Geothermal energy

The potential of a geothermal area is primarily dependent on volume and temperature of the reservoir and adequacy of fluid supply. Inadequate fluid supply may be a more common limiting factor than inadequate heat supply, for heat stored in the upper 10,000 ft of many hot spring systems is 1,000 to 10,000 times their annual natural heat flow. Except in very porous reservoirs, most of this heat is stored in rocks rather than in pore fluids. Geothermal fields can be classified as hot spring systems or as deep insulated reservoirs with little surface expression; gradations also exist. Hot spring systems have high near-surface permeability, at least locally on faults and fractures, permitting fluids to escape at high rates. Owing to vigorous circulation and escaping fluids and heat, near-surface temperatures are high, but temperatures deep in the system are lower than would prevail with inhibited escape. Deep reservoirs with little surface expression require permeable reservoir rocks capped by insulating rocks of low permeability. Larderello, Italy, and Salton Sea, California, have slight leakage, but others may have no leakage. Liquid water, which can be at temperatures far above 100° C because of existing pressures, is generally the dominant fluid. Steam can form by boiling as hot water rises to levels of lower pressure. However, in several explored systems the heat supply is so high and rate of discharge of water so low that steam exists even deep in the system. Dry steam areas are probably rare. About 30 areas in the United States have been explored for geothermal energy, but dry steam has been proved only at « The Geysers ». Extensive utilisation of geothermal energy must therefore depend largely upon steam « flashed » from hot water with decrease in pressure. Problems that confront broad utilisation of geothermal energy include: 1) discovery of reservoirs with adequate supply of energy and natural fluids; 2) deposition of CaCO; or SiO₂; 3) chemical corrosion; 4) objectionable chemicals in some effluents; and 5) inapplicability of existing public laws. The optimum environment for a geothermal reservoir includes:

1. 1.
   Potent source of heat, such as a magma chamber. A depth of at least two miles provides enough pressure to insure water of high temperature; 5 miles may be too deep for effective transfer of heat to circulating water. Such heat sources are most likely to occur in regions of late Cenozoic volcanism.     

Deep geothermal brine near Salton Sea,California

A well drilled for geothermal power near Salton Sea in Imperial Valley, Calif., is 5,232 feet deep; it is the deepest well in the world (1962) in a high-temperature hot spring area. In the lower half of the hole temperatures are too high to measure with available equipment, but are at loast 270°C, and may be as much as 370°C. For comparison, maximum temperature heretofore reported at depth (1962) for hot spring areas is 295°C. The well taps a very saline brine of Na-Ca-K-Cl type (about 185,000 ppm Cl) with exceptionally high potassium, and with the highest content of minor alkali elements known for natural waters; Fe, Mn, Zn, Pb, Cu, Ag, and some other metals are also exceptionally high. This brine may be connate, but present evidence favors a source in the magma chamber at depth that supplied late Quaternary rhyolite domes of the area. If the latter is correct, the brine is an undiluted magmatic water that is residual from the separation of a more volatile phase high in CO₂, H₂S, and with some alkali halides. Elsewhere, the hypothesized volatile phase may account for near-surface hot spring activity of most thermal areas of volcanic association. The residual brine of high salinity may ordinarily remain relatively deep in the volcanic systems because of high specific gravity and low content of volatiles, seldom appearing at the surface except in a greatly diluted form. The hot springs of Arima, Japan, may be a rare example of this type of magmatic water discharging at the surface in moderate concentration (Cl as much as 42,000 ppm). Independent evidence from fluid inclusions in minerals of high-temperature base-metal deposits also favors the existence of magmatic water high in Na, Ca, and Cl, and low in CO₂ and other volatile components. During a three-month production test several tons of material precipitated in the horizontal discharge pipe from the well. Amorphous silica with iron and manganese, and bornite are the dominant recognized components. This material contains the astonishingly high contents of about 20 percent copper, 2 percent silver, and notable sulfur, arsenic, bismuth, lead, antimony, and some other minor elements. Total quantities of all elements in the original whole brine are not yet known, but calculated amounts corresponding to 1 to 3 ppm of copper and 0.1 to 0.3 ppm of silver were precipitated from the brine to form the pipe deposits. The brine, therefore, may be man’s first sample of an « active » ore solution. Equally fascinating to many geologists is the possibility that in the lower part of the hole temperatures are so high and pressures are sufficient for young sedimentary rocks to be undergoing transformation into rocks with mineral assemblages of the greenschist facies of metamorphism. Drill cores from 4,400 to 5,000 feet in depth contain chlorite, albite, K-feldspar, epidote, mica, and quartz, with some indication of increase in metamorphic grade downward. Regional geological and geophysical studies favor a depth of about 20,000 feet to pre-Tertiary basement rocks in the general area. A shallow basement or local upfaulting of old metamorphic rocks are not likely possibilities for the thermal area.     

