Insights from fluid inclusions, thermal and PVT modeling for paleo-burial and thermal reconstruction of the Córdoba petroleum system (NE Mexico)

Carbonate reservoirs in the Córdoba petroleum system (NE Mexico) passed through a multiphase deformation history complicating the petroleum geology. The area evolved from passive margin and foreland setting to Laramide fold and thrust belt (FTB) that was subsequently buried below the Tertiary-Quaternary Veracruz Basin, which in turn underwent transpressional deformation. Reconstruction of paleo-burial (erosion) and paleo-thermicity through the different zones of the FTB and adjacent foreland is a challenging task since classical calibration tools fail to discriminate between several kinematic and thermal models. In this study results from detailed diagenetic and fluid inclusion (FI) analyses on carbonates from the western part of the Córdoba Platform helped constraining paleo-thermicity. Combined microthermometry, synchrotron FTIR analyses and PVT modeling of cogenetic hydrocarbon-aqueous FI allowed also calculation of absolute pressures. Thermal modeling exercises calibrated with organic maturity parameters, bottom-hole temperatures or temperatures from FI demonstrate that without controlling also paleo-erosion the model results may be misleading.     

Unforeseen importance of historical collections as baselines to determine biotic change of coral reefs: the Saba Bank case

Botanical and zoological collections may serve as archives for historical ecological research on the effects of global change and human impact on coral reef biota. Museum collections may harbour old specimens of reef‐dwelling species that have become locally extinct. Such collections also help to determine whether early records of invasive species can be obtained from times when they were not yet recognized as such. A case study (2006) involving Saba Bank, Caribbean Netherlands (former Netherlands Antilles), suggests that the coral reef fauna here may have become impoverished when compared with data obtained during an earlier expedition in 1972. However, the 1972 sampling may have been incomplete, as it was performed by professional divers who were not trained taxonomists, whereas the collecting in 2006 was done by experienced marine biologists who knew the taxa they were sampling. As Saba Bank has been under stress due to the anchoring of large vessels, and invasive species have been a potential threat as well, future studies are needed to obtain more insights into the changing reef biota of Saba Bank. Using this Saba Bank example, we want to address the importance of natural history collections as reservoirs of valuable data relevant to coral reef biodiversity studies in a time of global change. As such, these collections are still underexplored and underexploited.     

一种中国南海海绵Xestospongia testudinaria中化学成分的研究

综合运用正相和反相硅胶柱层析、Sephadex LH-20凝胶柱层析以及制备HPLC等分离方法,从1种中国南海海绵Xestospongia testudinaria中追踪分离抗肿瘤活性次级代谢产物。从95%乙醇提取物中分离获得8个单体化合物,通过NMR,MS等波谱技术鉴定其结构分别为:E-18,18-二溴-9,17-二烯-5,7-二炔硬脂酸甲酯(1),E-18,18-二溴-9,17-二烯-5,7-二炔硬脂酸乙酯(2),麦角甾-5,7,22-三烯-3-醇(3),麦角甾-4,6,8(14),22-四烯-3-酮(4),胆甾-4-烯-3-酮(5),3-吲哚醛(6),3-吲哚酸(7)和5-吲哚醛(8)。其中,化合物2-5和8为首次从该属海绵中分离得到。化合物1对肿瘤细胞株HCT116和A549显示较强的抑制活性。     

Use of remote sensing to document changes in marsh vegetation following the Amoco Cadiz oil spill (Brittany, France, 1978)

Image analysis of historical aerial photographs was used to examine the effects of the Amoco Cadiz oil spill and resulting clean-up on marsh ecology. Two heavily oiled marsh systems were compared. The marsh which received no clean-up recovered to its prior condition. The marshes in the system cleaned by sediment removal were extensively altered as a result of changes in intertidal height of the sediment surface.     

