Carbohydrates in recent marine sediments—II. Occurrence and fate of carbohydrates in a recent stromatolitic deposit: Solar Lake,Sinai

In a study on the diagenesis of carbohydrates in a recent stromatolitic deposit (Solar Lake, Sinai) monosaccharides are quantitated after mild acid hydrolysis and gas chromatographic analysis as alditol acetates. From the depth profiles of the individual monosaccharides relative to the total organic carbon three categories of carbohydrates can be distinguished. The behaviour of the various categories upon burial is discussed in terms of their potential to become a part of the organic matter that survives geological periods. The distribution patterns of especially the mono-O-methyl monosaccharides at various depths are characteristics for the bacterial communities present in the corresponding parts of the sediment column.     

Shallow seismicity at Montagne Pelée volcano,Martinique, Lesser Antilles

Continuous seismic monitoring at Martinique since the 1902 eruption of the Montagne Pelée volcano did not detect local earthquakes for the first 70 years. For the only eruption which occurred in this time span in 1929 the seismograph was 20 km away and of a standard type, not particularly suited for the detection of small-scale local seismicity. Improvement of the monitoring array over the last 15 years with the installation of sensors on the volcano itself allowed the detection of signals of local origin which were interpreted as being due to surface sources, such as rockfalls and landslides. Since December 1985 seismic sources in the volcano itself, i.e. small earthquakes at shallow depth, were identified and located with the aid of a temporary upgrading of the array close to these weak sources. Such an onset of local seismicity could not have been detected with previous seismic equipment; such episodes of seismicity in the volcano might have occurred in the past, apparently quiescent history of the volcano as the reinterpretation of seismograms of some events in 1976 would indicate, without evolving to more important volcanic phenomena. For seismographs on volcanoes the constant upgrading of observation capabilities is certainly perferred to a strict continuity of standard observations.     

Syntectonic subaqueous mass flows of the Neoproterozoic Otavi Group,Namibia: where is the evidence of global glaciation?

The thick (>1 km) Neoproterozoic Otavi Group of Namibia accumulated after ca. 760 Ma along >700 km of the faulted margin of the Congo Craton. The margin shows a north to south, downbasin transition from a shallow‐water carbonate shelf (Otavi Platform) to offshore deepwater slope (Outjo Basin). Within the latter, the Abenab and Tsumeb Subgroups contain large volumes of poorly sorted breccias, conglomerates and diamictites composed principally of locally derived carbonate. Diamictite facies were reported in the 1930s as tillites left by an ice sheet (although the absence of striated clasts and other key glacial indicators was viewed as problematic). Later workers rejected a glacial origin concluding that Outjo basin facies were deposited as parts of prograding submarine wedges built by mass flows during active rifting. Recently, the Snowball Earth hypothesis has returned to the earlier glacial interpretation; arguing that these strata represent a record of extraordinary late Neoproterozoic glacial and interglacial climates when global temperatures fluctuated by up to 100°C. Facies analysis of breccias, diamictites, conglomerates and sandstone strata of the Otavi Group identifies them as genetically related, subaqueously deposited sediment gravity flows. They lack diagnostic indicators of any one specific climate in source areas. These facies were all deposited in deepwater at the foot of landslide‐prone scarp blocks where debris flows and turbidity currents moved large volumes of coarse, freshly broken carbonate debris produced by faulting. Breccias, diamictites, conglomerates and sandstones occur in composite fining‐ and thinning‐upward bundles that are directly analogous to those reported from many other faulted margins in the Phanerozoic stratigraphic record. These rocks provide no clear sedimentological signature of a glacial source or catastrophic Snowball Earth‐type temperature fluctuations. Instead, they point to a dominant tectonic control on sedimentation related to faulting along the margin of the Congo Craton.     

根据天气类型划分欧洲中期天气预报中心的集合预报产品

该研究的主要目的是找出一种对集合预报产品进行释用的新方法。其基本假定是集合预报要素在一定程度上代表了未来可能发生的天气形势。为了解决天气尺度在中期预报的不可预报性问题 ,引入了天气类型的概念。对集合预报进行划分的方法是 Diday提出的动力模糊法 ,初始划分时的重心由天气类型定义 ,划分用到的距离是位移和最大相关方法。根据城市块 (City- Block)距离找出了影响中国的按冬夏两季划分的天气类型 ,初步划分结果表明 ,欧洲中期天气预报中心的集合预报系统可以预报出横槽转竖型天气类型的演变情况 ,在夏天的预报效果则没有冬天好。     

A quantitative evaluation of Playfair's law and its use in testing long‐term stream erosion models

