Laboratory determination of mechanical and hydraulic properties of chemically grouted sands

The purpose of this paper is to investigate mechanical and hydraulic properties of sands treated with mineral-based grouts through the results of a laboratory test programme consisting of unconfined compression tests (UCS), triaxial bender element tests (BeT) and constant flow permeability tests in triaxial apparatus. An improved apparatus was set up for obtaining high quality, multiple grouted specimens from a single column. Two selected natural sands having different grain sizes were grouted with two mineral-based silica grouts, resulting in different levels of improvement. The behaviour of the sands treated by mineral grouts, in terms of strength, initial stiffness and permeability, was compared with that exhibited by more traditional silicate grouts. The results of this study indicate that sands treated with mineral grouts result in higher strengths, higher initial shear modulus and lower permeability values than the sands treated with the silicate solution. The effect of grout type, effective confining pressure, and sand particle-size on small-strain shear modulus of grouted sand specimens was evaluated. Based on test results, the small strain shear modulus increment from treated to untreated specimens has been correlated with the unconfined compressive strength, obtaining a unique relationship regardless of grout type and grain-size of tested sands.     

The Laurentian Fan: Sohm abyssal plain

The 0.5- to 2-km thick Quaternary Laurentian Fan is built over Tertiary and Mesozoic sediments that rest on oceanic crust. Two 400-km long fan valleys, with asymmetric levees up to 700-m high, lead to an equally long, sandy, lobate basin plain (northern Sohm Abyssal Plain). The muddy distal Sohm Abyssal Plain is a further 400-km long. The sediment supplied to the fan is glacial in origin, and in part results from seismically triggered slumping on the upper continental slope. Sandy turbidity currents, such as the 1929 Grand Banks earthquake event, probably erode the fan-valley floors; but thick muddy turbidity currents build up the high levees.     

Oxidative damage to DNA: an immunohistochemical approach for detection of 7,8-dihydro-8-oxodeoxyguanosine in marine organisms

The modified nucleoside 7,8-dihydro-8-oxodeoxyguanosine (8-oxo-dG) is an index of oxidative DNA damage. An immunohistochemical approach based on the use of monoclonal antibody 1F7 against 8-oxo-dG was investigated in marine organisms with immunoperoxidase and immunofluorescent detection. Relative staining intensity as a measure of the 8-oxo-dG level was microscopically assessed. After laboratory exposures to benzo[a]pyrene (B[a]P), higher levels of oxidative DNA damage were clearly detected in all treated animals compared to controls. While this method eliminates DNA extraction reducing the processing of biological samples, absolute values are not provided. Further, the method requires only small amounts of tissue and potentially discriminates susceptibility to oxidative damage in different cell types. These results suggest that the assay should have practical applications in marine ecotoxicology.     

Quaternary sea-level change and sedimentation on the continental shelf and slope of Antibes,French Riviera

Thin Quaternary sediments overlie Neogene bedrock on the shelf off Antibes, southeastern France. Sparker seismic profiles show shelf break progradation at 110 m water depth, immediately below the most recent postglacial transgression. An older progradational event at the same depth correlates with the top of an acoustically, well-stratified sequence on the slope dated at 29.6 ka. Cores show the post-glacial transgressive surface overlain by shelly sands (dated at 12.7 ka at 85m) and several meters of mud. At the present, the seabed consists of an ephemeral cover of fine sand. The data set on sea-level rise complements data recently obtained on land on the Holocene transgression.     

A large late pleistocene blocky debris flow on the central scotian slope

A SeaMARC I side-scan sonar survey on the central Scotian Slope shows a blocky debris flow with high surface roughness between the 1,000 and 2,000 m isobaths, covering an area of about 1,000 km². The flow is at least 20 m thick, occuring as lenses within channels and as sheets on intervalley areas. The surface reflectivity is variable, with blocks and depressions 50 to 200 m wide and relief of 5 to 20 m. The source zone lies within two canyons on the upper slope and has relatively smooth surface reflectivity, in contrast to the gullied slope to either side.     

Reprint of “Seasonal and daily variation of mercury evasion at coastal and off shore sites from the Mediterranean Sea”

Dissolved gaseous mercury (DGM) was measured continuously using two newly developed techniques and a manual technique. The continuous techniques were based on the equilibrium between the aqueous and gaseous phase (DGM = Hg_extr / H', Hg_extr is the measured mercury concentration in the gas phase, H' is the Henry's Law coefficient at the desired temperature). In order to calculate the annual mercury evasion from the Mediterranean Sea, diurnal and seasonal measurements of DGM, total gaseous mercury in air (TGM), water temperature and wind speed were performed. During August 2003, March–April 2004 and October–November 2004 measurements of these parameters were conducted on board the RV Urania. The continuous measurements of DGM showed a diurnal variation in concentration, at both coastal and off shore sites, with higher concentrations during daytime than nighttime. The concentration difference could be as large as 130 fM between day and night. The degree of saturation was calculated directly from the measurements, S = Hg_extr / TGM and was found to vary between the different seasons. The highest average degree of saturation (850%) and the largest variation in saturation (600–1150%) was observed during the summer. The spring showed the lowest variation (260–360%) and the lowest average degree of saturation (320%). The autumn also showed a large variation in saturation (500–1070%) but a lower average (740%) compared to the summer cruise. This might be explained by the temperature difference between the different seasons, since that parameter varied the most. The flux from the sea surface was calculated using the gas exchange model developed by Nightingale et al. [Nightingale, P.D., Malin, G., Law, C.S., Watson, A.J., Liss, P.S., Liddicoat, M.I., Boutin, J., Upstill-Goddard, R. C., 2000. In situ evaluation of air–sea gas exchange parameterization using novel conservative and volatile tracers. Global Biogeochemical Cycles, 14(1):373–387]. The evasion varied between the different seasons with the highest evasion during the autumn, 24.6 pmol m^− 2 h^− 1. The summer value was estimated to 22.3 pmol m^− 2 h^− 1 and the spring to 7.6 pmol m^− 2 h^− 1. Using this data the yearly evasion from the Mediterranean Sea surface was estimated to 77 tons.     