Determination of chlorine concentrations in whole rock: Comparison between prompt-gamma activation and isotope-dilution AMS analysis

Accurate determination of chlorine concentrations in terrestrial rocks is of importance for the interpretation of terrestrial in-situ cosmogenic ³⁶Cl. Neutron capture by ³⁵Cl, together with production from Ca and K, is one of the three major production pathways of ³⁶Cl in rocks. Here, we present an inter-comparison of chlorine determinations by two procedures. The first approach is an independent Cl determination by prompt-gamma (neutron) activation analysis (PGAA). The second method is isotope-dilution based on isotopically enriched stable chlorine carrier added during chemical sample preparation for accelerator mass spectrometry (ID-AMS). Twenty-six (26) whole rock samples have been processed for PGAA and ID-AMS analysis. This study constitutes the first published inter-comparison for concentrations below 100 μgCl/g. Our results show no significant difference in Cl concentrations between methods. This agreement indicates good retention of chloride during the procedure we employ for whole rock sample dissolution. No significant loss of stable chlorine from either the spike or the sample occurs before isotopic equilibrium is reached, prior to AgCl precipitation. Uncertainties, which are <5% for both methods, affect the uncertainty of the total ³⁶Cl production rate less than 2% for our samples.The Cl concentration measured by PGAA can be used to calculate the amount of isotopically enriched spike for AMS-ID sample preparation with the aim to optimize ³⁶Cl analysis. Furthermore, PGAA offers an advance for the interpretation of ³⁶Cl measurements. It allows measurement of concentrations of major, minor and trace elements including the elements for ³⁶Cl production (Cl, K, Ca, Ti, and Fe), as well as of neutron absorbers and neutron moderators (H, B, Sm and Gd). These measurements are performed simultaneously and with a precision necessary for calculating the relative contributions to ³⁶Cl production from the different mechanisms.     

Cenozoic evolution of the eastern Black Sea: A test of depth-dependent stretching models

Subsidence analysis of the eastern Black Sea basin suggests that the stratigraphy of this deep, extensional basin can be explained by a predominantly pure-shear stretching history. A strain-rate inversion method that assumes pure-shear extension obtains good fits between observed and predicted stratigraphy. A relatively pure-shear strain distribution is also obtained when a strain-rate inversion algorithm is applied that allows extension to vary with depth without assuming its existence or form. The timing of opening of the eastern Black Sea, which occupied a back-arc position during the closure of the Tethys Ocean, has also been a subject of intense debate; competing theories called for basin opening during the Jurassic, Cretaceous or Paleocene/Eocene. Our work suggests that extension likely continued into the early Cenozoic, in agreement with stratigraphic relationships onshore and with estimates for the timing of arc magmatism. Further basin deepening also appears to have occurred in the last ～ 20 myr. This anomalous subsidence event is focused in the northern part of the basin and reaches its peak at ～ 15–10 Ma. We suggest that this comparatively localized shortening is associated with the northward movement of the Arabian plate. We also explore the effects of paleowater depth and elastic thickness on the results. These parameters are controversial, particularly for deep-water basins and margins, but their estimation is a necessary step in any analysis of the tectonic subsidence record stored in stratigraphy.     

