藻型湖区氧化亚氮排放特征及其影响因素

湖泊等内陆水体是大气N₂O潜在的重要排放源,也是全球N₂O收支估算的重要组成部分。目前全球湖泊普遍面临富营养化和蓝藻暴发等问题,明晰藻型湖泊N₂O排放强度及其环境影响因子对准确估算湖泊N₂O排放和预测其未来变化至关重要。本研究选择太湖藻型湖区为研究对象,同时选取人为活动影响较小的湖心区作为对比区域,基于2011年8月至2013年8月为期2年的逐月连续观测,探讨藻型湖区N₂O排放特征及其影响因素。结果表明,藻型湖区呈现极强的N₂O排放,其排放通量为(4.88±3.05) mmol/(m²·d),是参考区域(湖心:(2.10±4.31) mmol/(m²·d))的2倍多。此外,在藻型湖区中不同点位N₂O排放差异显著,受河流外源输入影响,近岸区是N₂O的热点排放区,其年均排放通量高达10.93 mmol/(m²·d)。连续观测表明N₂     

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砂土高压蠕变微观机理分析

砂土层在地面沉降过程中呈现一定的蠕变特性。文章采用一维压缩试验对4 MPa 下砂土的变形特征进行了研究,并 采用改进的试验装置对砂土的微观结构进行了提取。通过对8 组不同级配砂土样的蠕变特性和微观结构分析,得到如下结 论：粒径单一的砂土在蠕变过程中更容易出现突变,砂粒受力后更容易发生破碎,产生滑移错动;砂土蠕变的蠕变量与砂 粒级配密切相关,砂土的粒径越单一且粒径越大时,砂土的蠕变量也越大;采用表征砂土颗粒形状复杂程度的形状系数, 从微观上定量分析了砂土在蠕变过程中发生破碎的情况和蠕变量大小,且形状系数越小,表明该种砂土形状越复杂,在蠕 变过程中砂土的破碎性越高,蠕变量越大。     

赤峰托河盆地流纹岩年代学、地球化学特征及其地质意义

赤峰托河火山盆地位于大兴安岭南端内蒙古赤峰市克什克腾旗境内,处于西拉木伦河-长春缝合带以南、康宝-围场-赤 峰-开源断裂带以北的辽源地块,盆地中的长英质火山岩系角度不整合于下二叠统额里图组、于家北沟组之上,并被新近系汉诺 坝组玄武岩不整合覆盖。SHRIMP 锆石U-Pb年龄表明,盆地火山岩系中流纹岩锆石的206Pb/238U年龄为158.5±1.3 Ma,属晚侏罗 世早期岩浆活动的产物,应归入新民组。托河流纹岩具有较高的SiO2含量（68.6%~72.6%）,A/CNK值<1.1,标准矿物刚玉的含量< 1%;ΣREE含量较高,轻稀土富集,负铕异常显著;(87Sr/86Sr)i= 0.709244~0.713168,εNd(t)=-8.76~-8.42,TDM2=1656~1629Ma,(206Pb/ 204Pb)i=17.271~17.326,(207Pb/204Pb)i=15.401~15.413,(208Pb/204Pb)i=37.614~37.696,δ18OV-SMOW=4.1‰~4.5‰。经对比托河盆地流纹岩与 红山子盆地、芝瑞盆地流纹岩、流纹斑岩,它们主量元素、微量元素和Sr-Nd-Pb-O同位素地球化学特征基本一致,指示各盆地的 物质来源相同。文章证实赞同前人提出的物质来源既与地壳（特别是下地壳）有关,也与地幔特别是EMI型地幔有关的观点。在 (Yb+Ta)-Rb和Y-Nb图解上,托河盆地流纹岩均显示板內拉张的构造环境。类比红山子盆地的岩石组合、地质时代、同位素组 成、铀矿化特征等,提出托河盆地条件更优越,认为今后盆地内的铀矿勘查工作可参照红山子铀钼矿床的模式开展。     

CICE5.0与BCC_CSM2.0模式的耦合及对北极海冰的模拟评估

本文将美国Los Alamos国家实验室发展的最新海冰模式CICE5.0引入国家气候中心气候系统模式BCC_CSM2.0,替代原有的海冰模式SIS,形成一个新的耦合模式。在此基础上,评估新耦合模式对1985-2009年北极海冰的模拟性能,检验引入CICE5.0后对耦合模式中北极海冰、海洋和大气模拟结果的改进。结果表明,引入CICE5.0后,模式能较好地模拟出北极海冰的空间分布、季节以及年际变化特征。相比于旧版本耦合模式,新耦合模式模拟的北极多年冰增多、一年冰减少,同时,海冰增厚、海冰流速减慢,模拟效果得到显著改进,对波弗特涡流模拟的改善尤为明显。进一步分析发现,相比于SIS,CICE5.0对北极海冰特别是海冰厚度模拟性能的提升,在耦合进入BCC_CSM2.0后,会触发冰-温的正反馈机制,改进了模式对海平面气压场、表层气温和海表温度的模拟,由此进一步提高了模式对北极海冰的模拟能力。     