Satellite Measurements of Albedo and Radiant Temperature from Semi-Desert Grassland along the Arizona/Sonora Border

Along the international border separatingthe U.S. (Arizona) and Mexico (Sonora), differencesin the grazing intensity of domestic livestock arecommonly presumed to have created a large differencein vegetation cover between the two countries. Thisvegetation difference is reportedly responsible for anextensive albedo and temperature discontinuity thatmay be affecting regional climate. In this study, weused Landsat Thematic Mapper data to examinetrans-border differences in these two biophysicalparameters. Albedo and radiant temperature estimateswere computed for 25 km-long (east-west) transectsthrough semi-desert grassland on each side of theborder at two different times of year. Only smallaverage trans-border differences in these parameterswere found, and in some cases average albedo andtemperature data were essentially equal on each sideof the border. In addition, we found significantspatial heterogeneity in conditions on both sides ofthe border. These results suggest that, based on asmall sample, it may be difficult to assess whetherthere are significant differences in biophysicalproperties of semi-arid grassland between Arizona andMexico in the vicinity of the border. We concludethat more extensive spatial and temporal sampling iscritical in assessing any possible trans-borderdifferences in average terrain conditions that mightaffect climate, and that this data must be coupledwith more extensive meteorological data to assesswhether a difference in climate also exists.     

A Compilation of Silicon and Thirty One Trace Elements Measured in the Natural River Water Reference Material SLRS-4 (NRC-CNRC)

The natural river water certified reference material SLRS-4 (NRC-CNRC, National Research Council-Conseil National de Recherches Canada) has been routinely analysed for major and trace elements by six French laboratories. Most measurements were made using inductively coupled plasma-mass spectrometry. For silicon and thirty one trace elements (rare earth elements, Ag, B, Br, Cs, Ga, Ge, Li, P, Pd, Rb, Se, Th, Ti, Tl, W, Y and Zr), no certified values are assigned by NRC-CNRC. We propose some compilation values and related uncertainties according to the results obtained by the different laboratories.     

The 1783 Lakagigar eruption in Iceland: geochemistry,CO2 and sulfur degassing

About 12.3 km³ of basaltic magma were erupted from the Lakagigar fissure in Iceland in 1783, which may have been derived from the high-level reservoir of Grimsvotn central volcano, by lateral flow within the rifted crust. We have studied the petrology of quenched, glassy tephra from sections through pyroclastic cones along the fissure. The chemical composition of matrix glass of the 1783 tephra is heterogeneous and ranges from olivine tholeiite to Fe–Ti rich basalt, but the most common magma erupted is quartz tholeiite (Mg#43.6 to 37.2). The tephra are characterized by low crystal content (5 to 9 vol%). Glass inclusions trapped in plagioclase and Fo₈₆ to Fo₇₅ olivine phenocrysts show a large range of compositions, from primitive olivine tholeiite (Mg#64.3), quartz tholeiite (Mg#43–37), to Fe–Ti basalts (Mg#33.5) which represent the most differentiated liquids and are trapped as rare melt inclusions in clinopyroxene. Both matrix glass and melt inclusion data indicate a chemically heterogeneous magma reservoir, with quartz tholeiite dominant. LREE-depleted olivine-tholeiite melt-inclusions in Mg-rich olivine and anorthitic-plagioclase phenocrysts may represent primitive magma batches ascending into the reservoir at the time of the eruption. Vesicularity of matrix glasses correlates with differentiation, ranging from 10 to 60 vol.% in evolved quartz-tholeiite glasses, whereas olivine-tholeiite glasses contain less than 10 vol.% vesicles. FTIR analyses of olivine-tholeiite melt-inclusions indicate concentrations of 0.47 wt% H₂O and 430 to 510 ppm for CO₂. Chlorine in glass inclusions and matrix glasses increases from 50 ppm in primitive tholeiite to 230 ppm in Fe–Ti basalts, without clear evidence of degassing. Melt inclusion analyses show that sulfur varies from 915 ppm to 1970 ppm, as total FeO^* increases from 9 to 13.5 wt%. Sulfur degassing correlates both with vesicularity and magma composition. Thus sulfur in matrix glasses decreases from 1490 ppm to 500 ppm, as Mg # decreases from 47 to 37 and vesicularity of the magma strongly increases. These results indicate loss of at least 75% of sulfur during the eruption. The correlation of low sulfur content in matrix glasses with high vesicularity is regarded as evidence of the control of a major exsolving volatile phase on the degassing efficiency of the magma. Our model is consistent a quasi-permanent CO₂ flux through the shallow-level magmatic reservoir of Grimsvotn. Following magma withdrawal from the reservoir and during eruption from the Lakagigar fissure, sulfur degassing was controlled by inherent CO₂-induced vesicularity of the magma.     