Composition of back-arc basin volcanics, Valu Fa Ridge, Lau Basin: Evidence for a slab-derived component in their mantle source

Samples dredged from 2 localities near the crest of the Valu Fa ridge, an active back-arc basin spreading centre in the Lau Basin, consist of highly vesicular lava fragments of andesitic composition. The samples are characterized by rare, euhedral An₈₅ plagioclase phenocrysts in a hypocrystalline groundmass of An₆₀ plagioclase laths, brown glass and rare subhedral clinopyroxene. Samples from within and, to a lesser extent, between the dredge hauls show remarkable isotopic and chemical homogeneity, with: ⁸⁷Sr/⁸⁶Sr − 0.70330 ± 2; ¹⁴³Nd/¹⁴⁴Nd − 0.51303 ± 2; ²⁰⁶Pb/²⁰⁴Pb − 18.65 ± 2; ²⁰⁷Pb/²⁰⁴Pb − 15.55 ± 1; ²⁰⁸Pb/²⁰⁴Pb − 38.34 ± 4; Sr − 165 ppm; Rb − 7 ppm; Cs − 0.17 ppm; K − 3300 to 4200 ppm; Ba − 96 ppm; and REE — LREE depleted with 12–18 × chondritic abundances. On Sr-Nd, Pb-Pb and Sr-Pb plots the volcanics lie just within or on the edge of the MORB fields, overlapping with island-arc volcanics from the Marianas and Tonga. Compared with MORB and ocean-island basalts, the samples show alkali-element enrichment relative to REE and higher Cs relative to Rb. The isotopic and geochemical characteristics of the Valu Fa Ridge volcanics clearly indicate a minor, but significant, slab-derived component in the back-arc basin mantle source.     

Strong climate and tectonic control on plagioclase weathering in granitic terrain

Investigations to understand linkages among climate, erosion and weathering are central to quantifying landscape evolution. We approach these linkages through synthesis of regolith data for granitic terrain compiled with respect to climate, geochemistry, and denudation rates for low sloping upland profiles. Focusing on Na as a proxy for plagioclase weathering, we quantified regolith Na depletion, Na mass loss, and the relative partitioning of denudation to physical and chemical contributions. The depth and magnitude of regolith Na depletion increased continuously with increasing water availability, except for locations with mean annual temperature < 5 °C that exhibited little Na depletion, and locations with physical erosion rates < 20 g m^? 2 yr^? 1 that exhibited deep and complete regolith Na depletion. Surface Na depletion also tended to decrease with increasing physical erosion. Depth-integrated Na mass loss and regolith depth were both three orders of magnitude greater in the fully depleted, low erosion rate sites relative to other locations. These locations exhibited strong erosion-limitation of Na chemical weathering rates based on correlation of Na chemical weathering rate to total Na denudation. Sodium weathering rates in cool locations with positive annual water balance were strongly correlated to total Na denudation and precipitation, and exhibited an average apparent activation energy (Ea) of 69 kJ mol^? 1 Na. The remaining water-limited locations exhibited kinetic limitation of Na weathering rates with an Ea of 136 kJ mol^? 1 Na, roughly equivalent to the sum of laboratory measures of Ea and dissolution reaction enthalpy for albite. Water availability is suggested as the dominant factor limiting rate kinetics in the water-limited systems. Together, these data demonstrate marked transitions and nonlinearity in how climate and tectonics correlate to plagioclase chemical weathering and Na mass loss.     

