived black C (BC) is presumed to be the precursor of these recalcitrant polyaromatic structures. Our results also highlight the complementary role that might be played by organic C compounds composed of O-containing organic C moieties and aliphatic-C structures that persisted for millennia in these anthropic soils as additional or secondary sources of chemical recalcitrance of SOC in ADE. These organic C compounds could be the products of: (i) primary recalcitrant biomolecules from non-BC sources or (ii) secondary processes involving microbial mediated oxidative or extracellular neoformation reactions of SOC from BC and non-BC sources; and stabilized through physical inaccessibility to decomposers due to sorption onto the surface or into porous structures of BC particles, selective preservation or through intermolecular interactions involving clay and BC particles.     

Land-use-mediated <Emphasis Type="Italic">Escherichia coli</Emphasis> concentrations in a contemporary Appalachian watershed

A high-spatial resolution study design was used to investigate the relationship between land use practices, stream physicochemistry, hydroclimate, and stream Escherichia (E) coli concentrations in a mixed-land-use watershed in the Appalachian region. Stream samples were collected daily from six monitoring sites and analyzed for total E. coli counts using an enzyme metabolism indicator method. Statistical comparison of E. coli concentration time series showed significant (p?<?0.05) differences between study sites. Although highest average E. coli concentrations were observed at two agricultural sites (534 and 582 colony-forming counts (CFU) per 100 mL, respectively), highest total loadings were observed within the receiving stream, with values increasing downstream (2?×?10¹² and 4.2?×?10¹² study total CFU for bracketed upstream and downstream sites, respectively). No single physical variable displayed a significant correlation (p?<?0.05) with observed E. coli concentration at every site. However, sites displayed different patterns of significant correlations (p?<?0.05) between E. coli concentration and both physicochemical (e.g. pH, dissolved oxygen saturation) and hydroclimate variables (e.g. streamflow and precipitation). Percent agricultural land cover was the only land use category that showed significant (p?<?0.04) correlation with study average E. coli concentrations, thereby emphasizing the importance of land use practices to stream pathogen regimes. Results validate the analytical method and provide high-resolution, detailed, quantitative characterizations of stream E. coli regimes, thereby supplying land and water resource managers with science-based information to advance management decisions and improve public health.