长江口邻近海域沉积物和间隙水中硅的研究

以2011年6月和8月在长江口邻近海域采集的沉积物和间隙水样品为研究对象,讨论了沉积物中生物硅（BSi）和间隙水中溶解硅（DSi）的分布情况和影响因素,并初步探讨了生物硅的循环和保存。结果表明,表层沉积物中BSi的含量较低,且均小于1%。柱状沉积物中BSi的含量范围为0.34%~0.52%。C3、D1站位柱状沉积物中BSi的记录主要是由早期成岩过程控制,33#站位的分布特征主要是由水动力等变化控制。沉积物间隙水中DSi的浓度范围为101.6~263.9 μmol/L,低于纯BSi的溶解度;间隙水的pH值越大,沉积物的含水率越低,还原性越强,间隙水中DSi的含量越高。3站位生物硅的埋藏效率均较高,表明长江口邻近海域是潜在的硅的汇。沉积通量的分布与沉积速率和埋藏效率的分布一致,均有近岸高于远海的趋势。     

三峡库区范家坪滑坡地表形变InSAR监测与综合分析

位于湖北省秭归县的范家坪滑坡是长江三峡库区干流上的大型岩质滑坡之一。阐述了高分辨率合成孔径雷达干涉测量技术(InSAR)监测滑坡地表形变的工作方法与技术体系,采用22景3m空间分辨率的TerraSAR-X数据,辅以人工反射体布设和GPS测量,对范家坪滑坡变形进行监测,发现滑坡处在缓慢匀速变形状态,其谭家河滑坡体的形变比木鱼包滑坡体更为强烈,形变最大处的雷达视线向形变速率达到300mm/a。通过综合分析滑坡区2012年大气降雨和长江水位资料,发现年度内范家坪滑坡变形受水位变化和大气降雨影响微弱。     

Dye adsorption on electrochemical exfoliated graphene oxide nanosheets: pH influence,kinetics and equilibrium in aqueous solution

Graphene oxide nanosheets were synthesized by electrochemical exfoliation. X-ray diffraction, scanning electron microscopy, atomic force microscopy, Raman spectrometry and Fourier transform infrared spectrometry were used to characterize crystal structure, particle size, thickness and function groups of the nanosheets. The nanosheets were examined for adsorption of methyl orange, an anionic dye, in aqueous solution at different pHs and temperatures. The maximum adsorption capacity of methyl orange on graphene oxide nanosheets obtained from the Langmuir isotherm was 138.69 mg/g at pH 2.0, which is larger than that of other carbonaceous adsorbents. The large adsorption affinity of graphene oxide nanosheets to methyl orange might be due to the presence of hydrogen bonding and π–π interaction between methyl orange and graphene oxide nanosheets. Adsorption kinetics followed a pseudo-second-order kinetic model, and the isotherm adsorption results were fitted with Langmuir isotherm model in a monolayer adsorption manner. The thermodynamic studies indicated that the adsorption reaction was a spontaneous physisorption process.     

The diagenetic geochemistry and contamination assessment of iron,cadmium, and lead in the sediments from the Shuangtaizi estuary,China

Sediment and pore water samples have been collected from the coastal tidal flat in the Shuangtaizi estuary, China, in order to investigate the geochemical behavior of iron, cadmium, and lead during diagenesis and to assess the degree of contamination. The calculated enrichment factors and geoaccumulation indices for separate elements show that anthropogenic activities have had no significant influence on the distribution of Fe and Pb in the study area, whereas the distribution of Cd has been closely influenced in this way. The high percentage of exchangeable Cd (average of 56.34%) suggests that Cd represents a potential hazard to benthic organisms in the estuary. The calculated diffusive fluxes of metals show that the most mobilized metal is Fe (9.22 mg m^?2 a^?1), followed by Cd (0.54 mg m^?2 a^?1) and Pb (0.42 mg m^?2 a^?1). Low Fe²⁺ contents in surface pore water, alongside high chromium-reducible sulfur contents, and low acid-volatile sulfur, and elemental sulfur contents at 0–25 cm depth in sediments show that Fe²⁺ is formed by the reduction of Fe oxides and is transformed first to a solid phase of iron monosulfides (FeS) and eventually to pyrite (FeS₂). The release of adsorbed Pb due to reductive dissolution of Fe/Mn oxides during early diagenesis could be a source of Pb²⁺ in pore water. From the relatively low total organic carbon contents measured in sediments (0.46–1.28%, with an average of 0.94%) and the vertical variation of Cd²⁺ in pore water, sulfide or Fe/Mn oxides (instead of organic matter) are presumed to exert a significant influence on carrying or releasing Cd by the sediments.     

A distributed parameter model of a frame pin‐supported wall structure

Many reinforced‐concrete frames collapse via a soft‐story mechanism during severe earthquakes. Such collapses are mainly attributed to concentrated deformation in a soft story. Deformation control is thus important in preventing collapse. The frame pin‐supported wall structure is a type of rocking structure that releases constraints at the bottom of the wall. Previous research has obtained good results for the deformation control of this type of structure. However, the interior forces and strength demands of the pin‐supported wall have not been systematically explored. In this paper, a distributed parameter model is developed to investigate the strength demand of the wall in a frame pin‐supported wall structure. In the model, the pin‐supported wall is simplified as a bending beam and the frame is simplified as a shear beam. The two beams are joined by distributed shear connectors, so that the shear force can be transferred at any location on the interface. The model can be solved using differential equations based on equilibrium and compatibility. The accuracy of the model is verified using SAP2000 (Computers and Structures Inc., Berkeley, CA, USA). Displacement distribution of the structure and distributions of the moment and shear force within the pin‐supported wall are obtained for two typical external force profiles. It is found that the pin‐supported wall can effectively reduce the drift concentration factor. Distributions of the displacement, moment, and shear force are closely correlated with the relative stiffness of the wall and frame. Finally, recommendations on the stiffness and strength of a pin‐supported wall are made. Copyright © 2015 John Wiley & Sons, Ltd.