Appraisal problem in the 3D least squares Fourier seismic data reconstruction

Least squares Fourier reconstruction is basically a solution to a discrete linear inverse problem that attempts to recover the Fourier spectrum of the seismic wavefield from irregularly sampled data along the spatial coordinates. The estimated Fourier coefficients are then used to reconstruct the data in a regular grid via a standard inverse Fourier transform (inverse discrete Fourier transform or inverse fast Fourier transform). Unfortunately, this kind of inverse problem is usually under‐determined and ill‐conditioned. For this reason, the least squares Fourier reconstruction with minimum norm adopts a damped least squares inversion to retrieve a unique and stable solution. In this work, we show how the damping can introduce artefacts on the reconstructed 3D data. To quantitatively describe this issue, we introduce the concept of “extended” model resolution matrix, and we formulate the reconstruction problem as an appraisal problem. Through the simultaneous analysis of the extended model resolution matrix and of the noise term, we discuss the limits of the Fourier reconstruction with minimum norm reconstruction and assess the validity of the reconstructed data and the possible bias introduced by the inversion process. Also, we can guide the parameterization of the forward problem to minimize the occurrence of unwanted artefacts. A simple synthetic example and real data from a 3D marine common shot gather are used to discuss our approach and to show the results of Fourier reconstruction with minimum norm reconstruction.     

Earthquake early warning feasibility in the Campania region (southern Italy) and demonstration system for public school buildings

We present the results of a feasibility study of an earthquake early warning system (EEWS) for the Campania region (southern Italy) using schools as specific targets. The study considered the seismogenic zones as sources of potential earthquakes for the area, the Italian accelerometric network as the recording network for seismic event occurrence, and the performances of the software platform PRESTo ^Plus for data analysis and processing. We analyze the distribution of lead-times for all possible threatening seismic sources for each municipality in the region under study by extracting the lead-time value corresponding to the 5th, 10th and 25th percentiles of the distributions. We discuss the results for the 5th percentile in order to analyze the worst-case scenario: in the case of a single site, the lead-time is expected to be larger than this value in the 95 % of the cases. Since the population distribution in Campania is uneven and most of the people live nearby the coast, whilst the most destructive earthquakes occur along the Apennine chain, we can conclude that an efficient EEWS can allow most of the schools in the area to undertake some mitigating actions. The testing of the EEWS was carried out in the high school ITIS ‘E. Majorana’, located at Somma Vesuviana, about 80 km from the seismogenic Irpinia region. For this purpose, the Sentinel, an actuator made up of low-cost hardware (i.e., Arduino^®), was developed in close cooperation with students and teachers of the school to receive alert messages from the PRESTo ^Plus platform and warn the school users in case of a seismic event. The EEWS and the Sentinel were successfully tested during some blind drills performed during normal school activities.     

An integrated approach for investigating geomorphic response to extreme events: methodological framework and application to the October 2011 flood in the Magra River catchment,Italy

A high‐magnitude flash flood, which took place on 25 October 2011 in the Magra River catchment (1717 km²), central‐northern Italy, is used to illustrate some aspects of the geomorphic response to the flood. An overall methodological framework is described for using interlinked observations and analyses of the geomorphic impacts of an extreme event. The following methods and analyses were carried out: (i) hydrological and hydraulic analysis of the event; (ii) sediment delivery by event landslide mapping; (iii) identification and estimation of wood recruitment, deposition, and budgeting; (iv) interpretation of morphological processes by analysing fluvial deposits; (v) remote sensing and geographic information system (GIS) analysis of channel width changes. In response to the high‐magnitude hydrological event, a large number of landslides occurred, consisting of earth flows, soil slips, and translational slides, and a large quantity of wood was recruited, in most part deriving from floodplain erosion caused by bank retreat and channel widening. The most important impact of the flood event within the valley floor was an impressive widening of the overall channel bed and the reactivation of wide portions of the pre‐event floodplain. Along the investigated (unconfined or partly confined) streams (total investigated length of 93.5 km), the channel width after the flood was up to about 20 times the channel width before the event. The study has shown that a synergic use of different methods and types of evidence provides fundamental information for characterizing and understanding the geomorphic effects of intense flood events. The prediction of geomorphic response to a flood event is still challenging and many limitations exist; however a robust geomorphological analysis can contribute to the identification of the most critical reaches. Copyright © 2016 John Wiley & Sons, Ltd.