Analysis of acoustic backscatter in the vicinity of the Dry Tortugas

 Experimental measurements of the bottom backscattering strength from carbonate sediments were made with a 200-kHz multibeam sonar mounted on a remotely operated vehicle. Results were obtained from eight different sites, which may be grouped into three categories, labeled soft, medium and hard, according to measured sediment sound speed. Sediment samples were gathered at or near each site to help interpret the acoustic results. The acoustic results are compared with extant published data and with the BOGGART bottom backscatter model. Backscattering strength values measured in the soft and medium sites fell within the main cluster of previously published values from sediments of similar grain sizes. The values from the hard region fell close to the upper limit. Dependence of the apparent backscattering strength on sonar height above bottom, particularly for the lower values of height above bottom, was observed, which suggests that the scattering process is a multiple-scattering one.     

Coastal uplift rate at Matanzas (Cuba) inferred from MIS5e phreatic overgrowths on speleothems

Many morphological elements in Cuba's landscape (e.g. marine terraces, tidal notches) demonstrate that coastal uplift has taken place, but the rate at which this occurs is not known. Carbonate phreatic overgrowths on speleothems have been found in a cave in Central North Cuba, ~1 km from the present coastline at 16 m asl. They form exceptional and unique mushroom‐shaped speleothems and balconies decorating the walls of the rooms. These phreatic overgrowths on speleothems (POS) formed at the oscillating air–water interface in sea‐level controlled anchialine lakes. U/Th dating of these overgrowths suggests ages that are compatible with the Marine Isotope Stage 5e (i.e. 130–115 ka). These POS have fixed this sea‐level highstand and demonstrate that this part of Cuba has been subjected to a much lower uplift rate than previously reported, that is, less than 0.1 mm/year since the last interglacial.     

East-west trending magnetic anomalies in the Southern Hemisphere of Mars: Modeling analysis and interpretation

Maps of the vector components of the martian crustal magnetic field over the strongly magnetized Terra Cimmeria/Sirenum region are constructed using Mars Global Surveyor magnetometer data. Although pronounced east-west trending anomalies are present on the radial and north field component maps at the mapping altitude (∼360-380 km), these trends are much less prominent at the lower aerobraking altitude (∼90-150 km). Comparisons with similar maps produced using artificial data at the aerobraking altitude indicate that elongated sources in this region may have maximum lengths along the martian surface of ∼500 km and maximum aspect ratios of ∼2. Iterative forward modeling of several relatively isolated anomalies in the mapped region yields paleomagnetic pole positions consistent with those estimated in previous studies of other anomalies using mapping phase and science phasing orbit data. On this basis, it is inferred that sources in the studied region are most probably magnetized primarily in northward or southward directions. Using this additional constraint, iterative forward modeling is then applied to determine a magnetization distribution that is consistent with data at both the aerobraking altitude and the mapping altitude. The model magnetization distribution, which includes 41 discrete sources, again indicates no highly elongated sources. An examination of surface geology in the region as well as a consideration of the global distribution of anomalies suggests that magmatic intrusions (e.g., subsurface dike swarms), cooling in the presence of water, are the most likely sources of the magnetic anomalies.     

Controls on regional variability in marine pore-water diagenesis below the seafloor in Upper Jurassic–Lower Cretaceous prodeltaic sandstone and shales,Scotian Basin,Eastern Canada

Diagenesis in the uppermost Jurassic to Lower Cretaceous deltaic sandstones and shales of the Scotian Basin is an important control on reservoir quality. Ferruginous zone (sub-oxic) marine pore-water diagenesis controls the initial formation of Fe²⁺-silicates that are the precursors of grain-rimming chlorite that preserves porosity. This study assesses the regional controls on the type of marine pore-water diagenesis by studying the sedimentology, mineralogy, and geochemistry of the retrogradational units and underlying progradational units in parasequences from conventional cores in two wells in different parts of the basin. Coated grains preserve a record of whether marine pore-water diagenesis below the seafloor was dominantly in the ferruginous or sulphidic geochemical zone. Four types of coated grain were distinguished, each with a different mineral paragenesis. Mineralogical and chemical evidence of ferruginous zone diagenesis includes the presence of diagenetic chlorite and siderite, and the correlation of P with Fe or Ti. Pyrite and Fe-calcite are found where the sulphidic zone is more significant than the ferruginous zone. Ferruginous zone diagenesis was common in low-sedimentation rate retrogradational sediments with low organic carbon, and in delta-front turbidites and river-mouth sandstones. Estuarine, tidal flat and prodeltaic facies that are directly supplied by riverine sediments have a lower Fe:Ti ratio than do fully marine shoreface and open shelf facies as a result of input of detrital ilmenite and its alteration products. The relative contribution of colloidal iron (hydr)-oxides appears greater in distal low-sedimentation rate environments. Where large changes in sedimentation rate occurred at ravinement surfaces, the underlying progradational rocks have evidence of ferruginous zone diagenesis, whatever their facies. Rapid upward migration of the pore-water profile resulting from the change in sedimentation rate reduced the time available for mineral products to form in the deeper pore-water zones. This study has shown that the availability of Fe and organic carbon varying in a complex manner in marine deltaic sediments, but that the resulting diagenesis by marine pore-water can be predicted from facies and paleogeographic setting.