Relative stabilities of sedimentary rearranged sterenes as calculated by molecular mechanics: a key to unravel further steroid diagenesis

Molecular mechanics calculations of rearranged cholestenes revealed that diacholest-13(17)-enes with 10α stereochemistry are more stable than their 10β counterparts and that a partly rearranged sterene with a Δ⁸ double bond and 10β, 14β stereochemistry (compound 7) is relatively stable at thermodynamic equilibrium. The calculated data are in good agreement with sedimentary and experimental data and thus reinforce recent propositions for early-stage diagenesis of steroids.     

A Method to Represent a Well in a Three-Dimensional Discrete Fracture Network Model

In discrete fracture network (DFN) modeling, fractures are randomly generated and placed in the model domain. The rock matrix is considered impermeable. Small fractures and isolated fractures are often ignored to reduce computational expense. As a result, the rock matrix between fractures could be large and intersections may not be found between a well introduced in the model and the hydraulically connected fracture networks (fracture backbones). To overcome this issue, this study developed a method to conceptualize a well in a three-dimensional (3D) DFN using two orthogonal rectangular fractures oriented along the well's axis. Six parameters were introduced to parameterize the well screen and skin zone, and to control the connectivity between the well and the fracture backbones. The two orthogonal fractures were discretized using a high-resolution mesh to improve the quality of flow and transport simulations around and along the well. The method was successfully implemented within dfnWorks 2.0 (Hyman et al. 2015) to incorporate a well in a 3D DFN and to track particles leaving an injection well and migrating to a pumping well. Verification of the method against MODFLOW/MODPATH found a perfect match in simulated hydraulic head and particle tracking. Using three examples, the study showed that the method ensured the connectivity between wells and fracture backbones, and honored the physical processes of flow and transport along and around wells in DFNs. Recommendations are given for estimating the values of the six introduced well parameters in a real-world case study.     

Small-scale coexistence of island-arc- and enriched-MORB-type basalts in the central Vanuatu arc

We report here major, trace element and Sr–Nd–Pb isotopic data for a new set of basaltic lavas and melt inclusions hosted in Mg-rich olivines (Fo_86–91) from Mota Lava, in the Banks islands of the Vanuatu island arc. The results reveal the small-scale coexistence of typical island-arc basalts (IAB) and a distinct type of Nb-enriched basalts (NEB) characterized by primitive mantle-normalized trace element patterns without high-field-strength element (HFSE) depletion. The IAB show trace element patterns with prominent negative HFSE anomalies acquired during melting of mantle sources enriched with slab-derived, H₂O-rich components during subduction. In contrast, the NEB display trace element features that compare favourably with enriched-mid-ocean ridge basalt (MORB) and the most enriched basalts from the Vanuatu back-arc troughs. Both their trace element and Nd–Sr isotopic compositions require partial melting of an enriched-MORB-type mantle source, almost negligibly contaminated by slab-derived fluids (~0.2 wt%). The coexistence of these two distinct types of primitive magma, at the scale of one volcanic island and within a relatively short span of time, would reflect a heterogeneous mantle source and/or tapping of distinct mantle sources. Direct ascent of such distinct magmas could be favoured by the extensive tectonic setting of Mota Lava Island, allowing decompression melting and sampling of variable mantle sources. Significantly, this island is located at the junction of the N–S back-arc troughs and the E–W Hazel Home extensional zone, where the plate motion diverges in both direction and rate. More broadly, this study indicates that crustal faulting in arc contexts would permit basaltic magmas to reach Earth’s surface, while preserving the geochemical heterogeneity of their mantle sources.