Playfair's law (J. Playfair, illustrations of the Huttonian Theory of the Earth, 1802) requires any two tributaries in a river network to lower at the same rate near their junction. Although this law holds exactly at the junction, it is unclear how well it holds in the vicinity of the junction. This issue has practical importance because Playfair's law has been used to estimate parameters for detachment‐limited models of erosion. If the incision rate of a stream is modelled as βA^mSⁿ, where β is an erodibility parameter, A is the area drained by the stream, and S is the local gradient of the channel, then the ratio of the parameters m/n can be estimated from junctions by assuming that Playfair's law holds over the distance used to determine S for each tributary. In this paper, Playfair's law and associated m/n estimates are evaluated for simulated basins with constant and temporally varying uplift rates (or baselevel lowering rates). The results demonstrate that estimates of m/n may be biased for basins with upward‐concave stream profiles because the local slope must be approximated with an average upstream slope. In addition, when uplift rate varies temporally, knickpoints are shown to travel through the basins with constant vertical velocity. Because incision rates vary within the basin, Playfair's law only holds exactly at the junctions. These effects are more important when slopes are measured over longer distances. Finally, measurement techniques are presented which address these potential biases. Copyright © 2001 John Wiley & Sons, Ltd.     

Trace metals in acid sediments and waters, Pimpama catchment, southeast Queensland, Australia

The Pimpama River floodplain has developed over the last several thousand years as a result of sea-level fluctuations that shaped the lower catchment and enabled the formation of sedimentary pyrite. The subsequent production of sulfuric acid due to the oxidation of this pyrite enhances the breakdown of metal-bearing sediments and can lead to leaching of major and trace metals into the waters of the region. The seasonal pattern of rainfall and current land-use activities are important aspects that intensify the natural production of acid and influence the release and distribution of metals. To identify the source and migration of metals in the Pimpama catchment and to understand the impact of pyrite oxidation on the distribution of metals in sediments and waters, several components of the drainage system were analyzed: bedrock, sediments from river bed and bank, and water. The elements analyzed in this study (V, Cr, Co, Ni, Cu, Zn and Pb) are all present in the bedrock material which explains their occurrence in the unconsolidated sediments of the floodplain. These metals concentrate in the upper section of the sedimentary sequence and their presence is related to clay minerals such as smectite, organic matter and iron phases. However, Zn, Mo and Co occur in higher amounts than the local background and within standard shale. This comparison suggests that the diagenetic processes alone cannot explain the higher concentrations and it is concluded that these metals also have an anthropogenic source. The formation of sulfuric acid creates conditions for higher mobility of some metals, such as Cr, Co, Ni, Cu, Zn, but does not affect less mobile ones such as Mo and Pb. Over the longterm, the production of acid influences the breakdown of mineral phases and enhances the process of weathering. Over the short term, every rain event leaches acid from sediments and mobilizes metals resulting in a substantial reduction in the quality of river water. Received: 2 October 1998 · Accepted: 16 February 1999     

Two-dimensional modelling of some CFC replacement compounds

The Cambridge 2-D Eulerian model has been used to study the potential atmospheric distributions and lifetimes of a number of CFC replacement compounds and their degradation products. The study has focused on HFC 134a and HCFCs 123, 141b and 142b and the major products formed by their atmospheric degradation. The loss of these compounds and their products by hydroxyl radical attack, photolysis and in-cloud hydrolysis have been investigated. The study has shown that HCFCs 141b and 142b have sufficiently long lifetimes to enter the stratosphere in significant quantities, where degradation leads to an increase in the total stratospheric chlorine concentration. The study has also highlighted areas where further experimental work would be valuable, in particular characterisation of the product channels for the degradation reactions and determination of the removal rates of the products in the aqueous phase.     

ISO Far-IR spectroscopy of IR-bright galaxies and ULIRGs

Based on far-infrared spectroscopy of a small sample of nearbyinfrared-bright and ultraluminous infrared galaxies (ULIRGs) with theISO Long Wavelength Spectrometer we find adramatic progression in ionic/atomic fine-structure emission line andmolecular/atomic absorption line characteristics in these galaxiesextending from strong [O III]52,88 m and [N III]57 m lineemission to detection of only faint [C II]158 m line emissionfrom gas in photodissociation regions in the ULIRGs. The molecularabsorption spectra show varying excitation as well, extending fromgalaxies in which the molecular population mainly occupies the groundstate to galaxies in which there is significant population in higherlevels. In the case of the prototypical ULIRG, the merger galaxy Arp220, the spectrum is dominated by absorption lines of OH, H₂O, CH,and [O I]. Low [O III]88 m line flux relative to the integratedfar-infrared flux correlates with low excitation and does not appear tobe due to far-infrared extinction or to density effects. A progressiontoward soft radiation fields or very dusty H II regions may explainthese effects.